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Preparation of extreme pressure anti-wearing additive and energy-saving environmental-friendly engine oil containing same

An extreme pressure anti-wear agent, energy saving and environmental protection technology, applied in additives, petroleum industry, lubricating composition, etc., can solve problems such as redox catalyst poisoning failure, catalyst poisoning, reduced catalytic effect, etc., to achieve good wear resistance, Good bearing capacity and extreme pressure resistance, the effect of improving wear resistance

Active Publication Date: 2016-11-09
SHANDONG YUANGEN PETROLEUM CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Due to the setting of exhaust emission requirements, it directly promotes the development of engine hardware technology. The development and changes of these hardware directly put forward new requirements for lubricating oil. The use of some metal elements that are easy to generate ash, such as Zn, has been limited; the redox device requires reducing the sulfur content, because sulfur is easy to poison the redox catalyst and fail, and because the engine burns lubricating oil, the sulfur content of lubricating oil The higher it is, the more carbon deposits will be burned, and the more sulfur-containing substances will be emitted; devices such as NOx removal devices, three-way catalysis, and selective reduction catalysis are also required to reduce the content of sulfur and phosphorus, because phosphorus will affect the three-way catalytic conversion. The impact of the catalyst poisons the catalyst, thereby reducing the catalytic effect. At the same time, through the analysis of the combustion products adhering to the valve, it is found that its main component is Ca 3 (PO 4 ) 2 , it is not only the product of gasoline engine combustion, which is a component of engine lubricating oil, but these combustion products often cause abnormal combustion such as surface ignition

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] This embodiment provides a preparation method of an extreme pressure antiwear agent, and an energy-saving and environment-friendly engine oil containing the extreme pressure antiwear agent.

[0031] A preparation method of an extreme pressure antiwear agent, specifically comprising the following steps:

[0032] a. Dissolve 60g of lanthanum bromide in distilled water and stir until clear liquid;

[0033] b. Add dropwise an ethanol solution containing 160g of graphene modified by polymerized ionic liquids and 30g of sodium carbonate under vigorous stirring, the solution is immediately white and turbid, reacted at constant temperature for 1h, and the reaction is complete;

[0034] c. Set aside for sedimentation, filter, wash with distilled water for several times, and then wash with absolute ethanol for 10 times;

[0035] d. Finally, wash with potassium tetrafluoroborate aqueous solution for 10 times, carry out particle exchange, dry the sample, and grind it finely for la...

Embodiment 2

[0038] This embodiment provides a preparation method of an extreme pressure antiwear agent, and an energy-saving and environment-friendly engine oil containing the extreme pressure antiwear agent.

[0039] A preparation method of an extreme pressure antiwear agent, specifically comprising the following steps:

[0040] a. Dissolve 65g of lanthanum bromide in distilled water and stir until clear liquid;

[0041] b. Add dropwise an ethanol solution containing 170g of graphene modified by polymerized ionic liquids and 35g of sodium carbonate under vigorous stirring, the solution is immediately white and turbid, and reacted at constant temperature for 2 hours, and the reaction is complete;

[0042] c. Set aside to settle, filter, wash with distilled water for several times, and then wash with absolute ethanol for 15 times;

[0043] d. Finally, wash with potassium tetrafluoroborate aqueous solution for 12 times, carry out particle exchange, dry the sample, and grind it finely for l...

Embodiment 3

[0046] This embodiment provides a preparation method of an extreme pressure antiwear agent, and an energy-saving and environment-friendly engine oil containing the extreme pressure antiwear agent.

[0047] A preparation method of an extreme pressure antiwear agent, specifically comprising the following steps:

[0048] a. Dissolve 70g of lanthanum bromide in distilled water and stir until clear liquid;

[0049] b. Add dropwise an ethanol solution containing 180g of graphene modified by polymerized ionic liquids and 40g of sodium carbonate under vigorous stirring, the solution is immediately white and turbid, reacted at constant temperature for 3 hours, and the reaction is complete;

[0050] c. Set aside for sedimentation, filter, wash with distilled water several times for precipitation, and then wash 20 times with absolute ethanol;

[0051] d. Finally, wash with potassium tetrafluoroborate aqueous solution for 15 times, carry out particle exchange, dry the sample, and grind it ...

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Abstract

The invention belongs to the field of engine lubricants, and relates to preparation of an extreme pressure anti-wearing additive and energy-saving environmental-friendly engine oil containing same. Preparation of the extreme pressure anti-wearing additive comprises the following steps: dissolving lanthanum bromide into distilled water, stirring till a clear and transparent liquid, dropping an ethanol solution containing polymeric ionic liquid modified graphene and sodium carbonate drop by drop under violent stirring, then the solution can be white and muddy immediately, implementing constant-temperature reaction, after reaction is completed, leaving to stand and precipitate, filtering, washing the precipitate for multiple times with distilled water, further washing for multiple times with absolute ethyl alcohol, finally washing for multiple times with a potassium tetrafluoroborate solution, implementing particle exchange, drying so as to obtain a sample, and grinding for later use. The energy-saving environmental-friendly engine oil containing the extreme pressure anti-wearing additive comprises basic oil, an anti-wearing agent, the extreme pressure anti-wearing additive, a high-temperature antioxidant, a clearing agent, a dispersing agent, a viscosity index improver, and the like. The engine oil designed from the extreme pressure anti-wearing additive is relatively good in bearing capability and extreme pressure anti-wearing property, and is relatively good in environmental-friendliness.

Description

technical field [0001] The invention belongs to the field of engine lubricants, and in particular relates to the preparation of an extreme pressure antiwear agent and energy-saving and environment-friendly engine oil containing the extreme pressure antiwear agent. Background technique [0002] Lubricating grease is one of the important supporting materials for modern transportation, modern industry and national defense industry. However, according to the survey of the United Nations Environmental Protection Organization, 50% of the air pollution in large and medium-sized cities comes from the exhaust emissions of fuel vehicles. Therefore, how to effectively control vehicle exhaust Emissions, to prevent the recurrence of the national heavy smog in early 2013, is the key to protecting the atmospheric environment on which we live. [0003] As we all know, automobile exhaust emissions contain many substances harmful to the ecological environment and human health, such as CO 2 ,...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M125/26C10M169/04C10N30/06C10N30/12
CPCC10M125/02C10M125/10C10M125/26C10M169/04C10M2201/041C10M2201/062C10M2201/087C10M2201/14C10N2030/06C10N2030/12
Inventor 何茂伟袁俊洲徐金玲乔良
Owner SHANDONG YUANGEN PETROLEUM CHEM
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