Gangue based medium and high temperature phase change heat storage material and preparation method
A phase change heat storage material and phase change material technology are applied in the field of medium and high temperature phase change heat storage materials and preparation based on coal gangue, which can solve the problems of environmental pollution, waste of resources, occupying large land, etc. Easy to transport and install, low cost effect
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Embodiment 1
[0025] The coal gangue-based eutectic carbonate phase change heat storage material was prepared by the following steps:
[0026] (1) Pulverize, grind, and dry coal gangue, and dry sodium carbonate and potassium carbonate at 90°C for 4 hours;
[0027] (2) In terms of mass fraction, weigh 35 parts of coal gangue with powder particle diameter<20 μm respectively after drying in step (1), and 55 parts of eutectic carbonate with particle diameter<80 μm including sodium carbonate and potassium carbonate, fully Grind until well blended;
[0028] (3) Keep the mixed powder obtained in step (2) under the pressure of 20MPa for 30s, press the inner groove of the mold into a cylindrical shape; then sinter: from room temperature to 250°C at a rate of 5°C / min ℃ for 1 hour, then heated up to 400°C at a rate of 5°C / min, then raised to 640°C at a rate of 3°C / min, and finally raised to 750°C at a rate of 5°C / min, kept for 2 hours, and then After cooling, the eutectic carbonate phase change heat...
Embodiment 2
[0031] The coal gangue-based eutectic carbonate phase change heat storage material with the addition of ceramic framework materials was prepared by the following steps:
[0032] (1) Crush, grind, and dry coal gangue, and dry magnesium oxide at 100°C for 4 hours, and dry sodium carbonate and potassium carbonate at 90°C for 4 hours;
[0033] (2) In terms of mass fraction, weigh 35 parts of coal gangue with a particle size of <20 μm after drying in step (1), 10 parts of magnesium oxide with a particle size of <80 μm, and eutectic carbonate with a particle size of <80 μm, including: Totally 55 parts of sodium carbonate and potassium carbonate, fully ground until uniformly mixed;
[0034] (3) Keep the mixed powder obtained in step (2) under the pressure of 20MPa for 30s, press the inner groove of the mold into a cylindrical shape; then sinter: from room temperature to 250°C at a rate of 5°C / min ℃ for 1 hour, then heated up to 400°C at a rate of 5°C / min, then raised to 640°C at a r...
Embodiment 3
[0037] The coal gangue-based eutectic carbonate phase change heat storage material with the addition of ceramic framework materials and modified materials was prepared by the following steps:
[0038] (1) Pulverize, grind, and dry coal gangue, and dry magnesium oxide and clay at 100°C for 4 hours, and dry the eutectic salt composed of sodium carbonate and potassium carbonate at 90°C for 4 hours;
[0039](2) In terms of mass fraction, weigh 25 parts of coal gangue with a particle size of <20 μm after drying in step (1), 10 parts of magnesium oxide with a particle size of <80 μm, 10 parts of clay, and eutectic carbon with a particle size of <80 μm Acid salts include 55 parts of sodium carbonate and potassium carbonate, fully grind until uniformly mixed, and age for 8 hours;
[0040] (3) Keep the mixed powder obtained in step (2) under the pressure of 30MPa for 30s, press the inner groove of the mold into a cylindrical shape; ℃ for 1 hour, then heated up to 400°C at a rate of 5°...
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