High-barrier composite food packaging film and preparation method thereof
A composite food, high barrier technology, applied in the direction of packaging, wrapping paper, wrapping paper, etc., can solve the problems of poor mechanical strength of composite packaging film, limit the use of composite packaging film, puncture, etc.
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[0013] The invention provides a method for preparing a high-barrier composite food packaging film, comprising:
[0014] 1) Extruding starch, white carbon black, methylcellulose, carbon nanotubes and water to obtain puffed products;
[0015] 2) Mix PP (polypropylene), PVAL (polyvinyl alcohol), n-butyl methacrylate, white oil, lactic acid, rare earth oxides, tea polyphenols, globulin and puffed products to obtain a mixed product;
[0016] 3) The paper substrate is roughened, and then the coupling agent is coated on the surface of the paper substrate to form a coupling layer, and then the kneaded material is coated on the surface of the coupling layer to form a protective layer, and finally dried to produce High barrier composite food packaging film.
[0017] In step 1) of the present invention, the specific conditions of the puffing treatment can be selected within a wide range, but in order to further improve the excellent mechanical properties of the prepared high-barrier com...
Embodiment 1
[0031] 1) Starch, white carbon black, methyl cellulose, carbon nanotubes (with a particle size of 20nm) and water are puffed at 80°C for 13 hours at a weight ratio of 100:12:2:0.7:180 to obtain puffed products ;
[0032] 2) Mix PP, PVAL, n-butyl methacrylate, white oil, lactic acid, lanthanum oxide, tea polyphenols, globulin and puffed products according to the ratio of 100:58:37:14:20:5:1.4:7:35 Mixing at 190°C for 10 hours by weight to obtain a kneaded product;
[0033] 3) The paper substrate (vellum, thickness 10 silk) is roughened until the surface roughness is 3-8Ra, and the coupling agent KH550 is coated on the surface of the paper substrate to form a coupling layer (thickness 0.2 silk). Cover the surface of the coupling layer to form a protective layer (thickness is 0.7 silk), and finally dry (from 25°C to 55°C at a rate of 2°C / min and hold for 3 hours, then at a rate of 0.7°C / min to 78 ℃ and keep warm for 11h) to prepare high barrier composite food packaging film A1....
Embodiment 2
[0035] 1) Starch, white carbon black, methylcellulose, carbon nanotubes (with a particle size of 10nm) and water are puffed at 70°C for 10 hours at a weight ratio of 100:10:1:0.5:150 to obtain puffed products ;
[0036] 2) Mix PP, PVAL, n-butyl methacrylate, white oil, lactic acid, rubidium oxide, tea polyphenols, globulin and puffed products according to the ratio of 100:45:35:9:14:3:1.1:5:30 Mixing at 185°C for 8 hours by weight to obtain a mixture;
[0037] 3) The paper substrate (jute paper, thickness 5 filaments) is roughened until the surface roughness is 3Ra, and the coupling agent KH560 is coated on the surface of the paper substrate to form a coupling layer (thickness 0.1 filaments). On the surface of the coupling layer to form a protective layer (thickness of 0.5 silk), and finally dry (from 20°C at a rate of 1°C / min to 50°C and keep it for 2 hours, then at a rate of 0.5°C / min to 75°C and heat preservation for 9 hours) to prepare high barrier composite food packagi...
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