The invention discloses
isocyanate group modified
fluorocarbon resin with antifouling performance, an
antifouling coating thereof, a preparation method and application of the
antifouling coating, and the
isocyanate group modified
fluorocarbon resin is prepared by the following steps: under the protection of
inert gas, mixing mercaptan with an acrylic
monomer and a
photoinitiator, carrying out sulfydryl-vinyl click reaction at normal temperature, and then adding an initiator, so as to obtain the
isocyanate group modified
fluorocarbon resin. The preparation method comprises the following steps: adding an acrylic
monomer into
anhydrous fluorocarbon resin to obtain a modified acrylic
monomer, dropwise adding diisocyanate into the
anhydrous fluorocarbon resin, dropwise adding the modified acrylic monomer, and adding a
solvent and a catalyst to react to obtain the isocyanate-based modified fluorocarbon resin
polymer. The isocyanate group modified fluorocarbon resin disclosed by the invention has the characteristics of low
surface energy, strong adhesion capability (
bacteria, seaweed and the like) for inhibiting marine
fouling organisms, small
friction coefficient, good mechanical flexibility, low ice accumulation adhesion and high cycle stability, and is particularly suitable for ship surface protection.