Method for quickly preparing low-heat-conduction mullite heat-insulation brick on basis of foam processes

A technology of low thermal conductivity and mullite, which is applied in the field of heat-insulating refractory materials, can solve problems such as poor thermal shock resistance, high requirements for drying equipment, and uneven dispersion, so as to improve thermal shock resistance, shorten production cycle, and improve the preparation process. simple effect

Inactive Publication Date: 2018-04-24
YIXING MORGAN THERMAL CERAMICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patented technology has deficiencies: (1) The combustion of polystyrene and sawdust will cause harm to the environment; (2) Polystyrene and sawdust, etc., are used as pore-forming agents, and there is inhomogeneity in the dispersion of raw materials. Both are large in size, and the pores formed are mostly through holes, which are difficult to be used in the preparation of ultra-low thermal conductivity refractory materials
But there are also the following disadvantages: (1) Alumina hollow spheres will consume a lot of electric energy during the preparation process; (2) The pore diameter is large, and the porosity is difficult to further reduce, so its thermal insulation performance is affected
However, there are two problems with this technical solution: (1) Although microwave drying can be used to dry quickly, it is easy to cause cracking of large-sized samples, and at the same time, mass production requires high drying equipment, resulting in a significant increase in production costs; (2) ) The green strength of the product is extremely low, and it is not easy to handle without high temperature drying; (3) The product strength is too high, its thermal shock resistance is poor, and it is not easy to process
However, the current foam method has problems such as long drying cycle, easy cracking and low green strength, which restrict its large-scale application in the production of heat-insulating refractory materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Take 10wt% alumina fine powder, 25wt% corundum fine powder, 10wt% expansion agent, 10wt% gel powder, 10wt% clay, 25wt% mullite powder and 10wt% binder as raw materials, plus The raw materials are 0.1wt% quick-setting agent, 0.1wt% water reducing agent, 0.1wt% structural proppant and 20wt% water, pre-mixed for 3 to 5 minutes to prepare a premix; then add it to the premix Add 400~1000ml / kg foaming agent, mix evenly, cast into shape, cure at 25~50℃ for 1~5h, demould, dry, and fire at 1250~1600℃ for 3~6 hours, it will be fast Prepare low thermal conductivity mullite insulation bricks.

[0022] Wherein, the fine alumina powder is one of industrial alumina fine powder and calcined alumina fine powder, with a particle size of 0.074mm~0.147mm; the fine corundum powder is tabular corundum, white corundum and brown corundum One of Kyanite, andalusite and sillimanite with a particle size of 0.074mm~0.14mm; the expansion agent is one of kyanite, andalusite and sillimanite, and the pa...

Embodiment 2

[0024] Take 15wt% alumina fine powder, 20wt% corundum fine powder, 5wt% expansion agent, 15wt% gel powder, 15wt% clay, 20wt% mullite powder and 10wt% binder as raw materials, plus The raw materials 2wt% quick-setting agent, 0.5wt% water reducing agent, 1wt% structural proppant and 35wt% water are pre-mixed for 3 to 5 minutes to prepare a premix; then 400 is added to the premix ~1000ml / kg of foaming agent, mix evenly, pour into shape, cure at 25~50℃ for 1~5h, demould, dry, and fire at 1250~1600℃ for 3~6 hours, it can be quickly prepared Low thermal conductivity mullite insulation brick.

[0025] Wherein, the fine alumina powder is one of industrial alumina fine powder and calcined alumina fine powder, with a particle size of 0.074mm~0.147mm; the fine corundum powder is tabular corundum, white corundum and brown corundum One of Kyanite, andalusite and sillimanite with a particle size of 0.074mm~0.14mm; the expansion agent is one of kyanite, andalusite and sillimanite, and the part...

Embodiment 3

[0027] Using 20wt% alumina fine powder, 15wt% corundum fine powder, 10wt% expansion agent, 5wt% gel powder, 20wt% clay, 15wt% mullite powder and 15wt% binder as raw materials, plus The raw materials 1wt% quick-setting agent, 0.3wt% water reducing agent, 0.5wt% structural proppant and 25wt% water are premixed for 3~5 minutes to prepare a premix; then add to the premix 400~1000ml / kg foaming agent, mix evenly, cast into shape, cure at 25~50℃ for 1~5h, demould, dry, and fire at 1250~1600℃ for 3~6 hours, then it can be quickly prepared Produce low thermal conductivity mullite insulation bricks.

[0028] Wherein, the fine alumina powder is one of industrial alumina fine powder and calcined alumina fine powder, with a particle size of 0.074mm~0.147mm; the fine corundum powder is tabular corundum, white corundum and brown corundum One of Kyanite, andalusite and sillimanite with a particle size of 0.074mm~0.14mm; the expansion agent is one of kyanite, andalusite and sillimanite, and the ...

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Abstract

The invention discloses a method for quickly preparing a low-heat-conduction mullite heat-insulation bricks on the basis of foam processes. The method includes adding auxiliary materials including setting accelerators, water reducing agents, structural propping agents and water into raw materials including aluminum oxide fine powder, corundum fine powder, expansive agents, gel powder, clay, mullite powder and binding agents and mixing the auxiliary materials and the raw materials with one another to obtain first mixtures; adding foaming agents into the first mixtures and uniformly mixing the foaming agents and the first mixtures with one another to obtain second mixtures; calcining the second mixtures to obtain the low-heat-conduction mullite heat-insulation bricks. The invention further discloses the low-heat-conduction mullite heat-insulation brick prepared by the aid of the method. The method and the low-heat-conduction mullite heat-insulation brick have the advantages that the method includes simple preparation technologies and is free of environmental hazards, low in production cost and short in production cycle; good heat-insulation effects can be realized by the low-heat-conduction mullite heat-insulation brick prepared by the aid of the method, the low-heat-conduction mullite heat-insulation brick is high in thermal shock resistance, long in service life and wide in service range, and the like.

Description

Technical field [0001] The invention belongs to the technical field of heat-insulating refractory materials, and specifically relates to a method for quickly preparing low-thermal-conductivity mullite heat-insulating bricks based on a foam method. Background technique [0002] The energy saving of industrial furnaces has always been an important problem that needs to be solved urgently by large energy consumers such as metallurgy, machinery, chemical industry, etc. The use of lightweight thermal insulation materials with lower thermal conductivity as furnace lining is one of the effective ways to solve this problem. Lightweight thermal insulation materials mainly achieve lightweight and thermal insulation effects by making holes inside the material, and the shape and distribution of the pores in the material have a great impact on the thermal conductivity of the product. Studies have shown that when the porosity in the material is the same, the smaller the pore size and the highe...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B38/02C04B38/10C04B35/185C04B35/66
CPCC04B35/185C04B35/66C04B38/02C04B38/10C04B2235/3217C04B2235/349C04B2235/77C04B2235/9607
Inventor 廖佳殷波黄柯柯毛旭敏张少伟范昌龙
Owner YIXING MORGAN THERMAL CERAMICS CO LTD
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