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Insulating and heat-conductive sheet

It is a technology of insulation and high thermal conductivity, which is applied in the direction of insulators, organic insulators, plastic/resin/wax insulators, etc., and can solve problems such as high thermal anisotropy, reduced insulation breakdown strength, and lack of wettability of binder resins. To achieve the effect of ensuring insulation reliability and reducing damage

Inactive Publication Date: 2016-02-03
TOYOBO CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, thermal conduction is suppressed due to the matrix resin layer existing between fillers, and high thermal anisotropy cannot be obtained in terms of filling ratio
[0006] In addition, in general, fibrous heat-conducting materials obtain high thermal conductivity by increasing the orientation of molecules along the fiber axis direction. When there are many polymers that can obtain such an orientation, they do not have highly rigid molecular chains and are incompatible with Functional groups for interaction with other substances, lack of wettability with binder resin
Therefore, in the actual use environment, due to exposure to high temperature and repeated temperature changes, the interface between the thermally conductive material and the binder resin may peel off, and the dielectric breakdown strength may decrease.

Method used

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  • Insulating and heat-conductive sheet
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  • Insulating and heat-conductive sheet

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0158] The thermal conductivity of ZylonHM (manufactured by Toyobo Co., Ltd.) in the fiber axis direction was 40 W / mK. As the insulating high thermal conductivity fiber, use ZylonHM cut into a length of 400 μm, as the binder resin liquid, use the liquid silicone rubber main agent TSE3431-A / 100 parts by mass manufactured by MomentivePerformanceMaterialsInc., and the liquid silicone rubber curing agent TSE3431 manufactured by MomentivePerformanceMaterialsInc. -C / 30 parts by mass of the resin solution obtained by mixing. As an adhesive, a 10 wt.% aqueous solution of polyvinyl alcohol AH-26 (manufactured by Nippon Synthetic Chemicals) was used. As a base material, a 20μm thick The substrate was placed on a positive electrode plate thinly coated with paraffin oil as a lubricant, and the adhesive was applied to a thickness of 25 μm. Electrostatic flocking was performed on it with a distance between electrodes of 3 cm and a voltage of 18 kV for 5 minutes to make a Zylon flocking s...

Embodiment 2

[0160] Electrostatic flocking and substrate shrinkage were performed in the same manner as in Example 1, except that the amount of Zylon charged was 20%. As the binder resin solution, Toyobo Co., Ltd. saturated copolyester polyurethane solution UR3600 / 80.9 parts by weight, Toyobo Co., Ltd. saturated copolyester polyurethane solution BX-10SS / 12.0 parts by weight, Toyobo Co., Ltd. A liquid obtained by mixing epoxy resin AH-120 / 7.1 parts by weight manufactured by the company and 100 parts by weight of methyl ethyl ketone. The shrunk sheet was immersed in a binder resin liquid layer having a depth of 1200 μm, and vacuum degassed to impregnate the binder resin liquid. After drying at 60° C. for 2 hours, both sides of the sheet were rubbed with #2000 rubbing paper to prepare a Zylon complex ester polyurethane resin sheet with a thickness of 100 μm. In this state, the sheet is in a semi-cured state. In actual use, the sheet in a semi-cured state is bonded to a heat sink and a cooli...

Embodiment 3

[0162] The sheet|seat was produced by the method similar to Example 2 except having set the voltage of electrostatic flocking to 13 kV, and Zylon input amount to 17%. The volume intrinsic resistivity of the fully cured sheet is 10 16 More than Ω·cm (measuring machine exceeds the range).

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Abstract

The present invention addresses the problem of providing a heat-conductive sheet having excellent insulation properties and thermal anisotropy and also having high heat-dissipating properties. An insulating and heat-conductive sheet characterized by comprising insulating and highly heat-conductive fibers that penetrate in the thickness direction and a binder resin, wherein the penetration density of the insulating and highly heat-conductive fibers that penetrate in the thickness direction is 6% or more, the ratio of the thermal resistivity in the thickness direction to the thermal resistivity in the planar direction is 2 or more, and the initial dielectric breakdown strength is 20 kV / mm or more.

Description

technical field [0001] The present invention relates to an insulating heat conducting sheet having electrical insulation and high thermal anisotropy. More specifically, it relates to an insulating heat conduction sheet capable of ensuring insulation reliability and selectively transferring heat in a specific direction from heat radiators such as electronic substrates, semiconductor chips, and light sources. Background technique [0002] In recent years, the importance of heat dissipation measures has increased as electronic equipment has become lighter, thinner and smaller, and the heat dissipation density has increased due to higher power consumption. In order to reduce the thermal failure of electronic equipment, it is important to quickly release the heat generated in the equipment to heat radiators such as cooling materials and housings in a manner that does not adversely affect peripheral components. member. As a method of dissipating heat generated from radiators suc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J5/18B05D1/14H01L23/373H05K7/20C08J7/043C08J7/046C08J7/05
CPCH01L23/3737H01L2224/32225H01L2924/0002C08J2325/06C08J2367/00C08J2423/16C08J2433/06C08J2469/00C08J2475/04C08J2483/04H01B3/302H01B3/46H01B3/48C08J7/0427C08J7/05C08J7/043C08J7/046H01L2924/00
Inventor 桥本香菜公門惠都子恵岛明纪
Owner TOYOBO CO LTD
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