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Polystyrene microsphere composite material for laser sintering molding and preparation method thereof

A polystyrene microsphere, laser sintering molding technology, applied in the direction of additive processing, etc., can solve the problems of poor material uniformity, complex preparation process, low mechanical strength, etc., achieve fast molding speed, simple preparation process, high mechanical strength Effect

Inactive Publication Date: 2017-03-08
HEFEI GENIUS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Engineering plastic powder is a commonly used plastic powder material in laser sintering molding technology, among which nylon powder is the majority. During the preparation process, the material needs to be dissolved in an organic solvent first, and then undergo crystallization, grinding and screening. The preparation process is complicated and there are It is toxic to a certain extent and pollutes the environment. In addition, the homogeneity of the obtained material is poor, the performance is seriously reduced compared with that before powderization, and there are deficiencies such as low mechanical strength.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0043] (1) Add the required raw materials into the container one by one and mix thoroughly:

[0044] 100 parts of polystyrene microspheres,

[0045] 5 parts of nanometer nitrile rubber,

[0046] Toughening agent triglycidyl isocyanurate 0.1 part,

[0047] Light stabilizer benzotriazole chloride 0.1 part,

[0048] 0.5 part of defoamer ethylene oxide propylene oxide copolyether,

[0049] Leveling agent organosilicon-propylene oxide copolymer 0.5 parts,

[0050] 0.04 parts of antioxidant N,N'-bis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hexamethylenediamine,

[0051] 0.06 parts of antioxidant tris[2.4-di-tert-butylphenyl]phosphite.

[0052] (2) Stir the mixed material at high speed for 10 minutes at 50°C until it is evenly dispersed;

[0053] (3) Form the above materials into required parts through laser sintering rapid prototyping equipment, and test related properties.

[0054] The properties of the composite materials obtained are shown in Table 1.

example 2

[0056] (1) Add the required raw materials into the container one by one and mix thoroughly:

[0057] 100 parts of polystyrene microspheres,

[0058] 15 parts of nanometer nitrile rubber,

[0059] Toughening agent triglycidyl isocyanurate 0.2 part,

[0060] 0.2 parts of light stabilizer benzotriazole chloride,

[0061] 1.5 parts of defoaming agent ethylene oxide propylene oxide copolyether,

[0062] Leveling agent silicone-propylene oxide copolymer 1.5 parts,

[0063] 0.08 parts of antioxidant N,N'-bis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hexamethylenediamine,

[0064] Antioxidant tris [2.4-di-tert-butylphenyl] phosphite 0.12 parts.

[0065] (2) Stir the mixed material at high speed for 15 minutes at 60°C until it is evenly dispersed;

[0066] (3) Form the above materials into required parts through laser sintering rapid prototyping equipment, and test related properties.

[0067] The properties of the composite materials obtained are shown in Table 1.

example 3

[0069] (1) Add the required raw materials into the container one by one and mix thoroughly:

[0070] 100 parts of polystyrene microspheres,

[0071] 25 parts of nanometer nitrile rubber,

[0072] Toughening agent triglycidyl isocyanurate 0.3 part,

[0073] 0.3 part of light stabilizer benzotriazole chloride,

[0074]2.5 parts of defoaming agent ethylene oxide propylene oxide copolyether,

[0075] Leveling agent silicone-propylene oxide copolymer 2.5 parts,

[0076] 0.12 parts of antioxidant N,N'-bis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hexamethylenediamine,

[0077] 0.18 parts of antioxidant tris[2.4-di-tert-butylphenyl]phosphite.

[0078] (2) The mixed material is stirred at a high speed for 20 minutes at 70°C until it is evenly dispersed;

[0079] (3) Form the above materials into required parts through laser sintering rapid prototyping equipment, and test related properties.

[0080] The properties of the composite materials obtained are shown in Table 1. ...

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Abstract

The invention discloses a polystyrene microsphere composite material for laser sintering molding and a preparation method thereof, and belongs to the field of polystyrene microsphere laser sintering molding modification. The polystyrene microsphere composite material for laser sintering molding is prepared from the following raw materials in parts by weight: 100 parts of polystyrene microspheres, 5-45 parts of nano butadiene-acrylonitrile rubber, 0.1-0.5 part of a toughening agent, 0.1-0.5 part of a light stabilizer, 0.5-4.5 parts of a defoaming agent, 0.5-4.5 parts of a leveling agent, and 0.1-0.5 part of an antioxidant. The composite material prepared by the preparation method disclosed by the invention has the characteristics of high mechanical strength, good wear resistance and high molding speed; and meanwhile, the introduction of the nano butadiene-acrylonitrile rubber greatly reduces the comprehensive cost of the composite material. Moreover, the composite material disclosed by the invention has a simple preparation process, and can be applied and promoted on a large scale in the field of laser sintering molding.

Description

technical field [0001] The invention provides a polystyrene microsphere composite material for laser sintering molding and a preparation method thereof, belonging to the field of laser sintering molding modification of polystyrene microspheres. Background technique [0002] Laser sintering molding technology, also known as burning powder molding technology, is a rapid prototyping technology that uses laser to sinter powder materials, and completes the stacking of three-dimensional parts through the process from point to surface and from surface to body. The commonly used materials for laser sintering molding technology are powdered plastics, ceramics or metals. During the molding process, the powder materials are first melted and sintered by laser, and then the process from plane to three-dimensional is completed by adjusting the working components, and finally finished with certain functionality or appearance. Sexual three-dimensional artifacts. [0003] Engineering plasti...

Claims

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Application Information

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IPC IPC(8): C08L25/06C08L9/02C08K5/00C08K5/3492C08K5/3475C08K5/07C08K5/18C08K5/526C08K5/524B29C67/24B33Y70/00
Inventor 杨桂生李枭姚晨光
Owner HEFEI GENIUS NEW MATERIALS