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Embossing lacquer and method for embossing, and substrate surface coated with the embossing lacquer

An embossing and methyl technology, applied in the field of embossing paint, can solve the problems of low reliability of embossing, achieve the effect of improving the reliability of molding and reducing shrinkage

Active Publication Date: 2017-09-26
约阿内研究有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, they generally have the disadvantage that they can only be used very limitedly as embossing stamps in the sub-micron range, and that the cross-linked polymer material does not fully harden sufficiently rapidly in the embossing process so that the embossing is reliable sex relatively low, so it does not appear to be possible to achieve defect-free self-replication of impressions in the embossing process using currently available embossing lacquers

Method used

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  • Embossing lacquer and method for embossing, and substrate surface coated with the embossing lacquer
  • Embossing lacquer and method for embossing, and substrate surface coated with the embossing lacquer
  • Embossing lacquer and method for embossing, and substrate surface coated with the embossing lacquer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Preparation of embossing paints according to the invention

[0046] 84% acryloylmorpholine (ACMO), 10% 2-Ethylhexylthioglykolat (2-Ethylhexylthioglykolat), 5% 2-hydroxy-2-methyl as photoinitiator by gravure printing -1-Phenyl-propan-1-one and 1% polysiloxane surfactant applied on a PET film with a thickness of 50 μm, where the pickup volume of the gravure roll 1.6ml / m 2 , which corresponds to a wet layer thickness (Nassschichtdicke) of about 0.8 μm, and was carried out at an orbital speed (Bahngeschwindigkeit) of 10 m / min using a nickel embossing tool with a raised embossing structure with a structure width of 5 μm and a structure height of 1 μm embossed. The pneumatic pressure at the counter roll (Gegenwalze) was 4 bar. UV polymerization was carried out by irradiation with a Hg-medium pressure vapor lamp at 100 W / cm.

Embodiment 2

[0048] Preparation of embossing paints according to the invention

[0049] 84% IOBA, 10% 2-ethylene glycol bis(3-mercaptopropionate), 5% 2-hydroxy-2-methyl-1-phenyl-propane- 1-ketone and 1% of 1H,1H,2H,2H-perfluorooctyl acrylate were applied on a PET film with a thickness of 50 μm, with a small cup volume of a gravure printing roll 1.6ml / m 2 , which corresponds to a wet layer thickness of about 0.8 μm, and embossing was performed at a track speed of 10 m / min using a nickel embossing tool with a raised embossing structure with a structure width of 5 μm and a structure height of 1 μm. The pneumatic pressure at the counter roll was 4 bar. UV polymerization was carried out by irradiation with a Hg-medium pressure vapor lamp at 100 W / cm.

Embodiment 3

[0051] Preparation of embossing paints according to the invention

[0052] 84% acryloylmorpholine (ACMO), 10% dodecanethiol, 5% ethyl(2,4,-trimethylbenzoyl)phenylphosphinate as photoinitiator by gravure printing and 1% of 1H,1H,2H,2H-perfluorooctyl acetate applied on a PET film with a thickness of 50 μm, with a cuvette volume of 1.6 ml / m on a gravure printing roll 2 , which corresponds to a wet layer thickness of 0.8 μm, and embossing was performed at a track speed of 10 m / min using a nickel embossing tool with a raised embossing structure with a structure width of 5 μm and a structure height of 1 μm. The pneumatic pressure at the counter roll was 4.2 bar. UV polymerization was carried out by irradiation with a Hg-medium pressure vapor lamp at 100 W / cm.

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Abstract

The invention relates to an embossing lacquer which is based on a UV-polymerizable prepolymer composition that contains at least one acrylate monomer, said prepolymer composition containing, in addition to the acrylate monomer, at least one thiol, selected from the group consisting of: 3-mercaptopropionates, mercaptoacetates, thioglycolates and alkyl thiols and optionally a surface-active anti-adhesive additive selected from the group of non-ionic surfactants, such as polyether-siloxanes, fatty alcohol ethoxylates, such as polyoxyethylene-(9)-lauryl ether, mono-functional alkyl(meth)acrylates, poly-siloxane (meth)acrylates, perfluoroalkyl(meth)acrylates and perfluoropolyether(meth)acrylates and a photoinitiator. The invention also relates to a method for embossing substrate surfaces that are coated with an embossing lacquer.

Description

technical field [0001] The invention relates to embossing paints based on UV-polymerizable prepolymer compositions comprising at least one acrylate monomer And a method of embossing the surface of a substrate coated with an embossing varnish based on a UV polymerizable prepolymer composition comprising at least one acrylate monomer. Background technique [0002] Due to the rapid development of nanotechnology in recent years, the production of nanostructured components, where such nanostructured components are usually made from photopolymerizable prepolymer compositions, has become significantly more important in industrial manufacturing. Particularly in the field of decoration, product marketing and the surface modification of various materials such as films, extremely fine structures are increasingly used to achieve specific additional functions, such as decorative optical effects. For this purpose structures prefabricated by nanotechnology are used, which are produced fr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03F7/00G03F7/004G03F7/027G03F7/028G03F7/029G03F7/031G03F7/075
CPCG03F7/0002G03F7/0275G03F7/028G03F7/0046G03F7/0048G03F7/029G03F7/031G03F7/0757G03F7/027G03F7/0751G03F7/085G03F7/40G03F7/425G03F7/423C09K2323/03C09K2323/033C09K2323/035
Inventor D·内斯C·奥纳B·施塔德洛贝尔S·鲁特洛夫M·贝利格拉蒂斯
Owner 约阿内研究有限责任公司