Hydrogenation preprocessing method for coal tar raw material

A hydrogenation pretreatment and coal tar technology, which is applied in the fields of hydrogenation treatment process, hydrocarbon oil treatment, petroleum industry, etc., can solve the problems of affecting the operation cycle of the device, not considering the removal of metals, and the increase of bed pressure drop, etc., to achieve The effect of long operation period of the device, extended operation period and excellent properties

Active Publication Date: 2016-11-23
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, coal tar raw material is introduced into the raw material of this method, and the inventor only considered how to solve the coking problem of coal tar and coking distillate oil, and did not consider the removal of metals, etc., resulting in the deposition of metals in the feedstock on the catalyst bed , so that the pressure drop of the bed layer rises too fast, which affects the extension of the operating cycle of the device
[0006] Therefore, how to overcome the defect of using the above-mentioned prior art to process coal tar raw materials, and provide a method for processing coal tar with a simple process and a long device operation period on the basis of low energy consumption to provide a clean fuel with high yield and excellent properties is Key research objectives of researchers in this field

Method used

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  • Hydrogenation preprocessing method for coal tar raw material

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Effect test

Embodiment 1

[0091] With the coal tar raw material to be pretreated in Table 1 as the raw material, it enters the degassing tower and the dehydration tower successively after being filtered by a primary filter, and obtains the coal tar raw material after dehydration, wherein, in the coal tar raw material after the dehydration The dissolved oxygen content is 0.45 μL / L, and the water content is 260 μg / g; then it is sequentially combined with the hydrogenation protection catalyst in the first prehydrogenation reactor and the hydrogenation protection catalyst in the second prehydrogenation reactor and deasphaltene Catalyst contact reaction, the reaction effluent is separated by the post-separation system to separate the water generated by the reaction, the hydrogen-rich cycle gas, and the liquid-phase hydrocarbon effluent, and the liquid-phase hydrocarbon stream enters the stripping tower to remove hydrogen sulfide and ammonia, etc. , the stripper bottom effluent is the pretreated coal tar acco...

Embodiment 2

[0100] With the coal tar raw material to be pretreated in Table 1 as the raw material, it enters the degassing tower and the dehydration tower successively after being filtered by a primary filter, and obtains the coal tar raw material after dehydration, wherein, in the coal tar raw material after the dehydration The dissolved oxygen content is 0.4 μL / L, and the water content is 240 μg / g; then it is sequentially combined with the hydrogenation protection catalyst in the first prehydrogenation reactor and the hydrogenation protection catalyst in the second prehydrogenation reactor and deasphaltene Catalyst contact reaction, the reaction effluent is separated by the post-separation system to separate the water generated by the reaction, the hydrogen-rich cycle gas, and the liquid-phase hydrocarbon effluent, and the liquid-phase hydrocarbon stream enters the stripping tower to remove hydrogen sulfide and ammonia, etc. , the stripper bottom effluent is the pretreated coal tar accor...

Embodiment 3

[0109] With the coal tar raw material to be pretreated in Table 1 as the raw material, it enters the degassing tower and the dehydration tower successively after being filtered by a primary filter, and obtains the coal tar raw material after dehydration, wherein, in the coal tar raw material after the dehydration The dissolved oxygen content is 0.48 μL / L, and the water content is 270 μg / g; then it is sequentially combined with the hydrogenation protection catalyst in the first prehydrogenation reactor and the hydrogenation protection catalyst in the second prehydrogenation reactor and deasphaltene Catalyst contact reaction, the reaction effluent is separated by the post-separation system to separate the water generated by the reaction, the hydrogen-rich cycle gas, and the liquid-phase hydrocarbon effluent, and the liquid-phase hydrocarbon stream enters the stripping tower to remove hydrogen sulfide and ammonia, etc. , the stripper bottom effluent is the pretreated coal tar acco...

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Abstract

The invention relates to the field of coal tar processing, and discloses a hydrogenation preprocessing method for a coal tar raw material. The method is implemented in a reaction system comprising a first prehydrogenation reaction region and a second prehydrogenation reaction region and includes the steps that 1, the coal tar raw material to be preprocessed is sequentially degassed and dehydrated to obtain the dehydrated coal tar raw material, wherein the content of dissolved oxygen in the dehydrated coal tar raw material is smaller than 1 microliter / liter, and the content of water is smaller than 500 microgram / gram; 2, in the presence of hydrogen, the dehydrated coal tar raw material sequentially enters the first prehydrogenation reaction region and the second prehydrogenation reaction region. When the method is adopted to process coal tar, the use ratio of a hydrogenation protecting catalyst in the coal tar processing technical process can be remarkably increased, and the method has the advantages of low energy consumption, the simple technology, a long device operation cycle, the high product yield and good characteristics.

Description

technical field [0001] The invention relates to the field of coal tar processing, in particular to a method for hydrogenation pretreatment of coal tar raw materials. Background technique [0002] With the sustained and rapid development of social economy, my country's demand for petroleum products is also increasing. However, petroleum is a non-renewable energy source and is facing a crisis of depletion. In contrast, China has relatively abundant coal reserves, so producing liquid fuel from coal has become a basic direction of coal processing and utilization. [0003] With the rapid growth of the international and domestic steel industry, the coking industry presents a high growth trend, the output of coal tar is increasing, and the clean processing and effective utilization of coal tar are becoming more and more important. At present, the conventional processing method is to cut various fractions with concentrated components through pretreatment distillation, and then use...

Claims

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Application Information

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IPC IPC(8): C10G67/02
Inventor 李猛吴昊高晓冬胡大为孙淑玲何跃
Owner CHINA PETROLEUM & CHEM CORP
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