Reactive dye color fixing agent and preparation method thereof

A technology of reactive dyes and color-fixing agents, which can be used in dyeing, textiles, and papermaking. It can solve problems such as hue changes, and achieve the effects of preventing shedding or hydrolysis, reducing water solubility, and no secondary pollution.

Active Publication Date: 2017-05-31
宁波澳翔精细化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is easy to change the hue when fixing the sensitiv

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] In the embodiment of the present invention, a reactive dye fixing agent is composed of the following raw materials in parts by weight: 41 parts of bisphenol S, 5 parts of dichloropropane, 10 parts of dimethylformamide, 17 parts of dimethyl sulfoxide, 3 parts of fatty alcohol polyoxyethylene ether, 13 parts of dichloroacetic acid.

[0016] Dichloroacetic acid and deionized water are mixed to prepare a dichloroacetic acid solution with a mass concentration of 17%; fatty alcohol polyoxyethylene ether is mixed with deionized water whose mass is 8.7 times to prepare a fatty alcohol polyoxyethylene ether solution. Mix bisphenol S with dimethyl sulfoxide and dimethyl formamide, heat up to 60°C, and stir at this temperature for 40 minutes, then add fatty alcohol polyoxyethylene ether solution, heat up to 94°C and Stir at low temperature for 22 minutes; then add dichloropropane, and stir at 65°C for 20 minutes; then add dichloroacetic acid solution dropwise in 5 minutes, and sti...

Embodiment 2

[0018] In the embodiment of the present invention, a reactive dye fixing agent is composed of the following raw materials in parts by weight: 49 parts of bisphenol S, 13 parts of dichloropropane, 18 parts of dimethylformamide, 25 parts of dimethyl sulfoxide, 7 parts of fatty alcohol polyoxyethylene ether, 21 parts of dichloroacetic acid.

[0019] Dichloroacetic acid and deionized water are mixed to prepare a dichloroacetic acid solution with a mass concentration of 17%; fatty alcohol polyoxyethylene ether is mixed with deionized water whose mass is 8.7 times to prepare a fatty alcohol polyoxyethylene ether solution. Mix bisphenol S with dimethyl sulfoxide and dimethyl formamide, heat up to 60°C, and stir at this temperature for 40 minutes, then add fatty alcohol polyoxyethylene ether solution, heat up to 94°C and Stir at low temperature for 22 minutes; then add dichloropropane, and stir at 65°C for 20 minutes; then add dichloroacetic acid solution dropwise in 5 minutes, and st...

Embodiment 3

[0021] In the embodiment of the present invention, a reactive dye fixing agent is composed of the following raw materials in parts by weight: 43 parts of bisphenol S, 7 parts of dichloropropane, 12 parts of dimethylformamide, 19 parts of dimethyl sulfoxide, 4 parts of fatty alcohol polyoxyethylene ether, 15 parts of dichloroacetic acid.

[0022] Dichloroacetic acid and deionized water are mixed to prepare a dichloroacetic acid solution with a mass concentration of 17%; fatty alcohol polyoxyethylene ether is mixed with deionized water whose mass is 8.7 times to prepare a fatty alcohol polyoxyethylene ether solution. Mix bisphenol S with dimethyl sulfoxide and dimethyl formamide, heat up to 60°C, and stir at this temperature for 40 minutes, then add fatty alcohol polyoxyethylene ether solution, heat up to 94°C and Stir at low temperature for 22min; then add dichloropropane, stir at 65°C for 20min; then add dichloroacetic acid solution dropwise in 5min, and stir at 78°C for 64min...

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PUM

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Abstract

The invention discloses a reactive dye color fixing agent and a preparation method thereof. The color fixing agent is prepared from the following raw materials in parts by weight: 41-49 parts of bisphenol S, 5-13 parts of propylene dichloride, 10-18 parts of dimethyl formamide, 17-25 parts of dimethyl sulfoxide, 3-7 parts of fatty alcohol-polyoxyethylene ether and 13-21 parts of dichloroacetic acid. The preparation method comprises the steps of mixing the bisphenol S with the dimethyl sulfoxide and the dimethyl formamide, heating and stirring an obtained mixture; then, adding a fatty alcohol-polyoxyethylene ether solution, heating and stirring; after that, adding the propylene dichloride, heating and stirring; dropwise adding a dichloroacetic acid solution, heating and stirring, and cooling to the room temperature to obtain the reactive dye color fixing agent. The color fixing agent prepared by the method has the advantages of being high in dyeing fastness, capable of obviously improving dry-wet rubbing fastness and color fastness to washing, and the like under the interaction of all the raw materials, and enables reactive dyes basically not to have color change when being used for carrying out color fixation on the reactive dyes; furthermore, the reactive dye color fixing agent is formaldehyde-free, environment-friendly, free from secondary pollution, simple in production technology, suitable for industrial production and especially suitable for the field of color fixation of the reactive dyes.

Description

technical field [0001] The invention relates to the technical field of dye auxiliaries, in particular to a reactive dye fixing agent and a preparation method thereof. Background technique [0002] At present, there are many reasons why the fastness of dyed fabrics cannot meet the requirements. When dyeing with direct dyes, the dyes only rely on van der Waals force, hydrogen bonds and fibers, and the binding force between dyes and fibers is small, and there are sulfur in their molecular structure. Hydrophilic groups such as acid groups and carboxyl groups, when washing, the dyes are easily soluble in water and detached from the fibers, resulting in poor fastness to wet treatment. The reactive group in the reactive dye molecule is easy to bond with the fiber by covalent bond. Theoretically speaking, the covalent bond formed by reactive dyes and fibers is quite strong, and there is no problem of color fastness. In essence, during the dyeing process, especially when dyeing thi...

Claims

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Application Information

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IPC IPC(8): D06P5/08D06P5/04D06P5/06D06P1/38
CPCD06P1/38D06P5/04D06P5/06D06P5/08
Inventor 不公告发明人
Owner 宁波澳翔精细化工有限公司
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