Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Low-temperature lithium battery electrolyte

A low-temperature lithium battery and electrolyte technology, used in secondary batteries, circuits, electrical components, etc., can solve the problems of poor conductivity, poor low temperature performance, poor conductivity, etc., to reduce impedance, excellent performance, and improve conduction speed. Effect

Active Publication Date: 2016-12-07
HEFEI HENGNENG NEW ENERGY TECH
View PDF4 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the low-temperature performance of lithium-ion batteries is relatively poor at present, especially in low-temperature environments below -30°C.
[0003] The existing lithium battery electrolyte is mainly composed of organic solvents and lithium salts, which have poor conductivity, especially in low temperature environments, and have relatively high impedance in low temperature environments.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Low-temperature lithium battery electrolyte
  • Low-temperature lithium battery electrolyte

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Dissolve 1.1g lithium tetrafluoroborate, 12.1g lithium hexafluorophosphate, 1.2g fluoroethylene carbonate and 0.9g vinylene carbonate in 84.7g organic solvent (30.9g ethylene carbonate, 40.2g methyl ethyl carbonate, 9.6g propylene carbonate Esters, 4g of diethyl carbonate), mixed evenly to make electrolyte.

Embodiment 2

[0017] Dissolve 0.7g lithium tetrafluoroborate, 12.2g lithium hexafluorophosphate, 1.4g fluoroethylene carbonate and 0.4g vinylene carbonate in 85.3g organic solvent (30.7g ethylene carbonate, 40.8g methyl ethyl carbonate, 9.9g propylene carbonate Esters, 3.9g diethyl carbonate), and mix uniformly to make electrolyte solution.

Embodiment 3

[0019] Dissolve 0.5g lithium tetrafluoroborate, 13.6g lithium hexafluorophosphate, 2.3g fluoroethylene carbonate and 0.7g vinylene carbonate in 83.0g organic solvent (30.1g ethylene carbonate, 40.8g methyl ethyl carbonate, 9.0g propylene carbonate Esters, 3.1g diethyl carbonate), and mix uniformly to make electrolyte solution.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention belongs to the field of a lithium battery, and discloses a low-temperature lithium battery electrolyte. The low-temperature lithium battery electrolyte comprises an organic solvent, a lithium salt and an additive, wherein the mass ratio of the organic solvent to the lithium salt to the additive is 78-90 to 11.5-15.5 to 1.3-3.7; and the lithium salt of an original low-temperature lithium battery electrolyte only comprises lithium hexafluorophosphate. A small amount of lithium tetrafluoroborate is added to the lithium salt of the low-temperature lithium battery electrolyte provided by the invention; the conductive effect of the lithium tetrafluoroborate is better than that of the lithium hexafluorophosphate, and the addition proportion does not affect the low-temperature performance of the lithium salt; in addition, fluoroethylene carbonate is additionally added to perform a synergistic effect with vinylene carbonate, thereby improving a film-forming effect of the lithium battery, lowering impedance, improving the conduction velocity of electrons and ions at a low temperature, and improving the low-temperature cycle performance of the lithium ion battery; and furthermore, the mass ratios of the components are selected preferably, so that the performance of the electrolyte is more excellent.

Description

technical field [0001] The invention belongs to the field of lithium batteries, in particular to an electrolyte solution for a low-temperature lithium battery. Background technique [0002] Lithium batteries have the characteristics of high nominal voltage, high specific energy, long cycle life, no memory effect, etc., and are environmentally friendly and pollution-free. Therefore, they are widely used in digital products such as mobile phones, notebook computers, and MP3s. At the same time, they are used in electric vehicles, Electric bicycles, national defense equipment and other industries are also widely used. In recent years, lithium batteries have been used more and more widely in various fields. The environment in which batteries are used is complex, and the performance requirements for batteries are also higher. Even at low temperatures, the device can be started quickly. However, the low-temperature performance of lithium-ion batteries is relatively poor at presen...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0567H01M10/0568H01M10/0525
CPCH01M10/0525H01M10/0567H01M10/0568Y02E60/10
Inventor 刘欣武玉哲朱炜宏杨天刘琦白思宇周皖岳
Owner HEFEI HENGNENG NEW ENERGY TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products