Silicon-zirconium composite super-hydrophilic abrasion-resistant coating

A wear-resistant coating and silicon-zirconium composite technology, applied in the coating field, can solve the problems of wear resistance, scratch resistance, anti-fingerprint, poor stain resistance, short service life of super-hydrophilic coating, low coating hardness, etc. problems, to achieve the effects of good water resistance and weather resistance, good anti-fog performance, and high pollution resistance

Active Publication Date: 2017-03-22
GUANGDONG BINHAO TRAVELWARE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current commercialized superhydrophilic anti-fog coatings are mainly pure polymer material systems. The hydrophilic groups that play a superhydrophilic role in this material are connected to the main chain of the polymer, which makes the water resistance of this coating poor. , resulting in a short service life and poor weather resistance of the super-hydrophilic coating
At the same time, the hardness of the coating prepared by this coating is also low, and the wear resistance, scratch resistance, anti-fingerprint, and stain resistance are relatively poor.

Method used

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  • Silicon-zirconium composite super-hydrophilic abrasion-resistant coating
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  • Silicon-zirconium composite super-hydrophilic abrasion-resistant coating

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] The silicon-zirconium composite super-hydrophilic wear-resistant coating of the present invention comprises the following components by weight: 10 grams of single-layer zirconium hydrogen phosphate, 30 grams of silica sol containing sulfonic acid groups, and 30 grams of silane coupling agent , 50 grams of alcohol solvent. Wherein, the silane coupling agent is methyltriethoxysilane, and the alcohol solvent is ethanol.

[0036] The single-layer zirconium hydrogen phosphate is prepared by the following method: 20 grams of α-zirconium hydrogen phosphate is ultrasonically peeled off with 100 ml of 0.1 mol / liter propylamine solution, and 110 ml of 0.1 mol / liter hydrochloric acid is added to replace and remove the propylamine, and then water Excess hydrochloric acid was washed alternately with ethanol to obtain monolayer zirconium hydrogen phosphate.

[0037] The preparation method of the silica sol containing sulfonic acid group is: 40 grams of nano-scale silica sol are stir...

Embodiment 2

[0044]The silicon-zirconium composite super-hydrophilic wear-resistant coating of the present invention comprises the following components by weight: 30 grams of single-layer zirconium hydrogen phosphate, 50 grams of silica sol containing sulfonic acid groups, and 25 grams of silane coupling agent , 60 grams of alcohol solvent. Wherein, the silane coupling agent is a mixture of γ-mercaptopropyl tetraethoxysilane and γ-mercaptopropyl tetramethoxysilane in a mass ratio of 1:1, and the alcohol solvent is isopropanol.

[0045] Single-layer zirconium hydrogen phosphate is prepared by the following method: 40 grams of α-zirconium hydrogen phosphate is ultrasonically peeled off with 300 milliliters of 0.1 mol / liter propylamine solution, and 280 milliliters of 0.1 mol / liter hydrochloric acid is added to replace and remove propylamine, and then water Excess hydrochloric acid was washed alternately with ethanol to obtain monolayer zirconium hydrogen phosphate.

[0046] The preparation ...

Embodiment 3

[0054] The silicon-zirconium composite super-hydrophilic wear-resistant coating of the present invention comprises the following components by weight: 5 grams of single-layer zirconium hydrogen phosphate, 10 grams of silica sol containing sulfonic acid groups, and 20 grams of silane coupling agent , 30 grams of alcohol solvent. Wherein, the silane coupling agent is γ-mercaptopropylmethyltrimethoxysilane, and the alcohol solvent is propylene glycol methyl ether acetate.

[0055] The single-layer zirconium hydrogen phosphate is prepared by the following method: 10 grams of α-zirconium hydrogen phosphate is ultrasonically peeled off with 200 ml of 0.1 mol / liter propylamine solution, and 120 ml of 0.1 mol / liter hydrochloric acid is added to replace and remove the propylamine, and then water Excess hydrochloric acid was washed alternately with ethanol to obtain monolayer zirconium hydrogen phosphate.

[0056] The preparation method of the silica sol containing sulfonic acid group ...

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Abstract

The invention relates to a silicon-zirconium composite super-hydrophilic abrasion-resistant coating. The silicon-zirconium composite super-hydrophilic abrasion-resistant coating comprises the following components in parts by weight: 5-30 parts of single-layered zirconium hydrogen phosphate, 10-50 parts of silica sol containing sulfonic acid groups, 20-30 parts of a silane coupling agent and 30-60 parts of an alcohol solvent. A preparation method of the silicon-zirconium composite super-hydrophilic abrasion-resistant coating comprises the following steps: ultrasonically dispersing the single-layered zirconium hydrogen phosphate in the alcohol solvent to obtain single-layered dispersed zirconium hydrogen phosphate, blending and compounding the single-layered dispersed zirconium hydrogen phosphate with the silica sol containing the sulfonic acid groups, then adding the silane coupling agent, simultaneously adding acid, adjusting pH value of a system to be 3-5, and carrying out cohydrolysis reaction for 1-8 hours to obtain the silicon-zirconium composite super-hydrophilic abrasion-resistant coating. The silicon-zirconium composite super-hydrophilic abrasion-resistant coating is high in hydrophilicity, fog resistance, water resistance and weather resistance, and longer in service life; a coating prepared by the coating is high in hardness, abrasion resistance, scratch resistance, fingerprint resistance and stain resistance.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to a silicon-zirconium composite superhydrophilic wear-resistant coating. Background technique [0002] The contact angle of water on the surface of transparent materials such as glass, plastic, and film is above 40°. When there is a temperature difference between the inner and outer surfaces, water vapor will condense on the surface of the material to form fog when it is cold, affecting the transparency of the material. Coating a transparent coating with super hydrophilic properties on the surface of the material can make the contact angle of water on the surface of the material below 5°, so that the water mist or water droplets on the surface of the material will spread on the surface of the material to form a water film. Does not affect the transparency of the material, thus achieving the purpose of anti-fog. The current commercialized superhydrophilic anti-fog coatings are mai...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D1/00C09D5/16C09D7/12
CPCC09D1/00C09D5/16C09D7/63
Inventor 丁富传林文炳孔令涛龚泽胜林文彬
Owner GUANGDONG BINHAO TRAVELWARE
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