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Polyethylene terephthalate polymer, yarn comprising same, and method for manufacturing car mat

A polyethylene terephthalate yarn, polyethylene terephthalate technology, which is applied in the field of yarn and automobile pads, can solve the problems of low wear resistance and the like, and achieves improved wear resistance, The effect of increasing density

Inactive Publication Date: 2018-01-02
HYOSUNG ADVANCED MATERIALS CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the case of conventional PET car mats, its price is lower compared to nylon car mats, but it is only used in small cars due to the low abrasion resistance (300 times level) required for car mats

Method used

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  • Polyethylene terephthalate polymer, yarn comprising same, and method for manufacturing car mat

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] A slurry prepared by mixing 50 parts by weight of ethylene glycol with respect to 100 parts by weight of terephthalic acid was introduced into the esterification reactor, and pressurized at 250° C. for 4 hours under a pressure of 0.5 Torr to make the water Flow out of the reactor for esterification to produce bis(2-hydroxyethyl) terephthalate. In this case, 300 ppm of phosphorus-based heat stabilizer was added at the end of the esterification reaction. Meanwhile, 0.1% by weight of 90% barium sulfate particles having an average particle diameter of 1.4 μm and 10% of barium sulfate particles having a particle diameter of 4.2 μm were added to the polymer after the esterification reaction. Thereafter, 300 ppm antimony catalyst was added as a polymerization catalyst at the initial stage of the polycondensation reaction, the temperature was raised from 250° C. to 285° C. at 60° C. / hour, and the pressure was lowered to 0.5 Torr to carry out the polycondensation reaction.

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Embodiment 2~4

[0068] Polymers, yarns, and car mats were prepared in the same manner as in Example 1, except that the intrinsic viscosity of the polyethylene terephthalate polymer and the denier of the yarns were changed as shown in Table 1.

Embodiment 5

[0070] Polymer, yarn and car mat were prepared in the same manner as in Example 1, except that the intrinsic viscosity of the polyethylene terephthalate polymer and the denier of the yarn were changed as shown in Table 1, And 0.1% by weight of 90% of silica particles with an average particle diameter of 1.4 μm and 10% of silica particles with an average particle diameter of 4.2 μm was introduced in the manufacture of polyethylene terephthalate polymer instead of barium sulfate.

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Abstract

The present invention relates to a method for preparing a polyethylene terephthalate polymer with improved abrasion resistance by further introducing inorganic particles (metal) in addition to ethylene glycol (EG) and terephthalic acid (TPA), which form an existing polyethylene terephthalate bond, and to a yarn and car mat manufactured by using the polyethylene terephthalate polymer prepared by the method. When the yarn and the car mat are manufactured using the polyethylene terephthalate polymer, the density of the yarn is increased, leading to an improvement in abrasion resistance of the carmat.

Description

technical field [0001] The present invention relates to the manufacture of abrasion resistance by introducing inorganic particles (metals) in addition to ethylene glycol (EG, Ethyleneglycol) and terephthalic acid (TPA, terephthalic acid) which constitute the bonds of conventional polyethylene terephthalate Improved method of polyethylene terephthalate polymer, and yarn and car mat produced by using polyethylene terephthalate polymer produced by the above-mentioned production method. Background technique [0002] Generally, polyester resins, especially polyethylene terephthalate resins, are linear polymers synthesized from dicarboxylic acids or their ester-forming derivatives and diols or their ester-forming derivatives, and because of their low cost, It is excellent in mechanical properties and chemical properties as well as excellent in gas barrier properties, and is widely used in various products such as containers, films, and fibers. Meanwhile, polyester is manufactured...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G63/183C08G63/80C08J3/22C08K3/00D01F6/62B60N3/04
CPCC08G63/78D01F1/10C08K3/013C08G63/183C08G63/80C08K3/30C08K3/36C08K3/40C08K2003/2227C08K2003/2241C08K2003/265C08K2003/3045C08K2003/325C08K2201/003D01F6/62C08L67/02B60N3/04C08J3/22C08K3/00C08G2261/63C08K3/22C08K3/26C08K3/32
Inventor 金天基金袤松金钟敏权容澈
Owner HYOSUNG ADVANCED MATERIALS CORP