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A kind of highly conductive graphene film and preparation method thereof

A graphene film, high conductivity technology, applied in chemical instruments and methods, cable/conductor manufacturing, conductive layers on insulating carriers, etc., can solve problems such as difficult control, complex chemical reactions, etc. The process is simple and easy to implement, and the effect of improving electrical conductivity

Active Publication Date: 2019-02-15
PEKING UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This approach often involves complex chemical reactions that are difficult to control

Method used

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  • A kind of highly conductive graphene film and preparation method thereof
  • A kind of highly conductive graphene film and preparation method thereof
  • A kind of highly conductive graphene film and preparation method thereof

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Embodiment 1

[0052] Embodiment 1, improve the chemical functionalization method of graphene thin film conductivity

[0053] Such as figure 1 Shown is the schematic diagram of the method of the present invention.

[0054] Such as figure 2 Shown, be the technological installation figure of the inventive method, concrete steps are as follows:

[0055] 1) The growth of graphene on the copper foil substrate adopts a low-pressure chemical vapor deposition system (LPCVD).

[0056]Copper foil (purity 99.8%, thickness 25 microns) was annealed in a hydrogen atmosphere for 30 minutes at 1000 ° C, the hydrogen flow rate was 300 sccm, and the system pressure was maintained at 350 Pa, and then annealed in an argon atmosphere for 30 minutes, and the argon flow rate was 500sccm, the system pressure is maintained at 500Pa. The function of annealing under hydrogen atmosphere is to reduce the oxide layer on the surface of copper foil, and the function of annealing under argon atmosphere is to reduce the...

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Abstract

The invention discloses a high-conductivity graphene thin film and a preparation method thereof. The preparation method comprises the following steps of sequentially arranging a graphene thin film / copper foil composite film structure and a polyacrylonitrile fiber film / copper foil composite film structure in a quartz cavity along an air flow direction of a carrier gas, introducing the carrier gas, rising a temperature, and performing gas-phase reaction under a vacuum condition, thereby obtaining the high-conductivity graphene thin film, wherein the graphene thin film / copper foil composite film structure is a composite structure of a copper foil and a graphene thin film coated on a surface of the copper foil, and the polyacrylonitrile fiber film / copper foil composite film structure is a composite structure of a copper foil and a polyacrylonitrile fiber film coated on a surface of the copper foil. The process is simple and practical, the related electrostatic spinning and low-voltage chemical vapor deposition (CVD) are mature technologies, and the function of gas-phase reaction on the graphene thin film is high-efficiency and uniform; and the conductivity of the functionalized graphene thin film is improved by 40% or above and is very remarkable, and the influence on the transmitting of the graphene thin film is very low.

Description

technical field [0001] The invention relates to a high-conductivity graphene film and a preparation method thereof. Background technique [0002] Graphene is composed of a single layer of carbon atoms with sp 2 The two-dimensional material formed by hybridization has stable physical and chemical properties, excellent mechanical strength, and excellent electrical and thermal conductivity. It is widely used in many fields, especially as a flexible transparent conductive film for the next generation of flexible electronics. Devices, flexible touch screens, etc. Compared with traditional transparent conductive films (ITO, AZO, conductive polymers, etc.), the conductivity of graphene films is relatively small. Therefore, it is necessary to develop stable methods to improve the electrical conductivity of graphene films. At present, the methods for improving the conductivity of graphene films include the following categories: 1. The atom substitution of graphene lattice, such as...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B5/14H01B13/00B32B9/04B32B15/04B32B15/20B32B27/36
CPCB32B9/04B32B15/04B32B15/20B32B27/36H01B5/14H01B13/00
Inventor 彭海琳党文辉邓兵
Owner PEKING UNIV
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