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Low-burning-temperature and high-burning-rate solid propellant and preparation method thereof

A technology of solid propellant and burning rate, which is applied to attack equipment, compressed gas generation, etc., can solve the problems of no major improvement in the combustion performance of solid propellant, reduction of gas production rate of solid propellant, slowing down of fire extinguishing agent injection, etc. Achieve the effect of superior combustion performance, mature production process, and lower combustion rate pressure index

Active Publication Date: 2016-12-07
HEFEI KESIFU SAFETY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Too fast a burning rate may lead to uncontrolled combustion of the solid propellant in the reactor of the fire extinguishing device, even reaching deflagration, which brings danger to the use of personnel and equipment in the protected space; too low a burning rate will make the solid propellant The gas production rate is greatly reduced, which slows down the injection of fire extinguishing agent and weakens the fire extinguishing efficiency
At present, although there are some reports on improving the combustion performance of solid propellants, they have not been able to effectively increase the burning rate and enhance combustion stability while reducing the combustion temperature, and the process is relatively complicated, which does not greatly improve the combustion performance of solid propellants.

Method used

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  • Low-burning-temperature and high-burning-rate solid propellant and preparation method thereof
  • Low-burning-temperature and high-burning-rate solid propellant and preparation method thereof
  • Low-burning-temperature and high-burning-rate solid propellant and preparation method thereof

Examples

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Effect test

Embodiment 1

[0041] A low burning temperature and high burning rate solid propellant proposed by the present invention, its raw materials include: 31% of 5-aminotetrazole of 100 mesh or more, 3% of modified nano metal oxide with an average particle size of less than 100nm , 0.5% plasticizer, and the balance is greater than or equal to 100 mesh strontium nitrate.

[0042]The preparation method of the modified nanometer metal oxide is as follows: paraffin is used as a solvent and stearic acid is used as a modifier, and the nanometer metal oxide is subjected to ball milling dispersion modification.

[0043] The preparation method of the above-mentioned low-burning-temperature high-burning-velocity solid propellant proposed by the present invention comprises the following steps:

[0044] S1. Add 5-aminotetrazole, strontium nitrate, burning rate modifier, and absolute ethanol into a ball mill for ball milling, and then vacuum remove the solvent to obtain the first material;

[0045] S2. Add th...

Embodiment 2

[0049] A low burning temperature and high burning rate solid propellant proposed by the present invention, its raw materials include: 37% of 5-aminotetrazole of 100 mesh or more, 1% of modified nano metal oxide with an average particle size of less than 100nm , 0.5% of bis(2-ethylhexyl) adipate, 0.5% of isophorone diisocyanate, and the balance is greater than or equal to 100 mesh strontium nitrate.

[0050] The preparation method of the modified nanometer metal oxide is as follows: paraffin is used as a solvent and stearic acid is used as a modifier, and the nanometer metal oxide is subjected to ball milling dispersion modification.

[0051] The preparation method of the above-mentioned low-burning-temperature high-burning-velocity solid propellant proposed by the present invention comprises the following steps:

[0052] S1. Add 5-aminotetrazole, strontium nitrate, modified nano-metal oxides, and absolute ethanol into the ball mill for 20 hours. The speed of the ball mill is 1...

Embodiment 3

[0057] A low burning temperature and high burning rate solid propellant proposed by the present invention, its raw materials include: 35.8% of 100 mesh 5-aminotetrazole, 62.2% of 100 mesh strontium nitrate, and modified nano Iron oxide 1%, bis(2-ethylhexyl) adipate 0.5%, isophorone diisocyanate plasticizer 0.5%.

[0058] The preparation method of the modified nano-iron oxide is as follows: using paraffin as a solvent and stearic acid as a modifier, the nano-iron oxide is modified by ball milling dispersion.

[0059] The preparation method of the above-mentioned low-burning-temperature high-burning-velocity solid propellant proposed by the present invention comprises the following steps:

[0060] S1. Add 17.9g of 5-aminotetrazole, 31.1g of strontium nitrate, 0.5g of modified nano-iron oxide, and 50g of absolute ethanol into the ball mill for 18 hours. The speed of the ball mill is 180r / min, and the ratio of materials to balls is 1. : 4, the charge of material is 1 / 3 of the cap...

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Abstract

The invention discloses a low-burning-temperature and high-burning-rate solid propellant which comprises the following raw materials in percentage by weight: 31-37 percent of 5-amino tetrazole, 60-66 percent of strontium nitrate, 1-3 percent of a burning rate modifier and 0.5-1 percent of a plasticizer. The invention further discloses a preparation method of the low-burning-temperature and high-burning-rate solid propellant. The preparation method comprises the following steps: performing wet ball-milling by taking the 5-amino tetrazole and the strontium nitrate as raw materials and taking modified nanometer metal oxide as the burning rate modifier, removing a solvent, grinding, forming through mold pressing and then drying till constant weight. The low-burning temperature and high-burning rate solid propellant disclosed by the invention has the benefits that the burning performance of the solid propellant is greatly improved, the preparation process is simple, the operation is easy, the obtained solid propellant is low in burning temperature, high in burning rate, low in burning rate pressure index, low in decomposition temperature and good in thermal stability, a combustion product has good slagability, and the effect of the low-burning temperature and high-burning rate solid propellant is superior to that of a conventional 5-amino tetrazole solid propellant.

Description

technical field [0001] The invention relates to the technical field of solid propellants, in particular to a solid propellant with low burning temperature and high burning rate and a preparation method thereof. Background technique [0002] At present, halon fire extinguishing agent is the most widely used, and has the advantages of high fire extinguishing efficiency, no residue after fire extinguishing, low toxicity, and good diffusion performance. However, the product halon produced by it is more destructive to the ozone layer, which limits the use of halon fire extinguishing agent. The "Montreal Protocol on the Depletion of the Ozone Layer" is a global agreement on the specific control of substances that deplete the ozone layer. According to this convention, my country has expressly stipulated that the production of various halon fire extinguishing agents has been stopped since January 1, 2010. After the signing of the "Montreal Protocol" and other international conventi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C06D5/06
CPCC06D5/06
Inventor 张丹陆松曹承阳
Owner HEFEI KESIFU SAFETY TECH
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