Novel low-temperature insulation and thermal insulation pre-impregnated fiber cloth and preparation method thereof

A low-temperature insulation and pre-impregnation technology, which is applied in the field of pre-impregnated fiber cloth, can solve the problems of high material brittleness, difficulty in meeting the requirements of low-temperature engineering applications, and easy cracking, and achieve low porosity, controllable resin content, and heat release. little effect

Inactive Publication Date: 2016-10-26
TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, in low temperature environment, conventional resin-based prepregs have some problems, especially in ultra-low temperature environment, such as liquid helium temperature zone, liquid hydrogen temperature zone, etc., the material is brittle and easy to crack, so that it is difficult to meet the requirements. Requirements for cryogenic engineering applications
At present, there is no localized low-temperature pre-impregnated fiber cloth product on the market

Method used

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  • Novel low-temperature insulation and thermal insulation pre-impregnated fiber cloth and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Pre-impregnated fiber cloth for low-temperature insulation and heat insulation is made of ultra-high-strength glass fiber cloth impregnated with epoxy resin slurry. The epoxy resin slurry is composed of epoxy resin and phenolic epoxy resin mixture, modified epoxy resin and double A mixture of cyanamide and accelerators. Taking the total amount of epoxy resin slurry as the base, the amount of epoxy resin and novolac epoxy resin mixture is 81.4wt%, the amount of modified epoxy resin is 9.0wt%, and dicyandiamide accounts for 7.2wt%. The used amount of agent is 2.3wt%.

[0032] The preparation method of the low-temperature insulation heat insulation pre-impregnated fiber cloth of the present embodiment comprises the following steps:

[0033] (1): Pour 90g of bisphenol A epoxy resin and novolac epoxy resin mixture (weight ratio 1:1) into an adjustable speed disperser, add 10g of modified epoxy resin, stir at 60°C for 30min, and then add The mixture of 8g dicyandiamide and ...

Embodiment 2

[0038] Pre-impregnated fiber cloth for low-temperature insulation and heat insulation is made of ultra-high-strength glass fiber cloth impregnated with epoxy resin slurry. The epoxy resin slurry is composed of epoxy resin and phenolic epoxy resin mixture, modified epoxy resin and double The mixture of cyanamide and accelerator is mixed, wherein the amount of epoxy resin and novolac epoxy resin mixture is 75wt%, the amount of modified epoxy resin is 12wt%, surfactant 2wt%, flame retardant 1wt%, Dicyandiamide accounts for 8.2wt%, and the amount of accelerator used is 1.8wt%.

[0039] The preparation method of the low-temperature insulation heat insulation pre-impregnated fiber cloth of the present embodiment comprises the following steps:

[0040] (1): Pour 100g of bisphenol A epoxy resin and bisphenol F type epoxy resin mixture (weight ratio 1:1) into an adjustable speed disperser, add 16g of modified epoxy resin, 2.6g of surfactant and 1.3g of flame retardant, stirred at 60°C...

Embodiment 3

[0045]Pre-impregnated fiber cloth for low-temperature insulation and heat insulation is made of ultra-high-strength glass fiber cloth impregnated with epoxy resin slurry. The epoxy resin slurry is a mixture of epoxy resin and novolac epoxy resin (weight ratio 1:1), A mixture of modified epoxy resin, dicyandiamide and accelerator is mixed, wherein the amount of epoxy resin and novolac epoxy resin mixture is 80wt%, the modified epoxy resin is 8wt%, and the surfactant is 5wt%. %, flame retardant 1wt%, the amount of dicyandiamide used is 5wt%, and the amount of accelerator used is 1wt%. The content of epoxy resin slurry in the pre-impregnated fiber cloth is 55%. The accelerator uses 1,1-dimethyl-3-phenylurea. The preparation method of the low-temperature insulating and heat-insulating pre-impregnated fiber cloth described in this example is the same as that of Example 1, and will not be described in this example.

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Abstract

The invention relates to a novel low-temperature insulation and thermal insulation pre-impregnated fiber cloth. The novel low-temperature insulation and thermal insulation pre-impregnated fiber cloth is obtained by impregnating 45 wt%-65 wt% of glass fiber cloth in 35 wt%-55 wt% of epoxy resin sizing agent; the epoxy resin sizing agent is prepared from 85 wt%-95 wt% of epoxy resin mixture, 5 wt%-15 wt% of modified latent curing agent mixture, 70 wt%-90 wt% of epoxy resin, 5 wt%-25 wt% of modified epoxy resin flexibilizer, 0 wt%-10 wt% of surfactant, 0 wt%-5 wt% of flame retardant, 4.5 wt%-12 wt% of latent curing agent and 0.5 wt%-3 wt% of accelerator. The invention further discloses a preparation method of the novel low-temperature insulation and thermal insulation pre-impregnated fiber cloth. The obtained material is not prone to cracking, and the requirement of low-temperature engineering can be met.

Description

technical field [0001] The invention relates to a pre-impregnated fiber cloth, in particular to a novel low-temperature insulating and heat-insulating pre-impregnated fiber cloth and a preparation method thereof. Background technique [0002] Pre-impregnated fiber material is mainly composed of resin matrix and fiber fabric, and has become a kind of intermediate material widely used in the design and manufacturing process of fiber-reinforced composite materials. [0003] Chinese patent CN 103497349B discloses a precured glass fiber cloth impregnating material and its preparation method, which consists of a glass fiber cloth coated with an adhesive through a gluing machine and baked through a gluing machine oven; the adhesive consists of 1000 parts by mass It is composed of benzoxazine-maleamide resin solution, 15-30 parts by mass of linear isophthalic unsaturated polyester, 0.2-2 parts by mass of accelerator, and 0.1-0.3 parts by mass of initiator. The preparation method in...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B17/04B32B17/10B32B7/06B32B29/02C08L63/00C08L63/04
CPCB32B5/02B32B27/10B32B29/02B32B2260/021B32B2260/046B32B2262/101B32B2307/206B32B2307/304C08L63/00C08L63/04
Inventor 李来风应建明吴智雄陈皮伟李文丹
Owner TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI
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