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Plasma etching cleaning liquid, method for preparing same and application of plasma etching cleaning liquid

A technology of cleaning liquid and plasma, which is applied in the field of chemical reagents, can solve the problems that affect the cleaning effect of semiconductor devices, the circuit conduction effect, the large increase of particles, and the semiconductor devices that are easy to corrode.

Active Publication Date: 2018-08-07
SHANGHAI SINYANG SEMICON MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is to overcome the poor cleaning effect of the existing plasma etching cleaning solution, which is easy to corrode semiconductor devices, and is easy to agglomerate and produce particles during long-term placement and use, and the particle increase is large, which affects the cleaning effect and Defects in the conduction effect of semiconductor device circuits, and then provide a plasma etching cleaning solution, its preparation method and application

Method used

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  • Plasma etching cleaning liquid, method for preparing same and application of plasma etching cleaning liquid
  • Plasma etching cleaning liquid, method for preparing same and application of plasma etching cleaning liquid
  • Plasma etching cleaning liquid, method for preparing same and application of plasma etching cleaning liquid

Examples

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preparation Embodiment 1-9

[0061] Prepared plasma etching cleaning solution 1-9 according to the preparation method of above-mentioned plasma etching cleaning solution, wherein the composition and content of each cleaning solution are shown in Table 1; wherein cleaning solution 1-9 does not contain dispersant and Cyclodextrin modified alkylene glycol alkyl ether compound.

[0062] Table 1

[0063]

preparation Embodiment 11-19

[0091] The preparation examples 11-19 of the present invention are based on the cleaning liquid prepared in the aforementioned preparation examples 1-9, respectively added dispersant, the type and amount of the added dispersant and the amount of water are shown in Table 4, and the rest The components and contents remained unchanged, thus correspondingly obtained plasma etching cleaning solutions 11-19.

[0092] Table 4

[0093]

preparation Embodiment 21-29

[0100] Preparation Examples 21-29 of the present invention are based on the aforementioned cleaning solutions 11-19, respectively adding cyclodextrin-modified alkylene glycol alkyl ether compounds, and the added cyclodextrin-modified alkylene glycol alkyl The dosage of the base ether compound and the dosage of water are shown in Table 6, and the remaining components and contents remain unchanged, thus the plasma etching cleaning solutions 21-29 are correspondingly obtained.

[0101] Table 6

[0102]

[0103] Note 1: The mass content of p-toluenesulfonic acid mentioned in Table 6 refers to the percentage of the mass of p-toluenesulfonic acid to the total mass of substance A and cyclodextrin.

[0104] Note 2: In Examples 21-29, the reaction temperature and time of each step in the preparation of cyclodextrin-modified alkylene glycol alkyl ether compounds are shown in Table 7.

[0105] Table 7

[0106]

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Abstract

The invention discloses plasma etching cleaning liquid, a method for preparing the same and application of the plasma etching cleaning liquid. The plasma etching cleaning liquid is prepared from raw materials comprising dispersing agents, hydroxylamine compounds and / or salt of the hydroxylamine compounds, organic solvents, corrosion inhibitors, organic amine, cyclodextrin-modified alkylene diol alkyl ether compounds and water. The plasma etching cleaning liquid, the method and the application have the advantages that the plasma etching cleaning liquid can be used for cleaning etched and ashedsemiconductor chips; good cleaning effects can be realized by the plasma etching cleaning liquid, the plasma etching cleaning liquid is nearly free of agglomeration in long-term placing and using procedures, is basically free of particle generation and is low in metal and nonmetal corrosion speed, and accordingly the plasma etching cleaning liquid and the method have excellent industrial application and popularization prospects.

Description

technical field [0001] The invention relates to a chemical reagent used in semiconductor manufacturing process, in particular to a plasma etching cleaning solution, its preparation method and application. Background technique [0002] In the production process of semiconductor integrated circuits, it is necessary to deposit and form a plurality of patterned semiconductor layers, conductive layers and insulating material layers. A photoresist is applied on an inorganic substrate, a pattern is formed on the photoresist by exposure and subsequent development, and then the formed pattern is used as a mask. Parts of the inorganic substrate not masked by the photoresist pattern are etched by exposure to metal etching plasma to remove exposed metal to form fine circuits. After patterning, deposition and etching, the photoresist layer must be completely removed before the next process step. [0003] Plasma ashing can remove the photoresist, but leaves ashed residue on the substrat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03F7/42
CPCG03F7/426
Inventor 王溯蒋闯
Owner SHANGHAI SINYANG SEMICON MATERIALS
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