Unlock instant, AI-driven research and patent intelligence for your innovation.

A kind of water-based high temperature varnish that can be used for wet-on-wet process and preparation method thereof

A high-temperature varnish, wet-on-wet technology, applied in coatings, polyurea/polyurethane coatings, etc., can solve the problems of unsatisfactory performance and quality of water-based varnishes, unfavorable environmental protection, high product prices, etc., to save baking time and Energy consumption, saving pre-baking time, good impact resistance effect

Active Publication Date: 2020-06-02
GUANGDONG YATU CHEM
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Chinese patent CN102558981B discloses a high-temperature varnish, including a thermosetting acrylic resin, an anti-sag resin, an amino resin, an organic solvent, a catalyst and an auxiliary agent, wherein the thermosetting acrylic resin contains a thermosetting acrylic resin I, and the thermosetting acrylic resin I Glass transition temperature ≤ -5 degrees Celsius, hydroxyl value 50-120mgKOH / g, acid value 7.5-15, and the thermosetting acrylic resin accounts for 30-40% by weight of the total content of the high-temperature varnish, and the high-temperature varnish has high scratch resistance , however, its formula contains 10-25% organic solvents, which is not conducive to environmental protection
Although there are many influencing factors, in addition to the relatively high price of the product, the main problem is that the performance and quality of water-based varnishes are not satisfactory.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of water-based high temperature varnish that can be used for wet-on-wet process and preparation method thereof
  • A kind of water-based high temperature varnish that can be used for wet-on-wet process and preparation method thereof
  • A kind of water-based high temperature varnish that can be used for wet-on-wet process and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Embodiment 1, a kind of water-based high-temperature varnish that can be used for wet-on-wet process

[0036] The water-based high-temperature varnish that can be used in the wet-on-wet process is composed of the following components and their mass percentages: 50.9% of water-based polyurethane polyol dispersion, 1% of amine neutralizer, 10% of ethylene glycol butyl ether, methylated amino 15% resin, 5% closed polyurethane curing agent, 2% catalyst, 0.4% leveling agent, 0.2% defoamer, 0.5% basic wetting agent, 15% pure water; the catalyst is the amine of p-toluenesulfonic acid Saline solution; the leveling agent is composed of propylene glycol alginate and BYK leveling agent in a mass ratio of 1:25; the basic wetting agent is composed of polyether-siloxane copolymer and alkyl aryl polyether by mass The ratio is 8:3.

[0037] The preparation method of described closed type polyurethane curing agent is:

[0038] (1) get hexamethylene diisocyanate trimer, add nano sepiolit...

Embodiment 2

[0044] Embodiment 2, a kind of water-based high-temperature varnish that can be used for wet-on-wet process

[0045] The water-based high-temperature varnish that can be used in the wet-on-wet process is composed of the following components and their mass percentages: 69.4% of water-based polyurethane polyol dispersion, 1% of amine neutralizer, 5% of ethylene glycol butyl ether, methylated amino 10% resin, 3% closed polyurethane curing agent, 1% catalyst, 0.2% leveling agent, 0.1% defoamer, 0.3% basic wetting agent, 10% pure water; the catalyst is the amine of p-toluenesulfonic acid Saline solution; the leveling agent is composed of propylene glycol alginate and BYK leveling agent in a mass ratio of 3:22; the basic wetting agent is composed of polyether-siloxane copolymer and alkyl aryl polyether by mass The ratio is 12:3.

[0046] The preparation method of described closed type polyurethane curing agent is:

[0047] (1) get hexamethylene diisocyanate trimer, add nano sepiol...

Embodiment 3

[0053] Embodiment 3, a kind of water-based high-temperature varnish that can be used for wet-on-wet process

[0054] The water-based high-temperature varnish that can be used in the wet-on-wet process is composed of the following components and their mass percentages: 65% of water-based polyurethane polyol dispersion, 1.5% of amine neutralizer, 6% of ethylene glycol butyl ether, methyl etherified Amino resin 12%, closed polyurethane curing agent 3%, catalyst 1%, leveling agent 0.2%, defoamer 0.1%, basic wetting agent 0.4%, pure water 10.8%; The catalyst is p-toluenesulfonic acid Amine salt solution; the leveling agent is composed of propylene glycol alginate and BYK leveling agent in a mass ratio of 2:23; the basic wetting agent is composed of polyether-siloxane copolymer and alkyl aryl polyether The mass ratio is 9:4.

[0055] The preparation method of described closed type polyurethane curing agent is:

[0056] (1) get hexamethylene diisocyanate trimer, add nano sepiolite,...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
temperatureaaaaaaaaaa
Login to View More

Abstract

The invention belongs to the technical field of automobile coatings and particularly relates to high-temperature waterborne varnish applicable to a wet-to-wet process and a preparation method of the varnish. The high-temperature waterborne varnish applicable to the wet-to-wet process is prepared from components in percentage by mass as follows: 50%-70% of waterborne polyurethane polyol dispersoid,1%-2% of an amine neutralizer, 5%-10% of ethylene glycol butyl ether, 10%-15% of methylated amino resin, 3%-5% of an enclosed polyurethane curing agent, 1%-2% of a catalyst, 0.2%-0.4% of a levellingagent, 0.1%-0.2% of a defoaming agent, 0.3%-0.5% of a basic wetting agent and 10%-15% of pure water. The provided high-temperature waterborne varnish applicable to the wet-to-wet process has excellentperformance, has the all properties of a film reaching the level of oil varnish, has good weather fastness and stone impact resistance and is green and environmentally friendly.

Description

technical field [0001] The invention belongs to the technical field of automobile coatings, and in particular relates to a water-based high-temperature varnish which can be used in a wet-on-wet process and a preparation method thereof. Background technique [0002] Since the beginning of the 21st century, the world's important issues in the field of automotive coatings and coatings are to adapt to the requirements of the times: environmental protection, energy saving, resource saving, and reduction of coating costs on the basis of high quality, and reduction of VOC (volatile organic compounds) discharge volume. When the first coat of paint is not completely dry, the second coat is sprayed. This spraying process is called "wet on wet". The wet-on-wet process is a way to save energy and reduce work steps, but it is not suitable for all coatings. Traditional varnishes are dominated by solvent-based products. From the early phenolic paints, alkyd paints, nitro paints to the a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08G18/80C09D175/04C09D7/65
CPCC08G18/8003C08L2205/035C09D175/04C08L61/32
Inventor 冯兆华李海华李柏文李守康陈容爱
Owner GUANGDONG YATU CHEM