Modified acrylic acid waterproof paint and preparation method thereof

A waterproof coating, acrylic technology, applied in the direction of polyurea/polyurethane coatings, coatings, etc., can solve the problems of easy bubbles, affect waterproof performance, high glass transition temperature, and achieve the effects of simple construction, reliable quality and low viscosity

Inactive Publication Date: 2017-05-17
杭州东方雨虹建筑材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, free radical copolymerization of homologues such as butyl methacrylate and octyl acrylate is used. The curing reaction process is not affected by temperature and moderate, low viscosity, good construction performance, but small elongation at break, generally lower than 20%, vitrification High temperature, poor bendability at low temperature
As a waterproof coating, a large amount of butyl acrylate, octyl methacrylate, octyl acrylate and other homologues need to be added, and the application prospect is not great
The polyurethane waterproof coating has adjustable strength, large extension, good low temperature flexibility, and low price, but the curing reaction is affected by temperature and humidity. The low temperature response is slow in winter and the high temperature response is fast in summer. One-component polyurethane waterproof coating film is prone to bubbles , Two-component polyurethane waterproof coating requires high proportion accuracy, which is prone to construction quality problems and affects waterproof performance. At the same time, aromatic polyurethane has poor weather resistance and cannot be exposed alone. Aliphatic polyurethane is required for exposure, and the price of aliphatic polyurethane is relatively expensive.
At the same time, polyurethane contains a large number of polar groups and is a polar material, while polymethyl methacrylate is a non-polar material. If the two are mixed directly, the compatibility is poor, and polyurethane will precipitate, resulting in sticky surface or poor performance. , can affect the construction application

Method used

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  • Modified acrylic acid waterproof paint and preparation method thereof
  • Modified acrylic acid waterproof paint and preparation method thereof
  • Modified acrylic acid waterproof paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 1. Raw material ratio

[0023]

[0024]

[0025] 2. Process

[0026] (1) Add 30 parts by weight of polyether diol 2000D to the reaction vessel, stir and heat up to 100-120°C, and dehydrate for 2-3 hours under the condition of -0.01MPa vacuum;

[0027] (2) Lower the temperature to 50-100°C, add 5 parts by weight of isocyanate under high-speed stirring, and after 3-5 hours of reaction, add 3 parts by weight of hydroxyacrylic acid and 0.1 part by weight of organotin catalyst T-12, and continue the reaction for 2 After ~3 hours, the polyurethane prepolymer can be obtained by discharging;

[0028] (3) Add 70 parts by weight of acrylic acid monomer (methyl methacrylate) in the cylinder, the polyurethane prepolymer made by 1 part by weight, 0.5 parts by weight of defoamer, 0.5 parts by weight of antioxidant, 0.1 parts by weight of Accelerator (N, N-xylidine) in parts by weight, after being stirred evenly at a high speed, the modified acrylic waterproof coating can be o...

Embodiment 2

[0031] 1. Raw material ratio

[0032]

[0033]

[0034] 2. Process

[0035] (1) Add 50 parts by weight of polyether trihydric alcohol 330N into the reaction vessel, stir and heat up to 100-120°C, and dehydrate for 2-3 hours under the condition of -0.01MPa vacuum;

[0036] (2) Lower the temperature below 50-100°C, add 10 parts by weight of isocyanate under high-speed stirring, and after 3-5 hours of reaction, add 10 parts by weight of 2-hydroxyethyl methacrylate and 0.2 parts by weight of catalyst, After continuing to react for 2-3 hours, the polyurethane prepolymer can be obtained by discharging;

[0037] (3) Add 80 parts by weight of acrylic acid monomers, 26 parts by weight of the prepared polyurethane prepolymer, 60 parts by weight of pigments and fillers, and 1 part by weight of accelerators in the cylinder, and stir evenly at high speed to obtain modified acrylic acid waterproof coating;

[0038] (4) Add 2 parts by weight of initiator to the modified acrylic wate...

Embodiment 3

[0040] 1. Raw material ratio

[0041]

[0042] 2. Process:

[0043] (1) Add 70 parts by weight of polyether polyol to the reaction vessel, stir and heat up to 100-120°C, and dehydrate for 2-3 hours under the condition that the vacuum is -0.01MPa;

[0044] (2) Lower the temperature to 50-100°C, add 10 parts by weight of isocyanate under high-speed stirring, and after 3-5 hours of reaction, add 10 parts by weight of 2-hydroxyethyl methacrylate and 0.2 parts by weight of organotin catalyst T-12, continue to react for 2 to 3 hours and then discharge to obtain polyurethane prepolymer;

[0045] (3) Add 35 parts by weight of acrylic acid monomer (methyl methacrylate), 30 parts by weight of polyurethane prepolymer, 30 parts by weight of pigment and filler, 2 parts by weight of defoamer, and 2 parts by weight of accelerator in the cylinder , After stirring at a high speed, the modified acrylic waterproof coating can be obtained.

[0046] (4) Add 3 parts by weight of initiator (az...

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Abstract

The invention discloses a modified acrylic acid waterproof paint and a preparation method thereof. The modified acrylic acid waterproof paint is prepared from the following raw materials in parts by weight: 70-100 parts of acrylic monomer, 1-30 parts of polyurethane prepolymer, 0-50 parts of a plasticizer, 0-100 parts of a pigment filler, 0-3 parts of a high-performance assistant, 0.1-3 parts of an accelerant and 0.1-4 parts of an initiator. The invention further discloses the preparation method of the modified acrylic acid waterproof paint. Double bonds are introduced into the polyurethane prepolymer, and the modified acrylic acid waterproof paint is synthesized through free radical polymerization and acrylic monomer copolymerization; and the modified acrylic acid waterproof paint is free of solvent, low in viscosity, high in strength, simple in construction and reliable in quality, and can be applicable to engineering waterproofing of buildings, bridge decks, planting roofs and the like, and the reaction curing process is not affected by temperature and humidity.

Description

technical field [0001] The invention relates to a waterproof coating and a preparation method, in particular to a modified acrylic waterproof coating and a preparation method. Background technique [0002] Polymethyl methacrylate (commonly known as plexiglass) has high strength, small elongation, high glass transition temperature, and its performance cannot meet the requirements of coatings, especially waterproof coatings. However, methyl methacrylate has a wide range of sources, free radical polymerization, simple and controllable, dense coating film, good weather resistance, and can be exposed. [0003] At present, free radical copolymerization of homologues such as butyl methacrylate and octyl acrylate is used. The curing reaction process is not affected by temperature and moderate, low viscosity, good construction performance, but small elongation at break, generally lower than 20%, vitrification High temperature, poor bendability at low temperature. As a waterproof co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/14C09D7/12C08G18/66C08G18/48C08G18/34C08G18/10
CPCC09D175/14C08G18/10C08G18/348C08G18/4812C08G18/4825C08G18/4829C08G18/6692C08K3/22C08K3/26C08K13/02C08K2003/2241C08K2003/265C09D7/61C09D7/63C09D7/65C08L33/00
Inventor 焦明明
Owner 杭州东方雨虹建筑材料有限公司
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