Novel ceramic ink-jet ink and production process thereof

A ceramic inkjet and ink technology, which is applied in the field of architectural ceramic decoration, can solve the problems of particle agglomeration and low stability, unstable surface tension of ink, and low solubility of ceramic powder, etc. Color and stable effect

Inactive Publication Date: 2016-10-26
佛山市理想家科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Traditional ceramic ink is usually composed of ceramic powder, solvent, dispersant, binder, surfactant and auxiliary materials. Ceramic powder is the core of the ink, and its particle size is required to be less than 1 micron, which requires ball milling and high energy consumption. The solubility of ceramic powder is small, the surface tension of the ink is unstable, and the viscosity changes greatly. Usually, there are problems that the particles are easy to agglomerate and have low stability, and are greatly affected by other substances such as solvents. Spray on the surface of the tiles, due to the poor permeability, you can still feel the pattern texture protruding on the surface of the tiles, which affects the fidelity; in addition, ceramic products generally need to be fired at a high temperature of more than 1,000 degrees, and the ink on the surface is usually affected. High temperature affects the color effect, it is difficult to meet the requirements of high temperature firing, and the hardness of fired tiles is low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Embodiment 1-a kind of production technology of ceramic ink-jet ink, comprises the steps:

[0044] (1) Weigh 38% of the soluble metal salt and 60% of the water-soluble organic solvent to dissolve it, put it into the reaction kettle for heating reaction, and filter the residue after cooling;

[0045] Wherein: the soluble metal salt is a combination of copper sulfate, copper acetate and copper nitrate; the water-soluble organic solvent is ethanol, accounting for 29% of the ink solution; the auxiliary material accounts for 1% of the ink solution.

[0046] (2) Add dispersant to the reaction kettle in step (1), and add 0.05% pH regulator to adjust the pH value to 7;

[0047] (3) Put the remaining 40% water-soluble organic solvents and additives into the reaction solution for reaction;

[0048] (4) After completely dissolving and reacting, cool, filter with 350 mesh and 800 mesh respectively, and fill to obtain blue ceramic inkjet ink.

[0049] The ceramic inkjet ink prepar...

Embodiment 2

[0065] Embodiment 2-a kind of production technology of novel ceramic ink-jet ink, comprises the steps:

[0066] (1) Weigh 40% of soluble metal salt, 14% of surfactant and 9% of complexing agent in proportion, dissolve them with 40% of water-soluble organic solvent, put them into the reaction kettle for heating reaction, After cooling, the residue was removed by filtration;

[0067] Wherein: the soluble metal salt is a combination of chromium sulfate, chromium acetate and chromium chloride; the surfactant is dodecylphenyl acid; the complexing agent is sodium sulfate and EDTA; the water-soluble organic solvent is Ethanol and butanol account for 32% of the ink solution; excipients account for 2% of the ink solution.

[0068] (2) Add dispersant to the reaction kettle in step (1), and add 0.06% pH regulator to adjust the pH value to 7;

[0069] (3) Put the remaining 60% water-soluble organic solvents and additives into the reaction solution for reaction;

[0070] (4) After compl...

Embodiment 3

[0072] Embodiment 3 A kind of production technology of novel ceramic ink-jet ink, comprises the steps:

[0073] (1) Weigh 42% of soluble metal salt, 14% of surfactant and 8% of complexing agent in proportion, dissolve them with 50% of water-soluble organic solvent, put them into the reaction kettle for heating reaction, After cooling, the residue was removed by filtration;

[0074] Wherein: the soluble metal salt is a combination of zinc sulfate, zinc acetate and zinc chloride; the surfactant is sodium citrate and ammonium citrate; the complexing agent is potassium phosphate and caustic soda; the water-soluble organic solvent It is butanol, accounting for 30% of the ink solution; auxiliary materials account for 3% of the ink solution.

[0075] (2) Add dispersant to the reaction kettle in step (1), and add 0.08% pH regulator to adjust the pH value to 7;

[0076] (3) Put the remaining 50% water-soluble organic solvents and additives into the reaction solution for reaction;

...

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Abstract

The invention relates to a novel ceramic ink-jet ink and a production process thereof. The novel ceramic ink-jet ink is prepared from the following components by percentage by weight: 38%-42% of water-soluble metal salt, 7%-9% of a complexing agent, 14%-25% of a surfactant, 29%-34% of a water-soluble organic solvent, 1%-4% of an auxiliary material and 0.05%-0.1% of a pH value regulator. The novel ceramic ink-jet ink has strong stability, the influences caused by other substances such as solvents are small, the solubility range is relatively wide, the liquidity and the color development property are stable, and the pH value is neutral, so that the corrosion damage caused to a spray head is avoided; the novel ceramic ink-jet ink can directly infiltrate by 5mm-10mm into a tile blank, infiltration color development is formed, and the infiltration effect is good; the color development effect of metal salt is rich and stable, and after novel ceramic ink-jet ink infiltrates into the surface of a tile, the color is relatively fine and bright; the novel ceramic ink-jet ink can be subjected to 1260 DEG C high-temperature sintering with the tile blank, can meet the high-temperature sintering requirements of the tile blank and can reach Moh's hardness 6-7, and the hardness is obviously improved; lots of water grinding fineness processes are not required, the machining process is relatively environmentally friendly, and the energy consumption is relatively low.

Description

technical field [0001] The invention relates to the technical field of architectural ceramic decoration, in particular to a novel ceramic ink-jet ink and a production process thereof. Background technique [0002] Traditional ceramic inkjet is a kind of ceramic inkjet ink made of ceramic pigment powder into multicolor. The ceramic inkjet ink is ejected as small ink droplets from nozzles with a diameter of tens of microns at a speed of thousands of drops per second. The technique of depositing on the green body, glaze or other carrier can be single color or multi-color combination. Inkjet printing technology has been widely used, and its application mainly has the following two aspects: ceramic product decoration and ceramic forming; ceramic product decoration is to make ceramic colorant into multi-color ink, and print it on the ceramic surface through a computer-controlled printer For decoration, its advantage lies in the use of computer resources to realize the change of d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/30C09D11/36C09D11/38
CPCC09D11/30C09D11/36C09D11/38
Inventor 杜林伟
Owner 佛山市理想家科技有限公司
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