Soil conditioner for remediation of Cd/As combined pollution of paddy fields and preparation method thereof

A soil conditioner and compound pollution technology, which is applied in the field of soil conditioner and its preparation, can solve the problems of ecological balance, food quality and safety hazards, serious soil acidification area, and secondary pollution of farmland and cultivated land, so as to prevent damage to human body , Buffer the degree of soil acidification, and improve the effect of acidic soil

Inactive Publication Date: 2018-06-22
HUNAN INST OF AGRI ENVIRONMENT & ECOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (2) The area of ​​soil acidification is serious
[0005] (3) The problem of secondary non-point source pollution caused by low-efficiency heavy metal conditioners in paddy fields
There are some unreasonable abuses in the application of pesticides, fertilizers and conditioners in paddy fields
It is difficult to come up with an effective solution to the heavy metal compound polluted soil, which will cause secondary pollution to farmland to some extent
[0006] The cadmium and arsenic complex polluted acidic soil caused by the above problems has brought hidden dangers to ecological balance and food quality and safety. The existing conventional soil conditioners have certain limitations in stability and sustainability, and will greatly change the soil quality. The pH level will bring secondary pollution and compaction to the soil. Therefore, it is urgent to apply efficient and ecological soil conditioners and technologies.

Method used

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  • Soil conditioner for remediation of Cd/As combined pollution of paddy fields and preparation method thereof
  • Soil conditioner for remediation of Cd/As combined pollution of paddy fields and preparation method thereof
  • Soil conditioner for remediation of Cd/As combined pollution of paddy fields and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0061] A soil conditioner of the present invention comprises the following components in parts by mass: 39 parts of polyferric sulfate, 39 parts of activated silicate, 2 parts of ethylenediaminetetraacetic acid disodium salt, and 20 parts of superphosphate. Among them, the disodium salt of ethylenediaminetetraacetic acid is sodium zinc ethylenediaminetetraacetic acid (EDTA-Zn); the activated silicate is prepared by the following method: the silicate mineral and limestone are respectively crushed to 80 mesh, and then mixed evenly , and then calcined at 1000-1100 ° C to obtain activated silicate. The physical and chemical properties of the main components of the soil conditioner are shown in Table 3. The soil conditioner is in the form of mixed granules, and the percentage of granules with a particle diameter of 1mm-5.6mm is not less than 80%.

[0062] The physicochemical property of the main component of soil conditioner in table 3 embodiment 1

[0063]

[0064] The prepar...

Embodiment 2

[0067] A soil conditioner of the present invention comprises the following components in parts by mass: 39 parts of polyferric sulfate, 39 parts of activated silicate, 3 parts of ethylenediaminetetraacetic acid disodium salt, and 19 parts of superphosphate. Among them, the disodium salt of ethylenediaminetetraacetic acid is ethylenediaminetetraacetic acid sodium manganese (EDTA-Mn); the activated silicate is prepared by the following method: the silicate mineral and limestone are respectively crushed to 80 mesh, and then mixed evenly , and then calcined at 1000-1100 ° C to obtain activated silicate. The physical and chemical properties of the main components of the soil conditioner are shown in Table 4. The soil conditioner is in the form of mixed granules, and the percentage of granules with a particle diameter of 1mm-5.6mm is not less than 80%.

[0068] The physicochemical property of the main component of soil conditioner in table 4 embodiment 2

[0069]

[0070]

...

Embodiment 3

[0074] A soil conditioner of the present invention comprises the following components in parts by mass: 38 parts of polyferric sulfate, 38 parts of activated silicate, 4 parts of ethylenediaminetetraacetic acid disodium salt, and 20 parts of superphosphate. Among them, ethylenediaminetetraacetic acid disodium salt is 1 part of ethylenediaminetetraacetic acid sodium zinc (EDTA-Zn) and 3 parts of ethylenediaminetetraacetic acid manganese sodium (EDTA-Mn); the activated silicate is prepared by the following method : The silicate minerals and limestone are respectively crushed to 80 meshes, then mixed evenly, and then calcined at 1000-1100°C to obtain activated silicate. The physical and chemical properties of the main components of the soil conditioner are shown in Table 5. The soil conditioner is in the form of mixed granules, and the percentage of granules with a particle diameter of 1mm-5.6mm is not less than 80%.

[0075] The physicochemical property of the main component of...

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Abstract

The invention provides a soil conditioner for remediation of Cd / As combined pollution of paddy fields and a preparation method thereof. The soil conditioner comprises the following components in partsby weight: 20-60 parts of iron-containing sulfate, 20-60 parts of activated silicate, 0-40 parts of calcium superphosphate and 0-5 parts of disodium ethylenediamine tetraacetate. The preparation method of the soil conditioner comprises the following steps: (1) crushing the components respectively and carrying out sieving with an 80-mesh sieve; and (2) uniformly mixing and then granulating the sieved fine powder, carrying out drying until the moisture content is less than 5%, and finally carrying out detection to obtain a qualified finished product. The soil conditioner has a synchronous passivation effect on soil Cd / As pollution, and at the same time can effectively reduce the absorption of Cd / As by aboveground parts of crops, block heavy metals Cd and As from entering the food chain, prevent damages to human bodies, and promote protection and sustainable use of land resources. The preparation process of the soil conditioner is environment-friendly and feasible and has a low cost.

Description

technical field [0001] The invention belongs to the field of soil heavy metal pollution control, and in particular relates to a soil conditioner suitable for Cd / As composite polluted acidic soil, a preparation method and application thereof. Background technique [0002] With the continuous growth of the world's population and the acceleration of industrialization, as well as people's irrational use of the environment, the problem of soil pollution has become increasingly prominent, seriously threatening people's production and life. At present, the paddy field soil in southern my country mainly has the following safety factors that threaten the quality of soil resources and sustainable use: [0003] (1) Heavy metal pollution sources have increased. First, due to the rich mineral resources in the south, the discharge of industrial "three wastes" caused by human activities such as metallurgy and mining has intensified; second, with the increasing use of agricultural chemical...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K17/40C09K101/00
CPCC09K17/40C09K2101/00
Inventor 纪雄辉谢运河田发祥吴家梅彭华朱坚刘昭兵柳赛花官迪黄曦
Owner HUNAN INST OF AGRI ENVIRONMENT & ECOLOGY
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