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Oil-free environment-friendly reclaimed rubber and preparation method thereof

A reclaimed rubber, environmental protection technology, applied in the direction of plastic recycling, recycling technology, etc., can solve the problems of incomplete deodorization, heavy smell of reclaimed rubber, and reduced pollution, so as to improve the regeneration effect and uniformity, improve the dispersion and dissolution , Improve the effect of regeneration

Inactive Publication Date: 2016-02-03
XUZHOU COLLEGE OF INDAL TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Reclaimed rubber is generally polluted, has a strong smell, and is harmful to the human body and the environment. During the production, storage and use of conventional reclaimed rubber, a large amount of harmful substances such as polycyclic aromatic hydrocarbons, hexavalent chromium, polybrominated biphenyls, and heavy metals will be released, which not only smells bad Pollution is harmful to human body and environment
Some odorless reclaimed rubber uses the addition of fragrances and essences, which actually only play a covering role, but does not eliminate harmful substances in the reclaimed rubber; reaction, this method has defects such as incomplete deodorization and increased production cost of reclaimed rubber, and the problem of pollution still exists
[0003] The main reason for the heavy smell of reclaimed rubber is the softener added during the regeneration process. Although the use of polluting softeners such as coal tar with high pollution and heavy odor has been banned, the use of aromatic oils and environmental protection oils used to replace coal tar Softeners such as paraffin oil also contain a large amount of polycyclic aromatic hydrocarbons. Although the degree of pollution has been reduced, the problem of pollution and odor has not been solved from the root
Recently, the popular environment-friendly vegetable oil softener uses pure plant or biological components. Although the pollution and odor problems are alleviated, it has the disadvantages of poor mechanical properties and high product cost.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] This embodiment provides a kind of high-strength oil-free environmentally friendly reclaimed rubber, including 100 parts by weight of 60-mesh truck tire tread rubber powder, 3 parts by weight of sodium lauryl aminopropionate activator, and 1 part by weight of γ- Chloropropyltrimethoxysilane coupling agent, 90 parts by weight of water, 3 parts by weight of liquid polyisoprene rubber LIR-390 (molecular weight about 4800), 1 part by weight of antioxidant N,N'- Diphenyl-p-phenylenediamine.

[0019] This embodiment also provides a preparation method for the above-mentioned high-strength oil-free environmentally friendly reclaimed rubber, including the following steps: mixing 60-mesh tread rubber powder with sodium lauryl aminopropionate activator, γ-chloropropyl trimethoxy Add the silane coupling agent and water into the high-temperature dynamic reactor, and perform regeneration treatment under the conditions of 2.6Mpa pressure, 220°C, and 90r / min stirring blade rotation spe...

Embodiment 2

[0022] This embodiment provides a high-strength oil-free environmentally friendly reclaimed rubber, including 100 parts by weight of 50-mesh truck tire tread rubber powder, 4.5 parts by weight of sodium propyl glycine activator, 0.5 parts by weight of vinyl triacetoxy base silane coupling agent, 90 parts by weight of water, 6 parts by weight of liquid polyisoprene rubber LIR-50 (molecular weight about 5400), 1.5 parts by weight of antioxidant N-phenyl-α-naphthylamine.

[0023] This embodiment also provides the preparation method of the above-mentioned high-strength oil-free environmentally friendly reclaimed rubber, comprising the following steps: mixing 50 mesh tread rubber powder with propylene glycol sodium activator, vinyltriacetoxysilane coupling agent and water Add a high-temperature dynamic reaction kettle, and perform regeneration treatment under the conditions of 2.2Mpa pressure, 210°C, and agitator speed of 110r / min. The treatment time is 60 minutes; then, the high-te...

Embodiment 3

[0026] This embodiment provides a kind of high-strength oil-free environmentally friendly reclaimed rubber, including 100 parts by weight of 40-mesh truck tire tread rubber powder, 3 parts by weight of sodium butylaminodicarboxylic acid activator, and 1.5 parts by weight of γ- Mercaptopropyltrimethoxysilane coupling agent, 70 parts by weight of water, 4 parts by weight of liquid polyisoprene rubber LIR-200 (molecular weight about 3100), and 3 parts by weight of styrenated phenol.

[0027] This embodiment also provides a preparation method for the above-mentioned high-strength oil-free environmentally friendly reclaimed rubber, which includes the following steps: mixing 40-mesh tread rubber powder with butanylaminodicarboxylic acid sodium activator, γ-mercaptopropyltrimethoxysilane The coupling agent and water are added to the high-temperature dynamic reaction kettle, and the regeneration treatment is carried out under the conditions of 2.9Mpa pressure, 230°C, and the stirring s...

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Abstract

The invention discloses an oil-free environment-friendly reclaimed rubber and a preparation method thereof. The reclaimed rubber comprises the following components in parts by weight: 100 parts of load-carrying tire surface rubber powder, 3 to 5 parts of alkyl amino carboxylate type activator, 0.5 to 1.5 parts of silane coupling agent, 5 to 100 parts of water, 3 to 5 parts of liquid polyisoprene rubber, and 1 to 3 parts of phenol or amine type antioxidant. The preparation method comprises the following steps: adding load-carrying tire surface rubber powder, alkyl amino carboxylate type activator, silane coupling agent, and water into a high temperature dynamic reactor; carrying out regeneration under preset conditions, after regeneration, cooling, reducing pressure, discharging products; drying the discharged rubber powder; then adding liquid polyisoprene rubber and phenol or amine type antioxidant, evenly mixing, allowing the mixture to stand still for a while, adding the rubber powder into an open mill, processing the rubber powder for a while, and batching out the rubber powder to obtain high-strength oil-free environment-friendly reclaimed rubber. The provided preparation method radically reduces the odor of reclaimed rubber. The obtained reclaimed rubber and products of reclaimed rubber are nearly odorless, and only have the smell of rubber hydrocarbon.

Description

technical field [0001] The invention belongs to the field of waste rubber recycling, and in particular relates to a production method of high-strength, oil-free and environment-friendly regenerated rubber. Background technique [0002] Reclaimed rubber is generally polluted, has a strong smell, and is harmful to the human body and the environment. During the production, storage and use of conventional reclaimed rubber, a large amount of harmful substances such as polycyclic aromatic hydrocarbons, hexavalent chromium, polybrominated biphenyls, and heavy metals will be released, which not only smells bad And pollution is bad for human body and environment. Some odorless reclaimed rubber uses the addition of fragrances and essences, which actually only play a covering role, but does not eliminate harmful substances in the reclaimed rubber; reaction, this method has defects such as incomplete deodorization, increased production cost of reclaimed rubber, and the problem of pollu...

Claims

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Application Information

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IPC IPC(8): C08L17/00C08L9/00C08K5/17C08K5/5419C08K5/18C08J11/28
CPCY02W30/62
Inventor 孙鹏朱信明丛后罗刘希春王艳秋徐云慧臧亚楠
Owner XUZHOU COLLEGE OF INDAL TECH
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