Silicon-zirconium composite super-hydrophilic abrasion-resistant coating
A wear-resistant coating and silicon-zirconium composite technology, applied in the coating field, can solve the problems of wear resistance, scratch resistance, anti-fingerprint, poor stain resistance, short service life of super-hydrophilic coating, low coating hardness, etc. problems, to achieve the effects of good water resistance and weather resistance, good anti-fog performance, and high pollution resistance
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Embodiment 1
[0035] The silicon-zirconium composite super-hydrophilic wear-resistant coating of the present invention comprises the following components by weight: 10 grams of single-layer zirconium hydrogen phosphate, 30 grams of silica sol containing sulfonic acid groups, and 30 grams of silane coupling agent , 50 grams of alcohol solvent. Wherein, the silane coupling agent is methyltriethoxysilane, and the alcohol solvent is ethanol.
[0036] The single-layer zirconium hydrogen phosphate is prepared by the following method: 20 grams of α-zirconium hydrogen phosphate is ultrasonically peeled off with 100 ml of 0.1 mol / liter propylamine solution, and 110 ml of 0.1 mol / liter hydrochloric acid is added to replace and remove the propylamine, and then water Excess hydrochloric acid was washed alternately with ethanol to obtain monolayer zirconium hydrogen phosphate.
[0037] The preparation method of the silica sol containing sulfonic acid group is: 40 grams of nano-scale silica sol are stir...
Embodiment 2
[0044]The silicon-zirconium composite super-hydrophilic wear-resistant coating of the present invention comprises the following components by weight: 30 grams of single-layer zirconium hydrogen phosphate, 50 grams of silica sol containing sulfonic acid groups, and 25 grams of silane coupling agent , 60 grams of alcohol solvent. Wherein, the silane coupling agent is a mixture of γ-mercaptopropyl tetraethoxysilane and γ-mercaptopropyl tetramethoxysilane in a mass ratio of 1:1, and the alcohol solvent is isopropanol.
[0045] Single-layer zirconium hydrogen phosphate is prepared by the following method: 40 grams of α-zirconium hydrogen phosphate is ultrasonically peeled off with 300 milliliters of 0.1 mol / liter propylamine solution, and 280 milliliters of 0.1 mol / liter hydrochloric acid is added to replace and remove propylamine, and then water Excess hydrochloric acid was washed alternately with ethanol to obtain monolayer zirconium hydrogen phosphate.
[0046] The preparation ...
Embodiment 3
[0054] The silicon-zirconium composite super-hydrophilic wear-resistant coating of the present invention comprises the following components by weight: 5 grams of single-layer zirconium hydrogen phosphate, 10 grams of silica sol containing sulfonic acid groups, and 20 grams of silane coupling agent , 30 grams of alcohol solvent. Wherein, the silane coupling agent is γ-mercaptopropylmethyltrimethoxysilane, and the alcohol solvent is propylene glycol methyl ether acetate.
[0055] The single-layer zirconium hydrogen phosphate is prepared by the following method: 10 grams of α-zirconium hydrogen phosphate is ultrasonically peeled off with 200 ml of 0.1 mol / liter propylamine solution, and 120 ml of 0.1 mol / liter hydrochloric acid is added to replace and remove the propylamine, and then water Excess hydrochloric acid was washed alternately with ethanol to obtain monolayer zirconium hydrogen phosphate.
[0056] The preparation method of the silica sol containing sulfonic acid group ...
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