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A kind of medium and trace element compound fertilizer containing vitamin B and preparation method thereof

A technology of medium and trace elements and compound fertilizers, applied in the direction of organic fertilizers, fertilizer mixtures, fertilization devices, etc.

Active Publication Date: 2020-03-24
HENAN JIENONG BIOLOGICAL & CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there is some research on compound micronutrient fertilizers containing medium and trace elements needed for plant growth. Chelating agents are used to perform chelation reactions with various trace elements, and the obtained chelated trace element fertilizers can increase the yield of crops, but with only Increased crop yields are not enough to meet real demand for vegetables and fruits

Method used

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  • A kind of medium and trace element compound fertilizer containing vitamin B and preparation method thereof
  • A kind of medium and trace element compound fertilizer containing vitamin B and preparation method thereof
  • A kind of medium and trace element compound fertilizer containing vitamin B and preparation method thereof

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preparation example Construction

[0111] Another aspect of the present invention provides a kind of preparation method containing the trace element compound fertilizer of vitamin B, described method comprises the steps:

[0112] (1) immerse chitosan oligosaccharides with a weight average molecular weight of 3000 to 50000 in parts by weight in 2V 2vt% acetic acid solution and 2V 5wt% hydrogen peroxide solution;

[0113] (2) piperazine diketo acid is dissolved in 10V methanol by weight, then added to the chitosan oligosaccharide solution obtained in the step (1), to obtain a reaction solution;

[0114] (3) filter the reaction solution obtained in the step (2) with 10wt% NaOH aqueous solution to adjust the pH to be neutral, soak, wash, filter and dry the retentate;

[0115] (4) disperse the oligomeric chitosan piperazine diketone amide synthesized in the step (3) in acetone, add 20wt% NaOH aqueous solution, carry out alkalization, then add abscisic acid and salicylic acid in batches by weight , carry out the gra...

Embodiment 1

[0124](1) Piperazine diketo acid grafted on oligochitosan

[0125] In a 1000ml three-necked bottle, add 50g of chitosan oligosaccharides with a weight average molecular weight of 20000, 100ml of 2vt% acetic acid solution, 100ml of 5wt% hydrogen peroxide solution, stir, completely dissolve and then keep warm at 55°C for 5h; the reaction is over Finally, add piperazine diketopic acid (1g) dissolved in 10ml of methanol, stir and react at room temperature for 12h to obtain a reaction solution; adjust the pH of the reaction solution to neutral with 10wt% NaOH aqueous solution, filter, and soak in 200ml of acetone 10h, washed with 50ml of acetone, filtered, and dried under reduced pressure at 40°C for 12h.

[0126] (2) Grafting abscisic acid and salicylic acid on chitosan oligosaccharide modified with piperazinone diacid

[0127] In a 1000ml three-necked bottle, add synthetic oligomeric chitosan piperazine diketone amide, 300ml acetone, 100ml 20wt% NaOH aqueous solution, alkalinize...

Embodiment 2~6

[0132] The preparation method is the same as in Example 1, except that the types of vitamin B are different;

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Abstract

The invention provides a medium trace element compound fertilizer containing vitamin B.The medium trace element compound fertilizer is characterized by at least being prepared from, by weight, 0.1-2 parts of EDTA chelated copper, 3-10 parts of EDTA chelated zinc, 1-7 parts of EDTA chelated iron, 1-6 parts of EDTA chelated manganese, 1-5 parts of EDTA chelated magnesium, 2-8 parts of sodium borate, 2-10 parts of vitamin B, 1-20 parts of diethylaminoethyl hexanoate DA-6 and 3-12 parts of modified chitooligosaccharide.The medium trace element compound fertilizer containing vitamin B has high cold resisting and disease resisting capability, has a significant effect on etiolation caused by medium trace element deficiency of plants and can increase the nutritional ingredients and yield of crops; besides, according to a preparation method of the fertilizer, operation is easy, and the operation environment is safe.

Description

technical field [0001] The invention belongs to the field of agricultural planting, and more specifically, the invention relates to a compound fertilizer of medium and trace elements containing vitamin B and a preparation method thereof. Background technique [0002] Medium and trace elements play an extremely important role in plant growth. Trace elements refer to a chemical element with a very low content in nature. Some trace elements have biological significance and are necessary for the normal growth and life of plants and animals. Trace elements are in The functions in plants and animals have strong specificity, which are indispensable and irreplaceable. When the supply is insufficient, plants often show specific symptoms of deficiency. For example, the lack of trace elements in the process of plant growth will cause plant yellowing , the crop yield is reduced, the quality is reduced, and in serious cases, the yield may be lost, and the application of medium and trace ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C05G3/00C05G3/60
CPCC05D9/02C05G3/00C05F11/00C05F11/10
Inventor 张晓东
Owner HENAN JIENONG BIOLOGICAL & CHEM CO LTD