A kind of secondary battery and preparation method thereof
A secondary battery and electrolyte technology, applied in secondary batteries, battery electrodes, circuits, etc., can solve the problems of unsatisfactory electrochemical performance of potassium ion batteries, limited lithium resource reserves, complex processes, etc., and achieve a good charge-discharge cycle. performance, suitable for large-scale production, and the effect of simple process
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[0044] Correspondingly, an embodiment of the present invention also provides a method for preparing the above-mentioned secondary battery, including the following steps:
[0045] (1) Prepare the positive electrode: provide a positive electrode current collector with a clean surface, weigh the positive electrode active material, conductive agent and binder in a certain proportion, add an appropriate solvent and fully mix to form a uniform slurry; then apply the slurry evenly on the On the surface of the positive electrode current collector, a positive electrode active material layer is formed, and after being completely dried, it is pressed and cut to obtain a battery positive electrode of the desired size;
[0046] (2) Prepare the negative electrode: cut the metal foil into the required size, clean and dry the surface to obtain the negative electrode;
[0047] (3) Electrolyte preparation: Weigh a certain amount of potassium salt electrolyte and add it into the non-aqueous solv...
Embodiment 1
[0054] A method for preparing a secondary battery, comprising the steps of:
[0055] (1) Preparation of battery negative electrode: take tin foil with a thickness of 0.02 mm, cut it into discs with a diameter of 12 mm, clean the surface of the tin foil with ethanol, dry it and use it as a negative electrode for later use;
[0056] (2) Preparing the diaphragm: cutting the glass fiber film into discs with a diameter of 16 mm as a diaphragm for subsequent use;
[0057] (3) Preparation of electrolyte: weigh 3g of potassium hexafluorophosphate (KPF 6 ) into a mixed solvent of 5mL ethylene carbonate, dimethyl carbonate and ethyl methyl carbonate (the volume ratio of the three is 4:3:2), stir until potassium hexafluorophosphate is completely dissolved, and then add a mass fraction of 5% The fluoroethylene carbonate is used as an additive, and the electrolyte solution is obtained after being fully stirred evenly;
[0058] (4) Preparation of battery positive electrode: Add 0.8g of ex...
Embodiment 2-10
[0072] The only difference between Example 2-10 and Example 1 is that the material selection of the negative electrode is different, as shown in Table 2. The secondary battery obtained in Example 2-12 was subjected to a constant current charge and discharge test, and the results are shown in Table 2. Show:
[0073] Table 2
[0074]
[0075] It can be seen from Table 2 that when tin foil is used as the negative electrode, the specific capacity of the battery is higher, the cycle performance is better, and the energy density is the highest.
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