Efficient shrinkage-reducing anti-cracking agent and preparation method thereof

A technology of anti-cracking agent and shrinkage reducing agent, which is applied in the field of high-efficiency shrinkage-reducing anti-cracking agent and its preparation, which can solve the problems of concrete strength loss, high cost, and less active ingredients, so as to improve the effectiveness of expansion, expand the scope of use, and delay the early stage. The effect of hydration

Active Publication Date: 2016-05-25
JIANGSU SOBUTE NEW MATERIALS
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The addition of fiber only improves the tensile strength of concrete, prevents the expansion and extension of cracks to a certain extent, mainly plays the role of dispersing or homogenizing shrinkage stress, and cannot fundamentally eliminate the occurrence of cracks
Expansion agent is to compensate concrete shrinkage by generating expansion crystals through hydration reaction. Although it can compensate early shrinkage or produce micro-expansion, it can only achieve a suitable compensation effect when it is added in an appropriate amount (8% to 12%). When it is high, it will cause a large loss of concrete strength, and when the dosage is small, the compensation effect cannot be fully exerted, and the crack resistance effect is poor
In order to achieve the anti-cracking effect, the current amount of expansion agent in concrete is generally 8% to 12% of the total amount of cementitious materials, which brings high costs to long-distance transportation, resulting in limited sales of existing expansion agents. Conducive to the application and promotion of expansion agent
At present, the shrinkage reducing agents used at home and abroad are mostly polyether and polyether derivatives. Although they can reduce the shrinkage of concrete, they are mostly liquid products with few active ingredients. To achieve the required shrinkage reduction effect, a large amount needs to be mixed into concrete. Invisibly increases the cost of concrete, and the liquid shrinkage reducing agent is highly volatile, which seriously affects the health of workers and directly limits its promotion and application in China

Method used

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  • Efficient shrinkage-reducing anti-cracking agent and preparation method thereof
  • Efficient shrinkage-reducing anti-cracking agent and preparation method thereof

Examples

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preparation example Construction

[0017] 1. Preparation of shrinkage reduction components

[0018] Mix 2 parts of polyethylene glycol monoallyl ether, 2 parts of methoxypolyethylene glycol methacrylate and 1 part of styrene into the reaction kettle, and mix polyethylene glycol monoallyl ether with The molar ratio of hydrogen peroxide is 5:1. Add 0.1 mol / L hydrogen peroxide solution in proportioning ingredients, raise the temperature of the reactor to 65°C, and then add 0.5 parts of polyacrylamide and 0.1 parts of ammonium persulfate initiator dropwise to the reaction at the same time. In the kettle, add dropwise separately, and the dropping time is 60min. After the dropwise addition, keep the temperature for 3 hours. After the reaction, add alkali to neutralize to pH=7.1, and obtain a light milky white transparent liquid with a solid content of 46.3%, and a molecular weight of 49000. Liquid shrinkage reducing component A with a macromonomer conversion of 91.2%.

[0019] 2. Preparation of powder high-efficienc...

Embodiment 1

[0021] Get 65 parts of f-CaO content and be 65%, particle size is the commercially available calcium oxide expansion agent of 900 meshes and joins in the powder feeder of spray-drying tower as expansion component, feeds the gas that pressure is 0.5MPa to expand component It is delivered to the front end of the hot air distributor at the top of the drying tower, and hot air with a temperature of 190°C is introduced to quickly dry the expansion component and evenly disperse it in the hot air flow. Open the spray drying tower, and when the temperature of the feed inlet at the top of the spray drying tower is 120°C, use a screw pump to transport 35 parts of the above-mentioned liquid shrinkage reduction components to the liquid feed inlet at the top of the spray drying tower, and pass through the liquid feed inlet The high-speed centrifugal atomizing disc atomizes the liquid shrinkage component into micro-droplets with a droplet diameter of 50-100 microns, and at the same time, the...

Embodiment 2

[0023] Get 60 parts of f-CaO content and be 65%, particle size is the commercially available calcium oxide expansion agent of 900 meshes and joins in the powder feeder of spray-drying tower as expansion component, feeds the gas that pressure is 0.4MPa to expand component It is delivered to the front end of the hot air distributor at the top of the drying tower, and hot air with a temperature of 180°C is introduced to quickly dry the expansion component and evenly disperse it in the hot air flow. Open the spray drying tower, and when the temperature of the feed inlet at the top of the spray drying tower is 125°C, use a screw pump to transport 40 parts of the above-mentioned liquid shrinkage reduction components to the liquid feed inlet at the top of the spray drying tower, and pass through the liquid feed inlet The high-speed centrifugal atomizing disc atomizes the liquid shrinkage component into micro-droplets with a droplet diameter of 50-100 microns, and at the same time, the...

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Abstract

The present invention discloses an efficient shrinkage-reducing anti-cracking agent and a preparation method thereof, the efficient shrinkage-reducing anti-cracking agent comprises a shrinkage-reducing component and an expansion component, the shrinkage-reducing component is a shrinkage-reducing agent is a comb-shaped copolymer shrinkage-reducing agent, the expansion component is a calcium oxide type expander, and the mass ratio of the shrinkage-reducing component to the expansion component is 35: 65-45: 55. The shrinkage-reducing component is absorbed on the surface of the expansion component by spray drying, the expansion component is used as an anti-blocking insulating material to achieve fine powder production of the liquid shrinkage-reducing component, the shrinkage-reducing component is used as a waterproof insulation material to delay early hydration of the expansion component, and ultimately coordination and integration of expansion and shrinkage educing is achieved; by powder production and application, injuries of volatile organic solvents on workers during single use of the shrinkage-reducing agent can be avoided, the effective content of the product can be increased, the efficient shrinkage-reducing anti-cracking agent has a significant anti-cracking effect under conditions of low dosage, and helps are provided for expansion of the use range of anti-cracking materials.

Description

technical field [0001] The invention relates to a concrete admixture, in particular to a high-efficiency shrinkage-reducing anti-cracking agent and a preparation method thereof. Background technique [0002] The shrinkage of concrete and the resulting cracking is a persistent problem of concrete engineering quality, and it is also a problem that has been concerned by the academic and engineering circles. In recent years, with the continuous development of chemical admixture technology and the extensive use of various finely ground mineral admixtures, contemporary high-performance concrete characterized by low water-binder ratio and large-volume mineral admixtures has gradually replaced high-performance concrete. Traditional concrete, characterized by water-binder ratio and high cement content, plays a leading role in construction engineering and is widely used. Since the composition and structure of high-performance concrete are characterized by viscous paste, good water re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/26C08F283/06C08F212/08C04B103/60
CPCC04B24/2694C04B40/0042C04B2103/60C08F283/065C04B22/064C04B40/0046C08F212/08
Inventor 张守治田倩高南箫王育江陆安群姚婷
Owner JIANGSU SOBUTE NEW MATERIALS
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