Modified starch ethylene-vinyl acetate composite foaming agent wear resistant sole material
A technology of vinyl acetate and composite foaming agent, which is applied in the field of shoe sole materials, can solve problems such as application limitations and heavy weight, and achieve the effects of improving compatibility, improving light weight, and increasing wear resistance
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Embodiment 1
[0022] A kind of starch ethylene-vinyl acetate composite foaming agent shoe sole material, comprises by weight
[0023] Ethylene-vinyl acetate 100
[0024] Modified starch 30
[0025] Polyimide resin 10
[0026] Ethylene-acrylic acid copolymer 10
[0027] Glycerin Plasticizer 4
[0028] Tungsten carbide-cobalt cemented carbide particles 2.
[0029] The preparation method of described modified starch is as follows:
[0030] Dissolve starch in water, heat to 85°C, gelatinize for 20 minutes, then cool to below 60°C, add ammonium persulfate initiator, then add vinyl acetate monomer, react at 60°C for 5 hours, add absolute ethanol for precipitation , filtered, and dried to obtain grafted modified starch.
Embodiment 2
[0032] A kind of starch ethylene-vinyl acetate composite foaming agent shoe sole material, comprises by weight
[0033] Ethylene-vinyl acetate 100
[0034] Modified starch 50
[0035] Polyimide resin 30
[0036] Ethylene-acrylic acid copolymer 30
[0038] Inorganic filler 30
[0039] Glycerin Plasticizer 12
[0040] Tungsten carbide-cobalt cemented carbide particles 5.
[0041] The preparation method of described modified starch is as follows:
[0042] Dissolve starch in water, heat to 95°C, gelatinize for 40 minutes, then cool to below 60°C, add ammonium persulfate initiator, then add vinyl acetate monomer, react at 80°C for 5 hours, add absolute ethanol for precipitation , filtered, and dried to obtain grafted modified starch.
Embodiment 3
[0044] A kind of starch ethylene-vinyl acetate composite foaming agent shoe sole material, comprises by weight
[0045] Ethylene-vinyl acetate 100
[0046] Modified starch 40
[0047] Polyimide resin 20
[0048] Ethylene-acrylic acid copolymer 20
[0049] Graphene fibers 5
[0050] Inorganic filler 20
[0051] Glycerin plasticizer 8
[0052] Tungsten carbide-cobalt cemented carbide particles 3.
[0053] The preparation method of modified starch of the present invention is as follows:
[0054] Dissolve starch in water, heat to 90°C, gelatinize for 30 minutes, then cool to below 60°C, add ammonium persulfate initiator, then add vinyl acetate monomer, react at 70°C for 3 hours, add absolute ethanol for precipitation , filtered, and dried to obtain grafted modified starch.
[0055] The shoe sole material described in Examples 1-3, after being prepared into a shoe sole, its wear resistance is greatly improved, and its density is at least 0.085g / cm 3 , even without using gr...
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Abstract
Description
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Application Information
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