Anti-toxic three-way catalyst regenerated cleaning agent and preparation method thereof

A three-way catalyst, cleaning agent technology, applied in chemical instruments and methods, detergent compounding agents, detergent compositions and other directions, can solve the problems of catalyst component damage, reduce catalytic performance, etc., to improve oxidation resistance, improve Catalytic effect, effect of enhancing adsorption

Inactive Publication Date: 2017-06-13
安徽新态环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The performance of the regenerated catalyst obtained in the article "Study on the Regeneration and Cleaning of Waste Denitrification Catalysts" has only been partially restored, and the strong acid will cause damage to the catalyst components and reduce the catalytic performance. It needs to be improved, and the anti-corrosion performance of the cleaning agent needs to be improved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0013] An anti-poisoning three-way catalyst regeneration cleaning agent, made of the following parts by weight (kg) of raw materials: nano montmorillonite 0.7, ethyl orthosilicate 1.6, appropriate amount of hydrochloric acid, appropriate amount of ammonia, appropriate amount of ethanol, appropriate amount of deionized water , Penetrant T1.5, nitric acid 1.6, nitrilotriacetic acid 1.5, ammonium acetate 0.7, lanthanum acrylate 0.4, carbon nanotube 1, vitamin C 0.4, tetrabutyl titanate 1.

[0014] The preparation method of the anti-poisoning three-way catalytic converter regeneration cleaning agent includes the following steps:

[0015] (1) Mix tetrabutyl titanate: ethanol with a volume ratio of 1:20, stir to obtain tetrabutyl titanate ethanol solution, mix nano-montmorillonite and penetrant T, add 5 parts by weight of deionized water and stir evenly , Drip into the tetrabutyl titanate ethanol solution under constant stirring, stir for 1.5h at 250r / min to obtain a mixture, then slowly...

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Abstract

The invention discloses an anti-toxic three-way catalyst regenerated cleaning agent which is prepared from the following raw materials in parts by weight: 0.7-0.9 part of nanometer montmorillonite, 1.6-1.8 parts of ethyl orthosilicate, a defined amount of hydrochloric acid, a defined amount of ammonium hydroxide, a defined amount of ethyl alcohol, a defined amount of deionized water, 1.5-2 parts of penetrant T, 1.6-1.9 parts of nitric acid, 1.5-1.8 parts of nitrilotriacetic acid, 0.7-0.9 part of ammonium acetate, 0.4-0.6 part of lanthanum acrylate, 1-1.2 parts of carbon nano tube, 0.4-0.5 part of vitamin C and 1-1.2 parts of tetrabutyl titanate. According to the invention, the ammonium acetate, the lanthanum acrylate, the carbon nano tube are used; the ammonium acetate is absorbed by the carbon nano tube; the carbon nano tube can be attached to the catalyst surface; the acetic acid can be decomposed; the catalyst poisoning can be prevented; the vitamin C is used, so that the resistance to oxidation and alkali of the catalyst can be promoted; the poisoning can be avoided.

Description

Technical field [0001] The invention relates to the technical field of cleaning agents for three-way catalytic converters, in particular to an anti-poisoning cleaning agent for regenerating three-way catalytic converters and a preparation method thereof. Background technique [0002] With the country’s stricter and stricter control of nitrogen oxide emissions during the “Twelfth Five-Year Plan” period, selective catalytic reduction (SCR) flue gas denitrification technology has been widely used in the denitrification system of thermal power plants because of its efficient and reliable denitrification performance. The technical core of the SCR flue gas denitrification process is the vanadium tungsten titanium-based catalyst, which has the problem of decreased activity during operation. There are many reasons for catalyst deactivation, including the influence of operating conditions, such as dust in the flue gas and temperature fluctuations that will damage the macroscopic structure...

Claims

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Application Information

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Patent Type & AuthorityApplications(China)
IPC IPC(8): C11D1/28C11D3/12C11D3/20C11D3/04C11D3/30C11D3/33C11D3/60
CPCC11D1/28C11D3/00C11D3/042C11D3/044C11D3/12C11D3/1266C11D3/162C11D3/201C11D3/2079C11D3/2093C11D3/2096C11D3/30C11D3/33
Inventor肖飞龙仰春华刁节超
Owner安徽新态环保科技有限公司