Ni-Zn high-strength cupronickel alloy and preparing method thereof

A high-strength, white copper technology, applied in the field of copper wire processing, can solve the problems of not being able to achieve handicrafts, lower the quality of castings, and swelling of the riser, and achieve the effect of good elasticity, less impurities and beautiful appearance

Inactive Publication Date: 2016-11-09
WUHU CHUJIANG ALLOY COPPER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this process solves the problem of oxygen absorption in the smelting process of cupronickel, when the hydrogen changes from a solid phase to a liquid phase (melting point 1080°C), there is a sudden change in the amount of hydrogen dissolved, resulting in a large amount of hydrogen absorption; on the contrary, when the temperature drops to 1080°C, the hydrogen There is also a sudden change in the solubility in copper liquid, which decreases sharply. During the slow solidification process, precipitated pores are formed, which are pinholes. The quality of castings is reduced. The white copper material is easy to absorb oxygen during smelting, and the cast castings are prone to pore defects. Therefore, the ordinary smelting process cannot meet the requirements of handicrafts.

Method used

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Examples

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preparation example Construction

[0034] A preparation method of nickel-zinc high-strength copper-nickel alloy includes the following steps:

[0035] S1: Weigh 22~38 parts of Ni, 30~35 parts of Zn and copper into the smelting furnace, add manganese dioxide as an oxidant and mix, then melt at a temperature of 1200-1400°C, and the melting time is 2 to 4 hours Obtain molten metal;

[0036] S2: Weigh 20-30 parts of Mn, 12-18 parts of P, 4-7 parts of Fe, and 5-15 parts of Al into the melting furnace of molten metal obtained in step S1, and continue to heat to 1430°C-1660°C, Prepare alloy solution;

[0037] S3: The alloy solution obtained in step S2 is added to the deoxidizer phosphor-copper alloy for deoxidation, and finally a liquid cupronickel alloy is formed for pouring.

[0038] The melting temperature of the step S1 is 1300° C., and the melting time is 3 hours.

[0039] The melting temperature of the step S2 is 1500°C.

[0040] The phosphor-copper alloy in the step S3 is CuP12 or CuP14.

Embodiment 1

[0042] S1: Weigh 22 parts of Ni, 35 parts of Zn and copper into the smelting furnace, add manganese dioxide as an oxidant and mix, then melt at a temperature of 1400°C, and the melting time is 4 hours to obtain molten metal;

[0043] S2: Weigh 30 parts of Mn, 18 parts of P, 4 parts of Fe, and 15 parts of Al into the melting furnace of the molten metal obtained in step S1, and continue to heat to 1430°C to obtain an alloy solution;

[0044] S3: Add the alloy solution obtained in step S2 to the deoxidizer phosphor-copper alloy for deoxidation, and finally form a liquid cupronickel alloy for pouring.

Embodiment 2

[0046] S1: Weigh 22 parts of Ni, 30 parts of Zn and copper into the smelting furnace, add manganese dioxide as an oxidant and mix, then melt at a temperature of 1400°C, and the melting time is 2 hours to obtain molten metal;

[0047] S2: Weigh 30 parts of Mn, 18 parts of P, 7 parts of Fe, and 15 parts of Al into the melting furnace of the molten metal obtained in step S1, and continue heating to 1430°C to obtain an alloy solution;

[0048] S3: The alloy solution obtained in step S2 is added to the deoxidizer phosphor-copper alloy for deoxidation, and finally a liquid cupronickel alloy is formed for pouring.

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PUM

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Abstract

The invention discloses Ni-Zn high-strength cupronickel alloy and a preparing method thereof. The Ni-Zn high-strength cupronickel alloy is prepared from, by weight, 20-40 parts of Ni, 30-35 parts of Zn, 20-30 parts of Mn, 12-18 parts of P, 4-7 parts of Fe, 5-15 parts of Al and the balance Cu. The performance of the cupronickel alloy is higher, tensile strength and corrosion resistance can better meet the requirement of artware, the specific color intensity and hardness of cupronickel alloy can be maintained for artware produced in the later stage, and environment friendliness is higher and daily use requirements of people are better met. The cupronickel alloy contains zinc which can be dissolved in copper nickel in a solid state to generate a solution strengthening effect, and corrosion resistance is also realized. The cupronickel alloy has high strength and corrosion resistance, high elasticity, attractive appearance and low price, and cost can be saved.

Description

Technical field [0001] The invention relates to the field of copper wire processing, in particular to a nickel-zinc high-strength copper-nickel alloy and a preparation method thereof. Background technique [0002] Cupro-nickel alloy is a copper alloy with nickel as the main additive element. Its color is beautiful and mild silver-white, with good ductility and corrosion resistance. Generally, iron, lead and other elements are generally added to the composition of cupronickel alloys in the prior art in order to enhance corrosion resistance and formability. Cupronickel is mostly used for corrosion-resistant industrial parts, but there are few cupronickel alloys suitable for artistic casting and forming processes. [0003] Due to the contact with people, the alloying elements of art castings need to be safe and environmentally friendly, and require simple composition, lead-free and other heavy metal alloying elements. The existing white copper contains many metal materials such as ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/04C22C9/06C22C9/05C22C1/02C22C1/06
CPCC22C9/04C22C1/02C22C1/06C22C9/05C22C9/06
Inventor 吴明辉王权李丽兴谢道金狄风雨蒋云才李云飞黄景彪
Owner WUHU CHUJIANG ALLOY COPPER
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