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A method for separating and recovering titanium dioxide from waste scr denitrification catalyst

A technology of denitrification catalyst and titanium dioxide, which is applied in the field of environmental protection technology and circular economy, can solve the problems of increasing enterprise costs, waste of effective resources, large land resources, etc., and achieve the effects of saving resources, reducing consumption, and high social and economic benefits

Inactive Publication Date: 2019-03-01
北京恺岚科技发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, crushing and landfilling the spent SCR denitrification catalyst will occupy a large amount of land resources and increase the cost of the enterprise on the one hand; on the other hand, some toxic and harmful substances and some metal elements contained in the catalyst will be adsorbed during the use of the catalyst. It will enter the natural environment due to various effects, especially the water body, causing serious harm to the environment; on the other hand, the V contained in the SCR catalyst itself 2 o 5 、WO 3 and TiO 2 They are all precious resources. Discarding the spent denitrification catalysts leads to failure to recycle the various valuable metal resources contained in it, which will cause a huge waste of effective resources.

Method used

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  • A method for separating and recovering titanium dioxide from waste scr denitrification catalyst
  • A method for separating and recovering titanium dioxide from waste scr denitrification catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] 1) Pretreatment: Take a certain amount of waste SCR denitrification catalyst, dedust, crush, grind, pass through a 100-mesh sieve, and the under-sieve is the catalyst powder. The sieved material is mixed with the crushed waste SCR destocking catalyst and re-sieved.

[0044] 2) Four-stage cross-flow impregnation:

[0045] 21) 10 g of the catalyst powder obtained in step 1) was impregnated with 50 ml of 10% sodium hydroxide solution, in an oil bath at 150° C. for 2 h, and solid-liquid separation was performed after immersion to obtain a filtrate (filtrate a) and a filter cake (filter cake a);

[0046] 22) The filter cake (filter cake a) in step 21) was impregnated with 50 ml of 10% sodium hydroxide solution, oil bathed at 150° C. for 2 hours, and solid-liquid separation was obtained after immersion to obtain filtrate (filtrate b) and filter cake (filter cake b);

[0047] 23) The filter cake (filter cake b) in step 22) is impregnated with 50 ml of 10% sodium hydroxide so...

Embodiment 2

[0052] 1) Pretreatment: Take a certain amount of waste SCR denitrification catalyst, dedust, crush, grind, pass through a 100-mesh sieve, and the under-sieve is the catalyst powder. The sieved material is mixed with the crushed waste SCR destocking catalyst and re-sieved.

[0053] 2) Four-stage cross-flow impregnation:

[0054] 21) 10 g of the catalyst powder obtained in step 1) was impregnated with 20 ml of 40% potassium hydroxide solution, in an oil bath at 100° C. for 4 h, and solid-liquid separation was obtained after immersion to obtain a filtrate (filtrate a) and a filter cake (filter cake a);

[0055] 22) The filter cake (filter cake a) in step 21) is impregnated with 20ml of 40% potassium hydroxide solution, oil bathed at 100°C for 4h, and solid-liquid separation is obtained after immersion to obtain filtrate (filtrate b) and filter cake (filter cake b);

[0056] 23) The filter cake (filter cake b) in step 22) was impregnated with 20 ml of 40% potassium hydroxide sol...

Embodiment 3

[0061] 1) Pretreatment: Take a certain amount of waste SCR denitrification catalyst, dedust, crush, grind, pass through a 100-mesh sieve, and the under-sieve is the catalyst powder. The sieved material is mixed with the crushed waste SCR destocking catalyst and re-sieved.

[0062] 2) Four-stage cross-flow impregnation:

[0063] 21) 10 g of the catalyst powder obtained in step 1) was impregnated with 35 ml of 25% potassium hydroxide solution, in an oil bath at 125° C. for 3 h, and separated from solid and liquid after impregnation to obtain filtrate (filtrate a) and filter cake (filter cake a);

[0064] 22) The filter cake (filter cake a) in step 21) was impregnated with 35 ml of 25% potassium hydroxide solution, oil bathed at 125° C. for 3 hours, and separated from solid and liquid after immersion to obtain filtrate (filtrate b) and filter cake (filter cake b);

[0065] 23) The filter cake (filter cake b) in step 22) was impregnated with 35 ml of 25% potassium hydroxide solu...

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Abstract

The invention discloses a method for separating and recovering titanium dioxide from a waste SCR denitrification catalyst. The method comprises the following steps: soaking pre-treated waste SCR denitrification catalyst powder by virtue of an alkaline solution, wherein the soaking method is a four-level cross flow method or two-level reverse flow method, and washing, drying and calcining an immersed filter cake to obtain high-purity titanium dioxide powder. The titanium dioxide obtained by separation of the method is rutile titanium dioxide, the recovery rate can reach 97 percent, and both the matter purity and the crystal purity are greater than 98 percent. Therefore, the method is high in social and economic benefit and high in industrialized implementation property. By adopting the reverse flow or the cross flow operation, the water consumption and the alkali consumption are greatly reduced; and meanwhile, the use of chemicals added in the subsequent process can also be reduced, the resource is saved, and the economic benefit is prominent. The method has no high pressure condition in the operation and is simple in operation steps. The requirement on equipment in the real industrialization is reduced.

Description

technical field [0001] The invention relates to the fields of environmental protection technology and circular economy, in particular to a method for separating and recovering titanium dioxide from waste SCR denitration catalysts. Background technique [0002] Coal is the main energy source in my country, and the nitrogen oxides produced by its combustion will not only form acid rain, but also cause chemical smog, which is harmful to human health. 70% of my country's nitrogen oxide emissions come from direct combustion of coal, and the power industry is a large coal-burning household in my country, so thermal power plants are one of the main sources of nitrogen oxide (NOx) emissions. With the construction of ecological civilization incorporated into the five-in-one layout of socialist construction, the air pollution caused by coal burning has attracted more and more attention from the government. [0003] The Selective Catalytic Reduction method (abbreviation: SCR method) i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01G23/053B01D53/86B01D53/56
CPCB01D53/8628C01G23/053C01P2006/80
Inventor 陈然丁溪锋郑荣钏刘志猛
Owner 北京恺岚科技发展有限公司