A preparation method of gel-modified anti-fog film material
A film material and modification technology, applied in the field of preparation of gel-modified anti-fog film materials, can solve the problems of poor mechanical properties and durability of anti-fog film materials, improve the hydrophobic and anti-fog performance of the film, and achieve excellent compatibility. properties, excellent hydrophobicity
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example 1
[0018] According to the mass ratio of 1:10, chitosan was added to the mass fraction of 0.5% hydrochloric acid, stirred and mixed to obtain a mixed solution, and carbon nanotubes were added to the mixed solution according to a mass ratio of 1:5, and ultrasonically dispersed at 200W for 10 minutes. The dispersion was obtained, and the mass fraction of 1% sodium glycerophosphate solution was added dropwise to the dispersion according to the mass ratio of 1:15, and the dropping rate was controlled at 2mL / min. The disodium-sodium dihydrogen phosphate buffer solution adjusted the pH to 6.5 to obtain the modified solution and heated it in a water bath at 35°C for 2h, let it cool down to room temperature and placed it at 45°C for 20h to obtain the modified gel solution, In parts by weight, weigh 25 parts of methyl acrylate, 65 parts of modified gel solution, 10 parts of styrene and 1 part of potassium persulfate in a three-necked flask, stir and mix, and heat in a water bath at 75°C fo...
example 2
[0020] According to the mass ratio of 1:10, chitosan was added to the mass fraction of 0.5% hydrochloric acid, stirred and mixed to obtain a mixed solution, and carbon nanotubes were added to the mixed solution according to a mass ratio of 1:5, and ultrasonically dispersed at 300W for 15 minutes. The dispersion was obtained, and the mass fraction of 1% sodium glycerophosphate solution was added dropwise to the dispersion according to the mass ratio of 1:15, and the dropping rate was controlled at 3mL / min. The disodium-sodium dihydrogen phosphate buffer solution adjusted the pH to 6.5 to obtain a modified solution, which was heated in a water bath at 37°C for 3 hours, left to cool to room temperature, and left to stand at 50°C for 24 hours to obtain a modified gel solution. In parts by weight, weigh 30 parts of methyl acrylate, 70 parts of modified gel solution, 15 parts of styrene and 2 parts of potassium persulfate in a three-necked flask, stir and mix, and heat in a water bat...
example 3
[0022] According to the mass ratio of 1:10, chitosan was added to the mass fraction of 0.5% hydrochloric acid, stirred and mixed to obtain a mixed solution, and carbon nanotubes were added to the mixed solution according to the mass ratio of 1:5, and ultrasonically dispersed at 250W for 12min. The dispersion was obtained, and the mass fraction of 1% sodium glycerophosphate solution was added dropwise to the dispersion according to the mass ratio of 1:15, and the dropping rate was controlled at 2mL / min. The disodium-sodium dihydrogen phosphate buffer solution adjusted the pH to 6.5 to obtain a modified solution, which was heated in a water bath at 36°C for 2 hours, allowed to cool down to room temperature, and placed at 47°C for 22 hours to obtain a modified gel solution. In parts by weight, weigh 27 parts of methyl acrylate, 67 parts of modified gel solution, 12 parts of styrene and 2 parts of potassium persulfate in a three-necked flask, stir and mix, and heat in a water bath ...
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