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A method for preparing functional cotton fabric by using divalent nickel ions to complex phytic acid

A divalent nickel and cotton fabric technology, applied in plant fiber, textiles, papermaking, fiber treatment, etc., can solve the problems of loss of electrical conductivity, easy de-doping of doped acid, etc., to improve washability and not easy to de-dope Mixed, high-affinity effects

Inactive Publication Date: 2018-06-15
SOUTHWEST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The currently disclosed polyaniline-coated cotton fabrics are mainly doped with some small molecular organic acids, and the doped acids are easy to dedope and lose conductivity during the washing process.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] (1) Dissolve 3g of nickel chloride in 50mL of water, add cotton cloth, stir for 30min at 60ºC, take out and dry;

[0012] (2) Place the cotton treated above in 100 mL of an aqueous solution containing 5 g of phytic acid and stir for 45 minutes at 80ºC;

[0013] (3) Cool to 0ºC, add 0.5mL aniline;

[0014] (4) Slowly add 20mL aqueous solution containing 2g of ammonium persulfate, and let it stand for 30min after dripping;

[0015] (5) Take out the cotton fabric after the above treatment, wash and dry.

Embodiment 2

[0017] (1) Dissolve 5g nickel nitrate in 50mL water, add cotton cloth, stir at 60ºC for 30min, take it out and dry;

[0018] (2) Place the cotton treated above in 100 mL of an aqueous solution containing 10 g of phytic acid, and stir for 45 minutes at 80ºC;

[0019] (3) Cool to 5ºC, add 5mL aniline;

[0020] (4) Slowly add 20mL aqueous solution containing 7g of ammonium persulfate, and let it stand for 30min after dripping;

[0021] (5) Take out the cotton fabric after the above treatment, wash and dry.

Embodiment 3

[0023] (1) Dissolve 4g nickel nitrate in 50mL water, add cotton cloth, stir at 60ºC for 30min, take it out and dry;

[0024] (2) Place the cotton treated above in 100mL of 8g phytic acid aqueous solution, and stir for 45min at 80ºC;

[0025] (3) Cool to 0ºC, add 3mL aniline;

[0026] (4) Slowly add 20mL aqueous solution containing 5g of ammonium persulfate, and let it stand for 30min after dripping;

[0027] (5) Take out the cotton fabric after the above treatment, wash and dry.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention provides a method for preparing functional cotton fabric by divalent nickel ion complex phytic acid. The method comprises the following steps: (1) dissolving a divalent nickel ion salt into 50mL of water, adding cotton cloth, stirring at 60 DEG C for 30 minutes and taking out and drying the cotton cloth; (2) putting the processed cotton cloth into a phytic acid water solution and stirring the cotton cloth at 80 DEG C for 45 minutes; (3) cooling the cotton cloth to 0-5 DEG C and adding phenylamine; (4) slowly dropwise adding an ammonium persulfate water solution, and then standing for 30 minutes; and (5) taking out, washing and drying the processed cotton fabric. With divalent nickel ions as a phytic acid adsorbent, phytic acid is gathered on the surface of a cotton fiber; and the phenylamine is in situ polymerized on the surface of the cotton fiber on this basis, so that the cotton fabric has conductivity and flame retardant property. A flocculation technology of the divalent nickel ions on the phytic acid is combined with a phenylamine in-situ chemical synthesis technology, so that the washability of the phytic acid is improved; and the conductivity, the flame retardant stability and the durability of the cotton fabric are improved.

Description

Technical field [0001] The invention relates to a method for preparing functional cotton fabrics, in particular to a method for preparing functional cotton fabrics by complexing phytic acid with divalent nickel ions. Background technique [0002] With the advancement of science and technology, more electrical products have entered people's lives, bringing electromagnetic pollution to people, which is called the fourth largest pollution after air pollution, water pollution and noise pollution. After the human body is irradiated by excessive electromagnetic waves, blood, lymph fluid and cell protoplasm will change, causing DNA damage in cells and genetic mutations and deformities, which in turn induce leukemia and tumors, and also cause placental chromosomal changes. Lead to deformity of the baby or spontaneous abortion of pregnant women. [0003] Conductive polymers are organic polymers with adjustable conductive properties, especially polyaniline has been widely used in the fields...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06M13/292D06M15/61D06M11/28D06M11/65D06M101/06
CPCD06M11/28D06M11/65D06M13/292D06M15/61D06M2101/06D06M2200/30
Inventor 卢明樊涛刘一萍赵振云胡睿敏
Owner SOUTHWEST UNIV
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