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Low-viscosity, low-smoke and flame-retardant high-speed elevator balance compensating chain PVC sheath material and preparation method thereof

A low-smoke flame-retardant, balanced compensation technology, applied in the field of polymer composite material preparation, can solve the problems of fast coating speed, uneven elastic recovery, slow second coating speed, etc., and achieves easy extrusion molding processing. , Small change rate of tensile strength, good effect of smoke suppression and flame retardant

Inactive Publication Date: 2017-12-19
CHANGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, PVC elastomer-coated elevator balance chains are usually produced by a "two-step" extrusion process, that is, the first step is pre-coating, and a right-angle machine head is used to coat the surface of the iron chain and the gap between the chain rings with a certain thickness of PVC. The rubber material is then cooled rapidly to freeze the internal high-elastic deformation; the second step is coating, which rapidly heats the pre-coating material at high temperature to melt the surface, and then performs secondary coating through the right-angle head. This method has high production efficiency Low
Some companies have also tried to improve the above two-step molding process, such as using two extruders to perform two coatings on the same production line, but because the first coating speed is fast, the second coating speed is slow , the two speeds are difficult to coordinate, and the overall speed is not significantly improved. If the coating speed is increased, uneven elastic recovery will appear after the material exits the mold. After the product is cooled, the surface will appear uneven, and the product size will fluctuate significantly.
Since the PVC sheathing material of elevator balance compensation chain is mostly prepared by mixing PVC and elastomer, its viscoelasticity is relatively large. During the rapid extrusion process, due to the existence of the iron chain, the material is subjected to complex shearing in different directions, and the large Molecular orientation, after the material flows out of the die, the molecular chain is disoriented. Due to the different orientation degrees of different parts, the elastic recovery is inconsistent, which further aggravates the fluctuation of the product size, which brings difficulties to the realization of rapid prototyping.
In order to meet the requirements of rapid prototyping technology and environmental protection, the present invention provides a low-viscosity, low-smoke, flame-retardant, high-speed elevator balance compensation chain PVC sheath material and its preparation method. The produced PVC thermoplastic elastomer contains a large amount of plasticizer, its flame retardancy is poor, and thick smoke is generated during the combustion process, which contains a large amount of toxic and harmful gases (such as carbon monoxide, benzene, hydrogen chloride, etc.), so it is inhibit Smoke flame retardancy is also very important

Method used

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  • Low-viscosity, low-smoke and flame-retardant high-speed elevator balance compensating chain PVC sheath material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0011] The special low-viscosity, low-smoke, flame-retardant PVC elastomer material for elevator balance compensation chain sheath of this embodiment is a blend system composed of PVC resin and other additives. Additives include plasticizers, stabilizers, lubricants, flame retardants, smoke suppressants, viscosity reducers and pigments. PVC is made by mixing two resins with a degree of polymerization of 800 and 2500 according to 1:1.5; there are two plasticizers, the first is dioctyl phthalate, the second is diphenyl monooctyl phosphate, o Dioctyl phthalate and diphenyl monooctyl phosphate are mixed in a weight ratio of 5-10:1 to form a mixed plasticizer. In the 238kg special PVC elastomer material for elevator balance compensation chain sheath, the components and contents are as follows: PVC resin 100kg, heat stabilizer non-toxic liquid calcium-zinc stabilizer 7kg, plasticizer dioctyl phthalate 70kg, diphenyl iso-octyl phosphate 10kg, lubricant zinc stearate 3.5kg, flame reta...

Embodiment 2

[0017] The rest of this embodiment is the same as embodiment 1, the difference is: in the 269kg of special PVC elastomer material for elevator balance compensation chain sheath, each component and corresponding content are as follows: PVC resin 100kg, no heat stabilizer Toxic liquid calcium-zinc stabilizer 7kg, plasticizer dioctyl phthalate 75kg, diphenyl iso-octyl phosphate 10kg, lubricant zinc stearate 3.5kg, pigment carbon black 0.3kg, flame retardant modification Micron hydrotalcite 50kg, smoke suppressant zinc borate 8.2kg, 15kg chlorinated paraffin (chlorine content 20-40%). Among them, PVC is a 1:1 mixture of two resins with a degree of polymerization of 800 and 2500.

