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Ultrahigh-concentration phosphorus potassium fertilizer and preparation method

A fertilizer and concentration technology, applied in the direction of ammonium orthophosphate fertilizer, alkaline orthophosphate fertilizer, phosphate fertilizer, etc., can solve the problems of inability to supplement medium elements, increase in fertilizer cost, low absorption and utilization rate of foliar fertilizer, etc. Reduced dosage, not easy to run off, obvious effect

Inactive Publication Date: 2017-09-19
朱健勋 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the process of foliar fertilization, the absorption and utilization rate of many foliar fertilizers is very low, and it cannot supplement the medium elements. When the fertilizer is sprayed on the foliage, it will be lost as water droplets fall to the ground due to the effect of surface tension, making farmers Fertilizer costs increase

Method used

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Examples

Experimental program
Comparison scheme
Effect test

experiment example 1

[0027] Add 704 kg of 85% industrial phosphoric acid to the pilot test reactor, and then add 500 kg of water to dilute, slowly add 607 kg of potassium hydroxide with a content of 90% for chemical reaction, and at the same time, in the process of adding potassium hydroxide Add 2 kg of EDTA·2NaZn (Suzhou Liansheng Chemical Industry Co., Ltd.) stabilizer, heat, and when the reaction temperature reaches 120 ° C, slowly add the catalyst potassium formate, polyacrylamide, urea, and potassium citrate to the pilot test In the reactor, the molar ratio of the catalyst potassium formate, polyacrylamide, urea, and potassium citrate is 1:2.5:0.1:0.21, the amount of the catalyst is 0.006% of the total mass of the aforementioned raw materials, and the stirring speed is maintained at 120r / min. When the temperature of the system reaches 130-140°C, open the reflux cooling device, keep stirring at this temperature (and stirring speed) for 90-100 minutes, and then transfer the material to a high-sp...

experiment example 2

[0029] Add 7 tons of 85% industrial phosphoric acid to the reaction kettle, and then add 5 tons of water to dilute, slowly add 6 tons of potassium hydroxide with a content of 90% for chemical reaction, and add 20 kg during the process of adding potassium hydroxide EDTA·2NaZn stabilizer, heating, when the reaction temperature reaches 120°C, add the catalyst potassium formate, polyacrylamide, urea, and potassium citrate into the pilot test reactor, in which the catalyst potassium formate, polyacrylamide, urea , The molar ratio of potassium citrate is 1: 1.5: 0.2: 0.01, and the amount of catalyst is 0.008% of the total mass. Stir evenly and keep the stirring speed at 90r / min. When the temperature of the system reaches 130-140°C, open the reflux cooling device, keep stirring at this temperature for 100-110 minutes, and then transfer the material to a high-speed centrifugal spray dryer for spray drying to obtain a powder product. Product: P 2 o 5 : 43.2%, K 2 O: 39.3%, Zn: 0.2%...

experiment example 3

[0031] Add 704 kg of 85% industrial phosphoric acid to the pilot test reactor, and then add 500 kg of water to dilute, slowly add 607 kg of potassium hydroxide with a content of 90% for chemical reaction, and at the same time, in the process of adding potassium hydroxide Add 2 kg of EDTA2NaZn stabilizer and heat it. When the reaction temperature reaches 120°C, add the catalyst potassium formate, polyacrylamide, urea, and potassium citrate into the pilot test reactor. Among them, the catalyst potassium formate, polyacrylamide, The molar ratio of urea and potassium citrate is 1:0.5:0.1:0.01, and the amount of catalyst is 0.001% of the total mass. Stir evenly and keep the stirring speed at 70r / min. When the temperature of the reaction system reaches 130-150°C, open the reflux cooling device, keep stirring and reacting at this temperature for 80-100 minutes, and then transfer the material to a high-speed centrifugal spray dryer for spray drying to obtain a powder product. This pr...

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PUM

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Abstract

The invention discloses an ultrahigh-concentration phosphorus potassium fertilizer and a preparation method. A powdery neutral high-phosphorus-potassium (0-44-44+0.2Zn) water-soluble fertilizer containing trace elements is prepared through a chemical reaction of industrial phosphoric acid and potassium hydroxide and high-temperature centrifugal spray drying by taking EDTA.2NaZn as a stabilizer; the chemical expression of the fertilizer is K2HPO4.KH2PO4; the phosphorus pentoxide content is 44 percent; the potassium oxide content is 44 percent; the trace element content is 0.2 percent. The product has the characteristics that 1, the nutrient content is high, and the total amount of P2O5+K2O is greater than or equal to 88 percent; 2, the PH value is neutral, and the fertilizer has high leaf spreading performance. High-quality basic raw materials are provided for water-soluble fertilizer production enterprises, soil acidification, soil salinification and soil hardening are further prevented, and full utilization of the fertilizer is further ensured.

Description

technical field [0001] The invention belongs to chemical fertilizers, in particular to a kind of chemical fertilizer synthesized by industrial phosphoric acid and potassium hydroxide, EDTA2NaZn is used as a stabilizer, and obtained by high-temperature centrifugal spray drying to obtain powdery neutral high-phosphorus potassium (0-44-44+ 0.2Zn) water soluble fertilizer. Background technique [0002] At present, potassium dihydrogen phosphate, which is well known in the industry, is commonly used for physical mixing to make water-soluble fertilizers. It is used for drip irrigation or flushing, and it is also used as foliar fertilizer for direct spraying in agriculture. Potassium dihydrogen phosphate is the highest-grade raw material in terms of the current water-soluble fertilizer raw materials, but it is used to formulate a higher formula three-element water-soluble fertilizer (K 2 HPO 4 · KH 2 PO 4 ) is unlikely. For example, it is impossible to use potassium dihydroge...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G1/00
CPCC05B7/00C05D9/02
Inventor 朱健勋孙瑞穆石桥
Owner 朱健勋