Method for preparing slag-free PAC by means of high-efficiency emulsification shear stirring technology
An emulsifying shearing and technical technology, applied in chemical instruments and methods, aluminum chloride, aluminum halide, etc., can solve the problems of large amount of secondary hazardous waste sludge, increased production cost of enterprises, and increased cost of outsourced disposal. , to achieve the effect of realizing economic and environmental protection, low equipment investment cost, and ensuring sustainable development
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Embodiment 1
[0026] Combine 300g of industrial by-product waste hydrochloric acid (HCl mass fraction is 12.75%) and 100g of aluminum-containing sludge from the aluminum profile industry (Al 2 o 3 The mass fraction is 16.35%) to carry out acid-dissolution reaction, stirring and reacting at normal temperature and pressure for 1h until the aluminum-containing sludge is completely dissolved to obtain Al 2 o 3 Aluminum brine with a mass fraction of 4.09% and a HCl mass fraction of 0.79%; add 0.2g of TMT liquid heavy metal scavenger, stir and react for 0.5h, and let it settle for 2h to obtain a light yellow supernatant containing aluminum mother liquor water; take the supernatant 325g of liquid aluminum-containing mother liquor water was placed in an emulsification shear mixer for high-speed emulsification shear stirring, and at the same time slowly added 84g of liquid waste alkali (Al 2 o 3 The mass fraction is 18.62%, and the NaOH mass fraction is 24.47%) to adjust the degree of polymerizat...
Embodiment 2
[0028] 300g of industrial by-product waste hydrochloric acid (HCl mass fraction is 26.63%) and 100g of aluminum-containing sludge from the aluminum profile industry (Al 2 o 3 The mass fraction is 27.73%) to carry out the acid-dissolution reaction, stirring and reacting at normal temperature and pressure for 1.5h until the aluminum-containing sludge is completely dissolved to obtain Al 2 o 3 Aluminum brine with a mass fraction of 6.93% and a HCl mass fraction of 5.09%; add 0.4g of TMT liquid heavy metal scavenger, stir and react for 1 hour, and let it settle for 2.5 hours to obtain a light yellow supernatant liquid containing aluminum mother liquor; take the supernatant 327g of liquid aluminum-containing mother liquor water was placed in an emulsifying shear mixer for high-speed emulsifying shear stirring, and at the same time slowly added 120g of liquid waste alkali (Al 2 o 3 The mass fraction is 18.62%, and the NaOH mass fraction is 24.47%) to adjust the degree of polymeri...
Embodiment 3
[0030] 300g of industrial by-product waste hydrochloric acid (HCl mass fraction is 23.88%) and 100g of aluminum-containing sludge from the aluminum profile industry (Al 2 o 3 The mass fraction is 26.31%) to carry out the acid-dissolution reaction, stirring and reacting at normal temperature and pressure for 2h until the aluminum-containing sludge is completely dissolved to obtain Al 2 o 3 Aluminum brine with a mass fraction of 6.58% and a HCl mass fraction of 3.79%; add 0.8g of TMT liquid heavy metal scavenger, stir and react for 1 hour, and let it settle for 3 hours to obtain a light yellow supernatant liquid containing aluminum mother liquor; take the supernatant 299g of aluminum-containing mother liquor water is placed in an emulsifying shear mixer for high-speed emulsifying shear stirring, and at the same time slowly add 120g of liquid waste alkali (Al 2 o 3 The mass fraction is 18.62%, and the NaOH mass fraction is 24.47%) to adjust the degree of polymerization of the ...
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