Foaming polyurethane rubber compound particles capable of being sulfurized and crossly linked as well as preparation method and molding technology of foaming polyurethane rubber compound particles

A technology of polyurethane compound rubber and foamed polyurethane, which is applied in the field of foamed polyurethane compound rubber particles and its preparation, which can solve the problems of explosion, potential safety hazards, and inability to realize the melt viscosity, crosslinking degree and dimensional stability of polyurethane particles The adjustment effect and other issues, to achieve the effect of high cross-linking degree

Active Publication Date: 2018-03-23
福建安达福新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, the use of a large amount of aliphatic hydrocarbons as blowing agents is also prone to explosion, and there are potential safety hazards
[0006] Another example, Chinese invention patent application CN 103709726 A uses supercritical fluid to foam thermoplastic polyurethane, and adds foaming nucleating agent and antioxidant to blend with thermoplastic polyurethane particles, and obtain

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Weigh 100 parts by weight of polytetrahydrofuran diol (PTMG-1000, Du Pont) and 3.5 parts by weight of trimethylolpropane monoallyl ether in the reactor, heat to 105 ° C under reduced pressure to remove water for 2 h, then cooled down to 40°C, added 22.5 parts by weight of diphenylmethane diisocyanate, controlled the reaction temperature to 75°C, decompressed and defoamed for 20 min, then stopped stirring, continued defoaming for 3 min, and put the material into a stainless steel pan. Put the stainless steel pan with the material into an oven at 100°C, and continue to bake for 20 hours to obtain thermoplastic polyurethane materials with unsaturated carbon-carbon double bonds in the side chain, and use a crusher to granulate them into unsaturated polyurethane compound rubber particles .

[0045] Weigh 100 parts by weight of polyether polyol (DL-2000, Shandong Bluestar Dongda Chemical Industry Co., Ltd.), 8 parts by weight of 1,4-butanediol in the reactor, and heat it to ...

Embodiment 2

[0049] Weigh 100 parts by weight of hydroxyl-terminated polybutadiene (R-15HT, Japan Idemitsu Kosan Co., Ltd.), 8.5 parts by weight of 1,4-butanediol in the reactor, and heat it to 110 ° C under stirring. Remove water under pressure for 2 hours, then cool down to 40°C, add 17.5 parts by weight of toluene diisocyanate, control the reaction temperature to 75°C, decompress and defoam the reaction for 20 minutes, then stop stirring, continue defoaming for 3 minutes, put the material into in a stainless steel pan. Put the stainless steel plate filled with the material into an oven at 100°C, and continue to bake for 20 hours to obtain a thermoplastic polyurethane material with unsaturated carbon-carbon double bonds in the main chain, and use a crusher to granulate it into unsaturated polyurethane compound rubber particles.

[0050] With 70 parts by weight of unsaturated polyurethane rubber compound particles, 30 parts by weight of saturated thermoplastic polyurethane particles in Ex...

Embodiment 3

[0053] Take by weighing 100 parts by weight of polycaprolactone glycol (Placcel 210N, Japan Daicel Chemical Industry Co., Ltd.), 7.2 parts by weight of trimethylolpropane monoallyl ether, heated to Remove water under reduced pressure at 115°C for 1.5 h, then lower the temperature to 40°C, add 35 parts by weight of diphenylmethane diisocyanate, control the reaction temperature to 70°C, decompress and defoam the reaction for 18 min, then stop stirring and continue defoaming for 3 min, put the material into the stainless steel pan. Put the stainless steel pan with the material into an oven at 110°C, and continue to bake for 16 hours to obtain thermoplastic polyurethane materials with unsaturated carbon-carbon double bonds in the side chain, and use a crusher to granulate them into unsaturated polyurethane compound rubber particles .

[0054] 90 parts by weight of unsaturated polyurethane compound rubber particles, 10 parts by weight of saturated thermoplastic polyurethane partic...

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PUM

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Abstract

The invention discloses foaming polyurethane rubber compound particles capable of being sulfurized and crossly linked as well as a preparation method and a molding technology of the foaming polyurethane rubber compound particles. The foaming polyurethane rubber compound particles capable of being sulfurized and crossly linked are prepared from an unsaturated polyurethane rubber compound, a foamingnucleating agent, a foam pore size stabilizer and a melt viscosity regulator; all the components are melted, blended and granulated to prepare blended particles; then supercritical fluid is used as afoaming agent to carry out foaming; finally, the foaming particles with stable quality, uniform foam pore distribution, high foaming rate, low size shrinkage rate and beautiful surface can be obtained; meanwhile, the obtained foaming particles also can be further sulfurized to form an interpenetrating or semi-interpenetrating network structure; the cross linking degree of the foaming particles isregulated and controlled; the obtained foaming polyurethane rubber compound particles can be widely applied to fields including vibration absorption materials, packaging materials, child toys, sportsgoods, model airplanes, heat-preservation and heat-insulation materials, automobile interior materials and the like.

Description

technical field [0001] The invention relates to the technical field of preparation of polyurethane foam materials, in particular to a vulcanizable and crosslinkable foamed polyurethane compound rubber particle and its preparation method and molding process. Background technique [0002] Foamed plastics, also known as porous plastics, refer to materials with resin as the main body and countless tiny cells inside. Since the foam plastic is composed of a large number of cells, and the cells are filled with gas, it is also called a composite material with gas as a filler. Since World War II, foam plastics have become a very important part of the polymer industry, affecting almost every aspect of our daily lives. The rapid development of the foam plastic industry is due to its performance advantages, such as low density, light weight, heat and sound insulation, high specific strength, cushioning, etc., which can be widely used in protective packaging materials, thermal insulatio...

Claims

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Application Information

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IPC IPC(8): C08L75/08C08L23/08C08L75/14C08L55/02C08L23/06C08L27/06C08K13/02C08K3/34C08K3/26C08K3/38C08K3/22C08K5/1545C08K3/06C08K5/40C08K5/103C08J9/12C08J3/24
CPCC08J3/246C08J9/0023C08J9/0033C08J9/0061C08J9/0066C08J9/0095C08J9/122C08J2203/06C08J2203/08C08J2375/08C08J2375/14C08J2423/06C08J2423/08C08J2427/06C08J2475/08
Inventor 丁尤权林共情林志勇
Owner 福建安达福新材料科技有限公司
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