Copper slag-base low silicon iron tailing filling material and preparation technology thereof

A tailings filling and ferrosilicon technology, which is applied in sustainable waste treatment, solid waste management, climate sustainability, etc., can solve the problem of high concentration of paste pumping cement filling slurry, complicated maintenance and management of process equipment, and tailings. It can solve the problem of high utilization rate, and achieve the effect of solving ecological and environmental problems, saving manpower and material, and reducing the amount of cement used.

Inactive Publication Date: 2016-05-04
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The advantages and disadvantages of each filling process are obvious: the tailings particle size of the graded tailings filling should not be less than 37 μm, and its utilization rate is only about 55%; the high-concentration full tailings cemented filling has good mechanical properties, high strength, and a wide range of applications. Rapid; paste pumping cemented filling slurry with high concentration, short setting time, high utilization rate of tailings, less cement consumption, but high infrastructure costs, complex maintenance and management of process equipment, and great technical difficulties

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A copper slag-based low-silicon iron tailings filling cementing material, its raw materials are composed of: copper slag material 20wt%, cement clinker 5wt%, sodium hydroxide 0.5wt%, low-silicon iron tailings 74.5wt%; The raw material composition of the copper slag material is: copper slag 79.3wt%, lime 4.2wt%, gypsum 16wt%, naphthalene-based water reducer 0.5wt%.

[0027]The silicon dioxide content in the low-silicon iron tailings is 39.11wt%.

[0028] The preparation method of the copper slag material is as follows: after mixing the copper slag, lime, gypsum and naphthalene-based water reducing agent, ball milling for 25 minutes.

[0029] A kind of method that uses above-mentioned copper slag-based low-silicon iron tailings filling cementing material to prepare filling body test block, the mass ratio of filling cementing material and sand is 1:4, and slurry concentration is 75wt%; The compressive strength of block 28d is 3.62MPa, fully meeting the needs of mine filli...

Embodiment 2

[0031] A copper slag-based low-silicon iron tailings filling cementing material, its raw materials are composed of: copper slag material 21wt%, cement clinker 7wt%, sodium hydroxide 0.8wt%, low-silicon iron tailings 71.2wt%; The raw material composition of the copper slag material is: 80wt% copper slag, 3wt% lime, 16.7wt% gypsum, and 0.3wt% naphthalene-based water reducer.

[0032] The silicon dioxide content in the low-silicon iron tailings is 24.46wt%.

[0033] The preparation method of the copper slag material is as follows: after mixing the copper slag, lime, gypsum and naphthalene-based water reducing agent, ball milling for 25 minutes.

[0034] A method for preparing a filling body test block using the above-mentioned copper slag-based low-silicon iron tailings filling cementing material, the slurry concentration is 75wt%; the 28d compressive strength of the test block prepared at this time is 6.32MPa, which fully meets the mine filling needs .

Embodiment 3

[0036] A copper slag-based low-silicon iron tailings filling cementing material, its raw materials are composed of: copper slag material 25wt%, cement clinker 9wt%, sodium hydroxide 0.3wt%, low-silicon iron tailings 65.7wt%; The raw material composition of the copper slag material is: copper slag 75.2wt%, lime 6wt%, gypsum 18wt%, naphthalene-based water reducer 0.8wt%.

[0037] The silicon dioxide content in the low-silicon iron tailings is 25.42wt%.

[0038] The preparation method of the copper slag material is as follows: after mixing the copper slag, lime, gypsum and naphthalene-based water reducing agent, ball milling for 25 minutes.

[0039] A method of preparing a filling body test block using the above-mentioned copper slag-based low-silicon iron tailings filling cementing material, the slurry concentration is 75wt%; the 28d compressive strength of the test block prepared at this time is 8.51MPa, which fully meets the mine filling needs .

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Abstract

The invention belongs to the field of filling cementing material preparation and particularly relates to a copper slag-base low silicon iron tailing filling material. The filling cementing material is prepared from 15-25wt% of copper slag materials, 3-8wt% of cement clinker, 0.3-0.8wt% of sodium hydroxide and 70-80wt% of low silicon iron tailings. The copper slag materials are prepared from 75-80wt% of copper slag, 3-6wt% of lime, 15-18wt% of gypsum and 0.3-0.8wt% of naphthalene water reducer. The filling cement material is prepared through the copper slag and the low silicon iron tailings, the local ecological environment problems and slag waste problems of mines are solved, and manpower and material resources can be greatly saved. The cost is low, the equipment investment is small, the filling effect is good, and the copper slag-base low silicon iron tailing filling material has wide application prospects in the fields of mine backfilling, building materials and others.

Description

technical field [0001] The invention belongs to the field of preparation of filling cementing materials, in particular to a filling cementing material of copper slag-based low-silicon iron tailings. Background technique [0002] The use of metal tailings as mine filling materials has a long history at home and abroad, mainly in the following stages: ① Before the 1950s, waste rock dry filling process; ② In the 1960s, water-sand filling process; ③ 1960s-70s In the 1980s, tailings cemented filling technology; ④After the 1980s and 1990s, new technologies such as paste filling and full tailings cemented filling. The application and research of mining by filling method is relatively early in foreign countries. Canada began to use impact sand as filling material in the 1930s and applied it to the mining filling process. In the late 1940s, it began to use the tailings of the concentrator in the late 1940s. filling for research. At this time, backfill mining, as an auxiliary method...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/14C04B28/08C04B18/12
CPCC04B18/12C04B28/08C04B28/14C04B2103/302C04B2111/00724C04B7/00C04B7/32C04B24/226C04B22/062Y02W30/91
Inventor 晏全香库建刚
Owner FUZHOU UNIV
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