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A kind of molded laser holographic recording material and its preparation method

A laser holographic and recording material technology, applied in the field of molded laser holographic recording materials and their preparation, and composite materials for molded laser holographic recording, can solve problems such as plate sticking, drop points, and defects, and reduce surface energy and improve Good compatibility and wear resistance

Active Publication Date: 2019-04-12
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the above defects or improvement needs of the prior art, the object of the present invention is to provide a molded laser holographic recording material and a preparation method thereof, wherein the key material microscopic composition and structure (especially surface treatment of polytetrafluoroethylene, etc.) ) is improved, compared with the prior art, it can effectively solve the problem that the resin used in the existing molded laser holographic information recording layer is prone to defects such as sticking plate, dropping points or even defects during the molding process. The present invention adopts irradiation graft modification The PTFE micropowder is composited with the imaging resin, and at the same time, the polymer is grafted on the surface of the PTFE micropowder by electron beam irradiation and the grafting rate is controlled, which can improve the compatibility of the PTFE micropowder and the imaging resin, and obtain A molded laser holographic recording material with good internal uniformity and high stability; and, the present invention controls the composition of the imaging resin and the irradiation grafted modified polytetrafluoroethylene micropowder in the composite material for the molded laser holographic recording. Ratio, so that the molded laser holographic recording material has good wear resistance and anti-sticking performance, which can greatly improve the efficiency of molding processing

Method used

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  • A kind of molded laser holographic recording material and its preparation method
  • A kind of molded laser holographic recording material and its preparation method
  • A kind of molded laser holographic recording material and its preparation method

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preparation example Construction

[0043] Correspondingly, the method for preparing the molded laser holographic recording material in the present invention specifically includes the following steps:

[0044] ① Disperse polytetrafluoroethylene powder in the monomer solution, and use electron beam irradiation to initiate the graft polymerization of the monomer on the surface of the polytetrafluoroethylene powder. After the irradiation is completed, the grafted modified polytetrafluoroethylene is obtained by suction filtration, washing and drying. Vinyl fluoride powder; the mass fraction of the monomer solution is 4wt.% to 40wt.%, and the mass ratio of the polytetrafluoroethylene powder to the monomer is 1 / 0.5 to 1 / 3; the dose rate of the electron beam irradiation 4kGy / pass~30kGy / pass (because the sample can pass through the conveyor belt to the electron beam flow, the dose rate unit kGy / pass means the dose per single pass), and the radiation dose is 20kGy~90kGy;

[0045] ②Using electron beam to irradiate PTFE powder ...

Embodiment 1

[0055] The molded laser holographic recording material in this embodiment includes acrylic resin and radiation-grafted polyglycidyl methacrylate modified polytetrafluoroethylene micropowder, wherein the particles of the radiation-grafted modified polytetrafluoroethylene micropowder are The diameter is 0.2 microns, and the mass ratio to the acrylic resin is 1 / 20.

[0056] The molded laser holographic recording material is prepared according to the following steps:

[0057] ① Disperse polytetrafluoroethylene micropowder in 4wt.% glycidyl methacrylate aqueous solution, irradiate the mixed solution with electron beam, and after completion, suction filtration, washing and drying to obtain grafted modified polytetrafluoroethylene micropowder. The mass ratio of polytetrafluoroethylene powder and glycidyl methacrylate is 1 / 0.5, the irradiation dose rate is 4kGy / pass, and the irradiation dose is 20kGy.

[0058] ② Disperse the graft-modified polytetrafluoroethylene fine powder obtained in ste...

Embodiment 2

[0062] The molded laser holographic recording material in this embodiment includes acrylic resin and radiation grafted polyacrylic acid modified polytetrafluoroethylene powder, wherein the particle size of the radiation grafted modified polytetrafluoroethylene powder is 0.2 microns, and The mass ratio of acrylic resin is 3 / 100.

[0063] The molded laser holographic recording material is prepared according to the following steps:

[0064] ① Disperse polytetrafluoroethylene micropowder in a 12wt.% acrylic acid aqueous solution, irradiate the mixed solution with electron beam, and after completion, suction filtration, washing, and drying to obtain grafted modified polytetrafluoroethylene micropowder. The mass ratio of polytetrafluoroethylene powder to acrylic acid is 1 / 1, the irradiation dose rate is 20kGy / pass, and the irradiation dose is 60kGy.

[0065] ② Disperse the graft-modified polytetrafluoroethylene fine powder obtained in step ① in butyl acetate to obtain a graft-modified pol...

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Abstract

The invention discloses a molded laser holographic recording material and a preparation method thereof, wherein the molded laser holographic recording material includes imaging resin and irradiation grafted modified polytetrafluoroethylene micropowder for composite modification of the imaging resin ; The mass ratio of the radiation-grafted modified polytetrafluoroethylene micropowder to the imaging resin is 1 / 20-1 / 200. By improving the microcosmic composition and structure of the key materials, the present invention can effectively solve the problem that the resin used in the existing molding laser holographic information recording layer is prone to defects such as sticking plate, drop point or even defect in the molding process compared with the prior art , to obtain a molded laser holographic recording material with good internal uniformity and high stability.

Description

Technical field [0001] The invention belongs to the field of laser holographic information recording materials, and more specifically, relates to a molded laser holographic recording material and a preparation method thereof. The molded laser holographic recording material is composed of an imaging resin and radiation grafted modified polytetrafluoroethylene powder , Is a composite material especially suitable for molded laser holographic recording. Background technique [0002] Counterfeit and shoddy products not only harm the interests of merchants and consumers, affect the social and economic order, but also bring huge losses to national taxation. Anti-counterfeiting technology has become one of the effective means to combat counterfeit and shoddy products. Among the existing anti-counterfeiting technologies, the laser holographic embossing technology is widely used due to its advantages such as not easy to copy, diverse identification methods, and non-reusable. The technolog...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L33/04C08L51/00C08L75/04C08F259/08C08F220/32C08F220/06C08F220/58C08F220/28C08F220/18C08F220/54C08F220/14C08F220/56C08F2/54
CPCC08F2/54C08F259/08C08L33/04C08L75/04C08L51/003C08F220/281C08F220/1804C08F220/18C08F220/1802C08F220/325C08F220/58
Inventor 解孝林王晖周兴平郑成赋孙绍发李月生牟靖文廖永贵
Owner HUAZHONG UNIV OF SCI & TECH
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