Biomass oil suitable for modifying thermosetting resin and preparation method thereof

A biomass oil and thermosetting technology, which is applied in the treatment of hydrocarbon oil, petroleum industry, liquid carbon-containing fuel, etc., can solve the problems of complex operation, high cost, harsh reaction conditions, etc., and achieve simple preparation method, low production cost, and high reaction The effect of mild conditions

Active Publication Date: 2016-08-17
四川景文材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method requires high cost, and the conditions for rapid heating to above 500°C depend on

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A kind of biomass oil suitable for thermosetting resin modification described in this embodiment is made of the following raw materials in parts by weight: 250 parts of biomass briquettes, 400 parts of reaction medium A (methanol), 80 parts of reaction medium B (ethyl acetate), 12 parts of catalyst C (phenolsulfonic acid), 4 parts of catalyst D (phosphoric acid), and 5 parts of neutralizing agent (sodium hydroxide).

[0028] The preparation method of above-mentioned biomass oil comprises the following steps:

[0029] (1) Feeding: After the airtightness of the reactor is checked, add reaction medium A and reaction medium B respectively, raise the temperature to 45-50°C, and the heating rate is 5-6°C / 10min; then add catalyst C, catalyst D, and heat up To 60-65°C, the heating rate is 5-6°C / 10min; under the condition of stirring, put the biomass briquettes into the reactor, control the adding time within 1-1.5h, after the feeding is completed, seal the feeder of the reactor...

Embodiment 2

[0034] A kind of biomass oil suitable for thermosetting resin modification described in this embodiment differs from Example 1 in that: the biomass oil is made of the following raw materials in parts by weight: 250 parts of biomass briquettes, reacted 350 parts of medium A (ethanol), 80 parts of reaction medium B (acetone), 12 parts of catalyst C (p-toluenesulfonic acid), 4 parts of catalyst D (sulfuric acid), and 5 parts of neutralizing agent (barium hydroxide).

[0035] The index test results of the above-mentioned biomass oil are: the yield of biomass oil is 81.7%, the color is dark brown, the average molecular weight Mn is 753, and the softening point is 71°C. It can be used to modify phenolic resin, epoxy resin, amino resin, etc.

Embodiment 3

[0037] A kind of biomass oil suitable for thermosetting resin modification described in this embodiment differs from Example 1 in that: the biomass oil is made of the following raw materials in parts by weight: 250 parts of biomass briquettes, reacted 400 parts of medium A (including 200 parts of methanol and 200 parts of butanol), 80 parts of reaction medium B (toluene), 12 parts of catalyst C (benzenesulfonic acid), 4 parts of catalyst D (sulfuric acid), and 5 parts of neutralizer (ammonia) share.

[0038] The index test results of the above-mentioned biomass oil are: the yield of biomass oil is 78.6%, the color is dark brown, the average molecular weight Mn is 794, and the softening point is 79°C. It can be used to modify phenolic resin, epoxy resin, amino resin, etc.

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Abstract

The invention discloses biomass oil suitable for modifying thermosetting resin and a preparation method thereof. The biomass oil is prepared from the following raw materials in parts by weight: 150-350 parts of biomass briquette, 280-520 parts of reaction medium A, 30-120 parts of reaction medium B, 5-20 parts of catalyst C, 2-8 parts of catalyst D and 2-9 parts of neutralizing agent, wherein the reaction medium A is one or more of methanol, ethanol, butanol and glycerin; the reaction medium B is one or more of ethyl acetate, acetone, toluene and petroleum ether; the catalyst C is one or more of phenolsulfonic acid, p-toluenesulfonic acid, benzenesulfonic acid, phenyl phosphate and salicylic acid; the catalyst D is one or more of inorganic acids; and the biomass oil is prepared by the steps of charging, heating for reacting, cooling, separation and distillation. With relatively good quality indexes, the biomass oil does not need secondary processing and can be directly applied to the modification of thermosetting resin; and moreover, the preparation method is simple, the reaction conditions are mild, and the production cost is reduced.

Description

technical field [0001] The invention relates to the technical field of biomass oil and its production, in particular to a biomass oil suitable for thermosetting resin modification and a preparation method thereof. Background technique [0002] Biomass oil is a mixture of water and complex oxygenated organic matter, that is, a mixture of various degradation products of cellulose, hemicellulose and lignin. Its initial market positioning is to replace heavy oil, diesel and coal tar. Biomass oil can be directly burned as fuel, and can be used as fuel for oil-fired boilers and industrial kilns; secondly, after refined processing, it can replace No. 0 diesel as fuel for internal combustion engines; thirdly, it can be used as chemical raw materials to extract or process various chemical products such as agent, food seasoning, desulfurization and degumming agent, organic fertilizer, glycolaldehyde, levoglucosan, etc. [0003] The existing biomass oil preparation method usually ado...

Claims

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Application Information

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IPC IPC(8): C08L61/06C08L63/00C08L61/20C08L91/00C10L1/00
CPCC08L61/06C08L61/20C08L63/00C10G2300/1011C10L1/00C08L91/00
Inventor 曹海波王兴财
Owner 四川景文材料科技有限公司
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