The invention discloses a glass etching solution simulating a rock bedding staggered stacking effect, which comprises the following raw materials: NH4HF2, NH4F, ALF3, HNO3, H3PO4, H2SO4, (NH4) 2SiF6, BaSO4, KCl, V2O5, sodium alkyl benzene sulfonate, sorbitol and H2O, and the process for preparing glass by adopting the glass etching solution comprises the following steps: 1, weighing the raw materials; 2, putting the weighed raw materials into a stirring container, fully stirring until the liquid medicine is in a uniform supersaturated solution state, and standing and curing to obtain an etching liquid medicine; 3, coating the back surface of the cleaned glass sheet with a film for protection, and putting the glass sheet into an etching liquid for etching treatment; and 4, taking the etched raw glass sheet out of the liquid medicine, cleaning the raw glass sheet with pure water, and air-drying the raw glass sheet. The etched glass surface features in the microstructure show the uniform structural features that the line arrangement lines are clear and clear, the line arrangement lines are non-directionally arranged, a plurality of groups of inclined layers in different directions are mutually staggered and overlapped, and local disordered arrangement and overall uniform distribution are realized.