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Modified starch ethylene-vinyl acetate composite foaming agent wear resistant sole material

A technology of vinyl acetate and composite foaming agent, which is applied in the field of shoe sole materials, can solve problems such as application limitations and heavy weight, and achieve the effects of improving compatibility, improving light weight, and increasing wear resistance

Inactive Publication Date: 2017-03-22
WUXI CHANGAN SHUGUANG GLOVE FACTORY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although alloy particles increase the wear resistance of the sole, their weight is relatively large, which is contrary to the goal of lightweighting the shoe, so its application is greatly restricted

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A kind of starch ethylene-vinyl acetate composite foaming agent shoe sole material, comprises by weight

[0023] Ethylene-vinyl acetate 100

[0024] Modified starch 30

[0025] Polyimide resin 10

[0026] Ethylene-acrylic acid copolymer 10

[0027] Glycerin Plasticizer 4

[0028] Tungsten carbide-cobalt cemented carbide particles 2.

[0029] The preparation method of described modified starch is as follows:

[0030] Dissolve starch in water, heat to 85°C, gelatinize for 20 minutes, then cool to below 60°C, add ammonium persulfate initiator, then add vinyl acetate monomer, react at 60°C for 5 hours, add absolute ethanol for precipitation , filtered, and dried to obtain grafted modified starch.

Embodiment 2

[0032] A kind of starch ethylene-vinyl acetate composite foaming agent shoe sole material, comprises by weight

[0033] Ethylene-vinyl acetate 100

[0034] Modified starch 50

[0035] Polyimide resin 30

[0036] Ethylene-acrylic acid copolymer 30

[0037] Graphene Fiber 10

[0038] Inorganic filler 30

[0039] Glycerin Plasticizer 12

[0040] Tungsten carbide-cobalt cemented carbide particles 5.

[0041] The preparation method of described modified starch is as follows:

[0042] Dissolve starch in water, heat to 95°C, gelatinize for 40 minutes, then cool to below 60°C, add ammonium persulfate initiator, then add vinyl acetate monomer, react at 80°C for 5 hours, add absolute ethanol for precipitation , filtered, and dried to obtain grafted modified starch.

Embodiment 3

[0044] A kind of starch ethylene-vinyl acetate composite foaming agent shoe sole material, comprises by weight

[0045] Ethylene-vinyl acetate 100

[0046] Modified starch 40

[0047] Polyimide resin 20

[0048] Ethylene-acrylic acid copolymer 20

[0049] Graphene fibers 5

[0050] Inorganic filler 20

[0051] Glycerin plasticizer 8

[0052] Tungsten carbide-cobalt cemented carbide particles 3.

[0053] The preparation method of modified starch of the present invention is as follows:

[0054] Dissolve starch in water, heat to 90°C, gelatinize for 30 minutes, then cool to below 60°C, add ammonium persulfate initiator, then add vinyl acetate monomer, react at 70°C for 3 hours, add absolute ethanol for precipitation , filtered, and dried to obtain grafted modified starch.

[0055] The shoe sole material described in Examples 1-3, after being prepared into a shoe sole, its wear resistance is greatly improved, and its density is at least 0.085g / cm 3 , even without using gr...

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Abstract

The invention discloses a starch ethylene-vinyl acetate composite foaming agent wear resistant sole material. The material is prepared from, by weight, 100 parts of ethylene-vinyl acetate, 30-50 parts of modified starch, 10-30 parts of polyimide resin, 10-30 parts of ethylene-acrylic acid polymer, 0-10 parts of graphene fiber, 0-30 parts of inorganic filler, 4-12 parts of glycerin plasticizer and 2-5 parts of tungsten carbide-cobalt cemented carbide particles. The preparing method of the modified starch comprises the steps of dissolving starch into water, carrying out heating to 85-95 DEG C, carrying out gelatinization for 20-40 min, afterwards cooling to 60 DEG C or below, adding ammonium persulfate initiator, then adding vinyl acetate monomer, carrying out a reaction at 60-80 DEG C for 1-5 hours, adding absolute ethyl alcohol for precipitation, carrying out filtration, and carrying out drying to obtain the modified starch. The sole material has a minimum density of 0.085 g / cm<3> after being prepared into a sole; even if the graphene fiber is not adopted, the tensile strength of the sole material reaches 25 kg / cm<2>, the elasticity is over 54%, and tear strength is over 29 kg / cm; the sole material can improve a wear-resisting property and achieve light weight at the same time.

Description

technical field [0001] The invention relates to the technical field of shoe sole materials, in particular to a modified starch ethylene-vinyl acetate composite foaming agent wear-resistant shoe sole material. Background technique [0002] The structure of the sole is quite complex. In a broad sense, it can include all the materials that make up the bottom, such as the outsole, midsole and heel. In a narrow sense, it only refers to the outsole. The common characteristics of general sole materials should be wear-resistant, water-resistant, oil-resistant, heat-resistant, pressure-resistant, impact-resistant, good elasticity, easy to fit the shape of the foot, and not easy to change after being shaped. Heat preservation, easy to absorb moisture, etc., and at the same time, it must cooperate with the midsole, which has a braking effect when walking and changing feet, so that it will not slip and is easy to stop. There are many types of sole materials, which can be divided into n...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L51/02C08L79/08C08K13/04C08K7/06C08K5/053C08K3/14C08K3/08C08F251/00C08F218/08A43B13/04
CPCA43B13/04C08F251/00C08L23/0853C08L2203/14C08L2205/035C08L51/02C08L79/08C08L23/0869C08K13/04C08K7/06C08K5/053C08K3/14C08K2003/0843C08F218/08
Inventor 缪建良
Owner WUXI CHANGAN SHUGUANG GLOVE FACTORY