[0018] In step ②, the weight of the various raw materials weighed corresponds to the content of the above-mentioned components, 100 kg of PVC mixed resin, 7 kg of heat stabilizer non-toxic liquid calcium-zinc stabilizer, and 75 kg of plasticizer dioctyl phthalate , Diphenyl iso-octyl phosphate 10kg, chlori...

Embodiment 3

[0020] The rest of this embodiment is the same as embodiment 1, the difference is: in the 274kg of special PVC elastomer material for elevator balance compensation chain sheath, the components and corresponding contents are as follows:: PVC resin 100kg, heat stabilizer Non-toxic liquid calcium-zinc stabilizer 7kg, plasticizer dioctyl phthalate 75kg, diphenyl iso-octyl phosphate 10kg, lubricant zinc stearate 3.5kg, pigment carbon black 0.3kg, flame retardant modification 50kg of natural micron hydrotalcite, 8.2kg of smoke suppressant zinc borate, 20kg of chlorinated paraffin (chlorine content 20-40%). Among them, PVC is made by mixing two resins with a degree of polymerization of 800 and 2500 according to 1:2.

[0021] In step ②, the weight of the various raw materials weighed corresponds to the content of the above-mentioned components, 100 kg of PVC mixed resin, 7 kg of heat stabilizer non-toxic liquid calcium-zinc stabilizer, and 75 kg of plasticizer dioctyl phthalate , Diphen...

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Abstract

The invention provides a formula of a low-viscosity, low-smoke and flame-retardant high-speed elevator balance compensating chain PVC sheath material, which is adapted to a rapid moulding technology and meets an environment-friendly requirement, and a preparation method thereof. The raw material formula of the low-viscosity, low-smoke and flame-retardant high-speed elevator balance compensating chain PVC sheath material comprises the following components in parts by weight: 100-150 parts of PVC resin, 60-120 parts of a plasticizer, 4-8 parts of a stabilizer, 2-8 parts of a lubricant, 30-60 parts of a flame retardant, 5-15 parts of a smoke suppressant, 5-20 parts of a viscosity reducer and 0.3-1.0 part of a pigment. The preparation method comprises the following steps: mixing the PVC resin to 70-80 DEG C in a kneading machine, then adding a certain amount of an auxiliary agent, continuing mixing, and discharging after the temperature of a mixed material reaches 85-95 DEG C; sending the mixed material into a cooling stirrer, and cooling to 40-50 DEG C; finally, placing in a conical twin-screw extruder, and performing extrusion granulation at the extruding temperature of 130-170 DEG C to obtain a low-viscosity, low-smoke and flame-retardant elastic PVC material. The special low-viscosity, low-smoke and flame-retardant high-speed elevator balance compensating chain PVC sheath material prepared by the preparation method provided by the invention can be applied to the rapid moulding technology of an elevator balance compensating chain sheath, has relatively good appearance, high toughness, high heat aging resistance and high heat stability, and has low viscosity, low smoke performance and flame retardance.

Description

Technical field [0001] The invention relates to a preparation technology of a polymer composite material, in particular to a low-viscosity, low-smoke flame-retardant high-speed elevator balance compensation chain sheath material and a preparation method thereof. Background technique [0002] With the continuous emergence of high-rise buildings, the amount of elevators has grown exponentially. Elevator balance compensation chain is an important safety component that keeps the elevator lifting process running smoothly. The elevator balance compensation chain is composed of a special electric welded anchor chain and an outer coating composite material. In order to ensure that the elevator balance compensation chain reduces frictional noise and is stable during operation, the elevator balance compensation chain must be wrapped with a certain elastic polymer material. jacket. At present, the PVC elastomer-coated elevator balance chain is usually produced by a "two-step" extrusion pr...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L91/06C08K13/06C08K9/06C08K3/26C08K5/12C08K5/523C08K3/04C08K3/38B29C47/92B29C48/92
CPCC08L27/06B29C48/92B29C2948/92704C08K2003/387C08K2201/003C08L2201/02C08L2201/08C08L2201/22C08L2205/025C08L2205/03C08L2205/035C08L91/06C08K13/06C08K9/06C08K3/26C08K5/12C08K5/523C08K3/04C08K3/38
Inventor 徐建平黄昱臻龚方红刘春林魏昌林
Owner CHANGZHOU UNIV
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