Halogen-free flame-retardant high-temperature-resistant polyester elastomers and a preparation method therefor

A technology of high temperature resistant polyester and polyester elastomer, applied in halogen-free flame retardant and high temperature resistant polyester elastomer and its preparation, in the field of automobile engine peripheral wire industry, can solve problems such as high temperature resistance and flame retardant efficiency, and avoid the Degradation behavior, increasing flame retardant char formation, and the effect of broad market prospects

Active Publication Date: 2016-03-16
中广核三角洲(江苏)塑化有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The invention provides a halogen-free flame-retardant high-temperature-resistant polyester elastomer polymer, which aims to improve the deficiencies of the prior art, produce a kind of heat-resistant performance that can be improved without using radiation, and solve the problems of conventional products that are not resistant to high temperature and resistance to heat resistance. The problem of low fuel efficiency

Method used

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  • Halogen-free flame-retardant high-temperature-resistant polyester elastomers and a preparation method therefor
  • Halogen-free flame-retardant high-temperature-resistant polyester elastomers and a preparation method therefor

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Polyester type polyester elastomer 40 parts

[0046] Polybutylene terephthalate 15 parts

[0047] 3 parts of compatibilizer

[0048] Phosphorus nitrogen flame retardant 20 parts

[0049] Phosphonate flame retardant 10 parts

[0050] 3 parts acid absorber

[0051] Flame retardant synergist 7 parts

[0052] Antioxidant 0.5 parts

[0053] Anti-hydrolysis agent 1.5 parts

[0054] The preparation method is as follows:

[0055] In the first step, after weighing the raw materials according to the weight ratio of the raw materials, first dry 40 parts of polyester elastomer and 15 parts of PBT in an oven at 120-130 ° C for pretreatment; in the second step, mix 3 parts of compatibilizer, phosphorus nitrogen 20 parts of flame retardant, 10 parts of phosphate ester flame retardant, 3 parts of acid absorbing agent, 7 parts of flame retardant synergist, 0.5 part of antioxidant, 1.5 parts of anti-hydrolysis agent are thrown into the high mixer and mixed evenly; the third step ...

Embodiment 2

[0057] Polyester type polyester elastomer 35 parts

[0058] Polybutylene terephthalate 20 parts

[0059] 5 parts of compatibilizer

[0060] Phosphorus nitrogen flame retardant 15 parts

[0061] Phosphonate flame retardant 15 parts

[0062] 3 parts acid absorber

[0063] Flame retardant synergist 5 parts

[0064] Antioxidant 0.5 parts

[0065] Anti-hydrolysis agent 1.5 parts

[0066] The preparation method is as follows:

[0067] In the first step, after weighing the raw materials according to the weight ratio of the raw materials, 35 parts of polyester elastomer and 20 parts of PBT are dried and pretreated in an oven at 120-130 ° C; in the second step, 5 parts of compatibilizer, phosphorus nitrogen 15 parts of flame retardant, 15 parts of phosphate ester flame retardant, 3 parts of acid absorbing agent, 5 parts of flame retardant synergist, 0.5 part of antioxidant, 1.5 parts of anti-hydrolysis agent are thrown into the high mixer and mixed evenly; the third step , add ...

Embodiment 3

[0069] 30 parts polyester elastomer

[0070] Polybutylene terephthalate 25 parts

[0071] 7 parts of compatibilizer

[0072] Phosphorus nitrogen flame retardant 10 parts

[0073] Phosphonate flame retardant 20 parts

[0074] 3 parts acid absorber

[0075] Flame retardant synergist 3 parts

[0076] Antioxidant 0.5 part

[0077] Anti-hydrolysis agent 1.5 parts

[0078] The preparation method is as follows:

[0079] In the first step, after weighing the raw materials according to the weight ratio of the raw materials, 30 parts of polyester elastomer and 25 parts of PBT are dried and pretreated in an oven at 120-130 °C; in the second step, 7 parts of compatibilizer, phosphorus nitrogen 10 parts of flame retardant, 20 parts of phosphate ester flame retardant, 3 parts of acid absorbing agent, 3 parts of flame retardant synergist, 0.5 part of antioxidant, 1.5 parts of anti-hydrolysis agent are thrown into the high mixer and mixed evenly; the third step , add the dried polyest...

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Abstract

Provided are halogen-free flame-retardant high-temperature-resistant polyester elastomers and a preparation method therefor. The provided polyester elastomers comprise the following raw materials, by weight, 20-50 parts of polyester elastomers, 10-30 parts of polybutylene terephthalate, 2-10 parts of compatilizer, 10-30 parts of phosphor-nitrogen flame retardant, 5-20 parts of phosphonate flame retardant, 2-5 parts of acid absorbing agent, 3-8 parts of flame retardation synergistic agent, 0.3-0.8 part of anti-oxidant and 0.5-2 parts of anti-hydrolysis agent. The preparation method is as follows: polyester elastomers and polybutylene terephthalate are subjected to drying processing, and are mixed with other ingredients uniformly in a high-speed mixing machine; discharging is carried out, the mixture is subjected to bar drawing and granulation by a double screw extruder, and halogen-free flame-retardant high-temperature-resistant polyester elastomers are prepared. The defects of the prior art are overcome, on the premise that present device configuration and technological parameter setting are not changed, an optimal solution is provided that halogen-free flame-retardant high-temperature-resistant polyester elastomers can be produced stably, the high temperature resistance of the material is improved obviously, the flame resistance is raised greatly, and other performances are optimized.

Description

technical field [0001] The invention relates to the field of polymer elastomer materials, in particular to a halogen-free flame-retardant and high-temperature-resistant polyester elastomer and a preparation method thereof. The halogen-free flame-retardant and high-temperature-resistant polyester elastomer is especially used in the electric wire industry around automobile engines. Background technique [0002] Thermoplastic Polyester Elastomer (Thermoplastic Polyester Elastomer, hereinafter referred to as TPEE) is a type of linear block copolymer containing PBT polyester hard segment (crystalline phase, providing strength) and soft segment (continuous phase). The rigidity, polarity and crystallinity of the hard segment of TPEE make TPEE have outstanding strength and good high temperature resistance, creep resistance, solvent resistance, oil resistance and impact resistance; the low glass transition temperature and saturation of the soft segment It has excellent low temperatur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/06C08L67/02C08L51/00C08L85/02C08K5/5313C08K3/22C08K9/06C08K3/34
CPCC08K2201/011C08L75/06C08L2201/02C08L2201/08C08L2201/22C08L2205/035C08L67/02C08L51/00C08L85/02C08K5/5313C08K2003/2296C08K9/06C08K3/346
Inventor 唐伟
Owner 中广核三角洲(江苏)塑化有限公司
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