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Method for preparing slag-free PAC by means of high-efficiency emulsification shear stirring technology

An emulsifying shearing and technical technology, applied in chemical instruments and methods, aluminum chloride, aluminum halide, etc., can solve the problems of large amount of secondary hazardous waste sludge, increased production cost of enterprises, and increased cost of outsourced disposal. , to achieve the effect of realizing economic and environmental protection, low equipment investment cost, and ensuring sustainable development

Active Publication Date: 2018-08-28
CHANGZHOU WUJIN YOUBANG WATER PURIFICATION MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although this technology is clean, green and environmentally friendly, it can effectively prevent secondary pollution, make full use of waste resources, turn waste into treasure, and achieve the purpose of comprehensive utilization of waste recycling, ensuring the sustainable development of upstream enterprises and saving production costs. The dual benefits of economy and environmental protection have been realized, but this technology also has the following defects: (1) It needs to consume a large amount of mineral resources, and the scarcity of mineral resources has led to the skyrocketing price of raw materials, which eventually inevitably leads to enterprises Increase in production costs; (2) The amount of secondary hazardous waste sludge is large, difficult to handle, and easily causes secondary sludge, and at the same time increases the cost of outsourcing disposal by the enterprise; (3) The process operation is relatively complicated, and the dust in the production process Pollution is serious and can easily endanger human health

Method used

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  • Method for preparing slag-free PAC by means of high-efficiency emulsification shear stirring technology
  • Method for preparing slag-free PAC by means of high-efficiency emulsification shear stirring technology
  • Method for preparing slag-free PAC by means of high-efficiency emulsification shear stirring technology

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Combine 300g of industrial by-product waste hydrochloric acid (HCl mass fraction is 12.75%) and 100g of aluminum-containing sludge from the aluminum profile industry (Al 2 o 3 The mass fraction is 16.35%) to carry out acid-dissolution reaction, stirring and reacting at normal temperature and pressure for 1h until the aluminum-containing sludge is completely dissolved to obtain Al 2 o 3 Aluminum brine with a mass fraction of 4.09% and a HCl mass fraction of 0.79%; add 0.2g of TMT liquid heavy metal scavenger, stir and react for 0.5h, and let it settle for 2h to obtain a light yellow supernatant containing aluminum mother liquor water; take the supernatant 325g of liquid aluminum-containing mother liquor water was placed in an emulsification shear mixer for high-speed emulsification shear stirring, and at the same time slowly added 84g of liquid waste alkali (Al 2 o 3 The mass fraction is 18.62%, and the NaOH mass fraction is 24.47%) to adjust the degree of polymerizat...

Embodiment 2

[0028] 300g of industrial by-product waste hydrochloric acid (HCl mass fraction is 26.63%) and 100g of aluminum-containing sludge from the aluminum profile industry (Al 2 o 3 The mass fraction is 27.73%) to carry out the acid-dissolution reaction, stirring and reacting at normal temperature and pressure for 1.5h until the aluminum-containing sludge is completely dissolved to obtain Al 2 o 3 Aluminum brine with a mass fraction of 6.93% and a HCl mass fraction of 5.09%; add 0.4g of TMT liquid heavy metal scavenger, stir and react for 1 hour, and let it settle for 2.5 hours to obtain a light yellow supernatant liquid containing aluminum mother liquor; take the supernatant 327g of liquid aluminum-containing mother liquor water was placed in an emulsifying shear mixer for high-speed emulsifying shear stirring, and at the same time slowly added 120g of liquid waste alkali (Al 2 o 3 The mass fraction is 18.62%, and the NaOH mass fraction is 24.47%) to adjust the degree of polymeri...

Embodiment 3

[0030] 300g of industrial by-product waste hydrochloric acid (HCl mass fraction is 23.88%) and 100g of aluminum-containing sludge from the aluminum profile industry (Al 2 o 3 The mass fraction is 26.31%) to carry out the acid-dissolution reaction, stirring and reacting at normal temperature and pressure for 2h until the aluminum-containing sludge is completely dissolved to obtain Al 2 o 3 Aluminum brine with a mass fraction of 6.58% and a HCl mass fraction of 3.79%; add 0.8g of TMT liquid heavy metal scavenger, stir and react for 1 hour, and let it settle for 3 hours to obtain a light yellow supernatant liquid containing aluminum mother liquor; take the supernatant 299g of aluminum-containing mother liquor water is placed in an emulsifying shear mixer for high-speed emulsifying shear stirring, and at the same time slowly add 120g of liquid waste alkali (Al 2 o 3 The mass fraction is 18.62%, and the NaOH mass fraction is 24.47%) to adjust the degree of polymerization of the ...

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Abstract

The invention provides a method for preparing slag-free PAC by means of a high-efficiency emulsification shear stirring technology. The method comprises the steps of acid dissolution, recapturing andemulsification shear stirring. The method has the advantages that waste alkali is used for replacing traditional bauxite resources, dust pollution is avoided, no secondary hazardous waste is generated, and the quality of products is ensured; the PAC is quickly prepared by means of the novel high-efficiency emulsification shear mixing technology, the operation is simple, the processing capacity islarge, the production cycle is short, the yield is high, the energy consumption is low, the equipment investment cost is low, and the cost is low. Regeneration and comprehensive utilization of resources including aluminum-containing sludge, waste hydrochloric acid and waste alkali are achieved, waste is turned into treasure, sustainable development of upstream enterprises is ensured, the production cost of the enterprises is saved, and double benefits of economy and environmental protection are achieved. The prepared slag-free PAC is pure, clear, stable in quality, good in fluidity and dispersibility and capable of achieving higher basicity, and the decolorization and turbidity removal capabilities of the PAC are 5-10% times higher than those of general PACs sold on the market.

Description

technical field [0001] The invention relates to the technical field of comprehensive utilization of solid waste disposal and resource regeneration, relates to the technical transformation of a slag-free PAC in the technical field of sewage treatment, and specifically relates to a method for preparing a slag-free PAC using a high-efficiency emulsification shear stirring technology. Background technique [0002] Polyaluminum chloride is a water purification material, inorganic polymer coagulant, also referred to as polyaluminum, English abbreviation is PAC, the molecular weight produced due to the bridging effect of hydroxide ions and the polymerization of polyvalent anions Larger, higher charge inorganic polymer water treatment agent. The fundamental difference between polyaluminum chloride and traditional inorganic coagulants is that traditional inorganic coagulants are low-molecular crystalline salts, while the structure of polyaluminum chloride is composed of polyvalent ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01F7/56C02F1/52
CPCC01F7/56C02F1/5236
Inventor 左选凤居银栋蒋银峰王桂玉
Owner CHANGZHOU WUJIN YOUBANG WATER PURIFICATION MATERIALS
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