Preparation method of polymer particles with wrinkling surfaces

A technology of polymers and particles, which is applied in the field of preparation of surface wrinkled polymer particles, can solve problems such as difficult to remove, affect the performance of polymers, and easy aging of polymers, and achieve large shape controllability, low cost, Easy post-processing effects

Inactive Publication Date: 2018-06-01
NORTHWESTERN POLYTECHNICAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

And because the amphiphilic dispersant must be used in the suspension polymerization process, it is difficult to remove it from the po...

Method used

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  • Preparation method of polymer particles with wrinkling surfaces
  • Preparation method of polymer particles with wrinkling surfaces

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Example 1: Polyglycidyl methacrylate initiates polymerization of ethylene glycol dimethacrylate to prepare surface wrinkled polymer particles

[0018] Mix 6g of polyglycidyl methacrylate, 40g of ethylene glycol dimethacrylate, and 100g of water, stir and emulsify at room temperature for 10 minutes, heat to 60°C, and react for 12 hours, then fully wash to remove unpolymerized dimethylformaldehyde Polyethylene glycol acrylate and polyglycidyl methacrylate dissolved in water to obtain polyethylene dimethacrylate surface wrinkled polymer particles.

Embodiment 2

[0019] Example 2: Polyglycidyl methacrylate initiates divinylbenzene polymerization to prepare surface wrinkled polymer particles

[0020] Mix 4g of polyglycidyl methacrylate, 40g of divinylbenzene monomer, and 100g of water, stir and emulsify at room temperature for 10 minutes, heat to 70°C, and react for 12 hours, then fully wash to remove unpolymerized divinylbenzene and polyglycidyl methacrylate dissolved in water to obtain polydivinylbenzene surface wrinkled polymer particles.

Embodiment 3

[0021] Example 3: Polyglycidyl methacrylate initiates bismaleimide polymerization to prepare surface wrinkled polymer particles

[0022] Mix 4g of polyglycidyl methacrylate, 40g of bismaleimide, and 100g of water, stir and emulsify at room temperature for 30 minutes, heat to 70°C, and react for 12 hours, then fully wash to remove unpolymerized bismaleimide imine and polyglycidyl methacrylate dissolved in water to obtain polybismaleimide surface wrinkled polymer particles.

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PUM

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Abstract

The invention relates to a preparation method of polymer particles with wrinkling surfaces. According to the preparation method, macromolecular poly(glycidyl methacrylate) with initiating activity andamphiphilicity is taken as a raw material, and without adding additional small molecular emulsifiers or initiators, a hydrophobic cross-linking monomer is initiated to polymerize, so that polymer particles having a surface wrinkling morphology are obtained. Compared with an existing preparation method for polymer particles with wrinkling surfaces, the method is simple in system and technology, simple for post-processing, high in universality, low in cost and suitable for industrial mass production. The prepared polymer particles have wide application prospects in the fields of optical devices, drug loading systems, self-cleaning coatings, cell adhesion, super-hydrophobic materials, electronic self-assembly templates and the like due to a relatively large surface area and morphological controllability.

Description

technical field [0001] The invention belongs to a method for preparing polymer materials, and relates to a method for preparing surface wrinkled polymer particles. Background technique [0002] Polymer particles with complex wrinkle circuits on the surface are widely used in optical devices, drug-loading systems, self-cleaning coatings, cell adhesion, superhydrophobic materials and electronic self-assembly due to their large specific surface area and shape controllability templates etc. At present, a series of methods are applied to the preparation of surface wrinkled polymers, mainly including microfluidic technology, ultraviolet radiation method and suspension polymerization method. [0003] In the above preparation methods, microfluidic technology focuses on the construction of microfluidic channel systems to realize the control and operation of fluids at microscopic scales. The devices required for microfluidic systems include micropumps, microvalves, micromixers, micro...

Claims

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Application Information

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IPC IPC(8): C08F265/04C08F222/14C08F212/36C08F222/40C08F2/22
CPCC08F2/22C08F265/04C08F222/102C08F222/40
Inventor 张秋禹刘锦刘毅彬张宝亮张和鹏
Owner NORTHWESTERN POLYTECHNICAL UNIV
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