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MnO2-ACF material for removing indoor formaldehyde and preparation method thereof

A technology of formaldehyde and activated carbon fiber, which is applied in the field of MnO2-ACF materials and its preparation, can solve the problems of small adsorbent capacity, catalyst failure, and low conversion efficiency, and achieve simple preparation process, developed microporous structure, and large adsorption capacity. Effect

Active Publication Date: 2016-11-23
南京尚易环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The adsorption method is often unable to effectively remove low-concentration pollutants due to the small capacity of the adsorbent and the non-selectivity of the adsorption, and the desorption is easy to cause secondary pollution; the photocatalytic method needs to be carried out under low ultraviolet light conditions, and has a considerable application limitations, and the conversion efficiency is low; noble metal catalysts are prone to catalyst poisoning, which makes the catalyst invalid, and due to the scarcity and high price of precious metal resources, its promotion and application in room temperature catalytic oxidation formaldehyde removal catalysts are limited. Therefore, whether it is adsorption Neither photocatalysis nor noble metal catalysis can achieve satisfactory results.

Method used

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  • MnO2-ACF material for removing indoor formaldehyde and preparation method thereof
  • MnO2-ACF material for removing indoor formaldehyde and preparation method thereof
  • MnO2-ACF material for removing indoor formaldehyde and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0023] like figure 1 Shown, the MnO of the present invention 2 -ACF material is prepared by the following steps:

[0024] (1) 6.5 parts of KMnO 4 , 5.0 parts of NaOH, 1.2 parts of polyvinylpyrrolidone dissolved in 230 parts of pure water, stirred until KMnO 4 , NaOH and polyvinylpyrrolidone were completely dissolved to prepare mixed solution A; under stirring condition, the above mixed solution A was added dropwise by 7.8 parts MnSO 4 ·H 2 MnSO prepared by dissolving O in 260 parts of pure water 4 In the solution, after the dropwise addition, the reaction was continued for 1 hour to obtain a tan slurry B;

[0025] (2) Activated carbon fiber (ACF) is pretreated. The pretreatment process includes: immersing the ACF mat in 500ml ethanol, ultrasonic cleaning for 10min, taking out the ACF and cleaning it with 1000ml deionized water for 3 times, and then immersing the ACF in 500ml with a concentration of In 6% nitric acid solution, ultrasonically clean for 10 minutes, take out...

Embodiment 2

[0030] The basic steps are the same as in Example 1, except that the shaking time in step (3) is 30 minutes.

[0031] This example makes MnO 2 - MnO of ACF material 2 The loading rate is 10%, and the degradation rate of formaldehyde is 79.6% for indoor low-concentration formaldehyde treatment for 100 minutes.

Embodiment 3

[0033] MnO of the present invention 2 -ACF material is prepared by the following steps:

[0034] (1) 6.5 parts of KMnO 4 , 5.0 parts of NaOH, 1.2 parts of polyvinylpyrrolidone, 0.5 parts of hexadecylamine dissolved in 230 parts of pure water, stirred until KMnO 4 , NaOH, polyvinylpyrrolidone and hexadecylamine are completely dissolved to prepare a mixed solution A; under stirring conditions, the above mixed solution A is added dropwise by 7.8 parts of MnSO 4 ·H 2 MnSO prepared by dissolving O in 260 parts of pure water 4 In the solution, after the dropwise addition, the reaction was continued for 1 hour to obtain a tan slurry B;

[0035] (2) The activated carbon fiber (ACF) is pretreated first. The pretreatment process includes: soaking the ACF felt in 500ml ethanol, ultrasonic cleaning for 12min, taking out the ACF and washing it with 1000ml deionized water for 3 times, and then immersing the ACF in a concentration of 500ml In a 4% nitric acid solution, ultrasonically cl...

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Abstract

The invention discloses an MnO2-ACF material for removing indoor formaldehyde and a preparation method thereof. The material comprises carrier active carbon fiber and MnO2 loaded on the surface of a carrier. The preparation method of the MnO2-ACF material comprises the following steps of firstly dissolving KMnO4, alkaline substances, dispersing agents and template agents into water to prepare a mixed solution; then, dripping the mixed solution into a manganese salt solution; performing reaction to prepare a mixture; finally, soaking the active carbon fiber into the mixture; performing oscillation, washing, drying, calcination and cooling; preparing the MnO2-ACF material. The MnO2-ACF material has the advantages that the MnO2-ACF material provided by the invention can be used for efficiently removing low-concentration formaldehyde contaminants in a room; the stability is high; the service life is long; the cost is low; the repeated use can be achieved; meanwhile, the preparation process is simple; the operation is safe; the cost is lower.

Description

technical field [0001] The invention belongs to the field of preparation of air purification materials, in particular to a kind of MnO used for removing indoor formaldehyde 2 - ACF materials and methods for their preparation. Background technique [0002] Formaldehyde is a serious hazard to human health. It ranks second on the priority list of toxic chemicals in my country and has been identified as a Class I carcinogen by the World Health Organization (WHO) and the International Agency for Research on Cancer (IARC). The problem of indoor formaldehyde pollution has aroused great concern from all walks of life. Studies have shown that short-term exposure to formaldehyde can irritate the eyes, nasal cavity and respiratory tract and cause allergic reactions. Long-term exposure to low-dose formaldehyde can easily increase the possibility of nasopharyngeal cancer, leukemia and death. The "Indoor Air Quality Standard" (part B / T 18883-2002) promulgated by China stipulates that th...

Claims

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Application Information

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IPC IPC(8): B01J20/20B01J23/34B01D53/86B01D53/72
CPCB01D53/02B01D53/8668B01J20/20B01J23/34
Inventor 孙丽媛陈毛毛石俊峰
Owner 南京尚易环保科技有限公司
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