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A composite ultra-high water filling material and its preparation method

A filling material, ultra-high water technology, applied in the field of materials, can solve the problems of long condensation and hardening time, complicated construction process, affecting the conveying effect, etc., to achieve perfect structure and performance, good slurry fluidity, and simple and feasible preparation method. Effect

Active Publication Date: 2017-09-08
HENAN POLYTECHNIC UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the filling technologies used mainly include paste filling technology, paste-like filling technology, high-water filling technology, gangue filling technology, etc. The above filling technologies have the advantages of large material consumption, complicated construction process, long setting and hardening time, incomplete filling, It needs to consume a lot of manpower and other disadvantages. Although the ultra-high water filling technology can avoid the above disadvantages, due to the limited ability of the current ultra-high water material to consolidate water, most of it is still free water dispersed in the filling body. During the process, if you encounter this filling area, it is as if the coal cutter has encountered a mud area. Along the direction of rotation of the coal cutter, the filling material will fly around and fly to the scraper machine. Due to the high water content of the filling material, it will Slippage occurs on the scraper machine, which affects the conveying effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A composite ultra-high water filling material, formula: the filling material is composed of A slurry and B slurry with a volume ratio of 1:1, A slurry is composed of 1000g A1, 100g A2 and 4000g water, and B slurry is composed of 1000g B1, 100g B2 and 4000g water;

[0024] The parts by weight of A1 consist of: 85 parts of sulphoaluminate cement clinker, 7 parts of fly ash, and 8 parts of composite additive;

[0025] The parts by weight of A2 consist of: 100 parts of polyoxypropylene glycol, 1 part of triethylenetetramine;

[0026] The composition of composite additive 1 in parts by weight is: 10 parts of sodium chloride, 20 parts of sodium sulfate, 60 parts of sodium metaaluminate, 5 parts of sodium gluconate, and 5 parts of hydroxypropyl methylcellulose;

[0027] The parts by weight of B1 consist of: 70 parts of gypsum, 20 parts of lime, 7 parts of fly ash, 3 parts of composite additive two;

[0028] The parts by weight of B2 consist of: 85 parts of diphenylmethane di...

Embodiment 2

[0041] A composite ultra-high water filling material, formula: composite admixture 1, composite admixture 2, A1, A2, B1, and B2 are the same as in Example 1, except that the A slurry is composed of 1000g A1, 150g A2 and 6000g water Composition, B slurry consisted of 1000g B1, 150g B2 and 6000g water.

[0042] Preparation method: the steps are the same as in Example 1, and the only difference from Example 1 is that the amount of each raw material is weighed according to the formula of the filling material in Example 2.

[0043] It is tested by sampling: the single liquid storage time of A slurry and B slurry is 28 hours and 32 hours respectively, the single liquid fluidity of A slurry and B slurry is 325mm and 335mm respectively; the hardening time of mixed slurry is 61min, 2h compressive strength is 0.26MPa, 28d compressive strength is 1.22MPa, and the seed setting rate is 98.3%.

Embodiment 1-2

[0045] 1. The storage time of the single liquid, the hardening time of the mixed slurry and the compressive strength refer to 6.4 single slurry setting time and 6.3 gelling in the coal industry standard of the People's Republic of China "High Water Filling Materials" (MT / T 420-1995) Time, 6.2 compressive strength;

[0046] 2. The fluidity of single liquid is carried out according to Appendix A of GB 50119-2003;

[0047] 3. The setting rate refers to the solid volume Vs after the slurry solidifies and the initial volume V of the slurry 0 ratio, expressed as a percentage. If the seed setting rate is greater than 1, the fruit body expands; if the seed setting rate is less than 1, the fruit body shrinks.

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Abstract

The invention belongs to the technical field of materials, and discloses a composite type ultrahigh water filling material and a preparation method thereof. The composite type ultrahigh water filling material is prepared from slurry A and slurry B in equal volumes, wherein the slurry A is prepared from the following components in parts by weight: 1 part of A1, 0.05 to 0.20 part of A2 and 3 to 11 parts of water; the slurry B is prepared from the following components in parts by weight: 1 part of B1, 0.05 to 0.20 part of B2 and 3 to 11 parts of water; A1 is prepared from sulfate aluminate cement clinker, pulverized fuel ash and a composite additive I; A2 is prepared from polymer polyol and a catalyst; the composite additive I is prepared from sodium chloride, anhydrous sodium sulfate, sodium metaaluminate, sodium gluconate and hydroxypropyl methyl cellulose; B1 is prepared from gypsum, lime, the pulverized fuel ash and a composite additive II; B2 is prepared from polyisocyanate and a dispersing agent; the composite additive II is prepared from sodium carbonate, aluminum sulfate and the hydroxypropyl methyl cellulose. The composite type ultrahigh water filling material disclosed by the invention has the advantages of better hardening performance and better using performance.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to a composite ultra-high water filling material and a preparation method thereof. Background technique [0002] On the one hand, after mining in coal mines and other mining industries, in order to avoid the formation of collapsed areas, it is necessary to fill the gobs, especially the "three ups and one down" areas; Due to geological structure and other reasons, there will be unfavorable conditions such as caving areas or collapsed columns. In order to avoid their impact on the coal mining process, pre-filling is often required. At present, the filling technologies used mainly include paste filling technology, paste-like filling technology, high-water filling technology, gangue filling technology, etc. The above filling technologies have the advantages of large material consumption, complicated construction process, long setting and hardening time, incomplete filling,...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/14C04B18/08C04B22/00C04B22/06C04B22/10C04B22/12C04B22/14C04B24/10C04B24/12C04B24/32C04B24/38C04B103/40
CPCC04B28/14C04B2103/408C04B2111/00724C04B7/32C04B18/08C04B22/124C04B22/0093C04B22/142C04B24/10C04B24/383C04B24/32C04B24/121C04B22/06C04B22/064C04B22/10C04B22/148C04B24/12Y02W30/91
Inventor 王雨利马玉祥熊祖强张耀辉杨佳
Owner HENAN POLYTECHNIC UNIV
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