Moisturizing type cigarette paper and preparation method thereof

A technology of cigarette paper and organic solvent, which is applied in the field of preparation of moisture-retaining cigarette paper technology, can solve the problems of high porosity, low adsorption capacity, high specific surface area, etc., achieve good promotion and application significance, and reduce dryness and irritation Sexuality and good practical value

Active Publication Date: 2018-11-30
CHINA TOBACCO HENAN IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Porous materials such as zeolites, silica gels, and metal-organic frameworks (MOFs) can adsorb water molecules from the air over a wide range of humidity, but conventional zeolites or silica gels either have low water adsorption capacity or require relatively high High energy is needed to release the adsorbed water molecules
Due to its highly ordered multi-dimensional network structure, high porosity, high specific surface area, and easy structure adjustment, MOFs materials have been widely used in gas storage, drug sustained release, catalysis, dehumidification and other fields. However, There is no report on its application to cigarette paper moisture retention

Method used

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  • Moisturizing type cigarette paper and preparation method thereof
  • Moisturizing type cigarette paper and preparation method thereof
  • Moisturizing type cigarette paper and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Preparation of MOF-Zr material A: Take 5.8 g of fumaric acid (fumaric acid) and 16 g of zirconyl chloride octahydrate in a mixed solution of N,N-dimethylformamide and formic acid, where N , the volumes of N-dimethylformamide and formic acid were 210 mL and 70 mL respectively, and reacted at 130 °C for 6 h at a constant temperature. After cooling to room temperature, the products were separated by centrifugation, and the products were washed with fresh N,N-dimethylformamide and methanol were washed 3 times respectively, soaked in anhydrous N,N-dimethylformamide for three days, changed the solvent once a day, and then soaked in deionized water for three days to exchange the remaining N,N in the molecular pores. Finally, N-dimethylformamide molecules were soaked in anhydrous methanol for three days to exchange the remaining water molecules in the molecular pores, centrifuged, and the obtained precipitate was dried at a constant temperature of 150°C for 24 hours to remove th...

Embodiment 2

[0025] The difference between the preparation of MOF-Zr material B and Example 1 is that the metal zirconium salt is 11.6 g of zirconyl nitrate, and the reaction time is 12 h.

[0026] In the preparation of cigarette paper, the amount of MOF-Zr material B added was 8% of the mass of cigarette paper.

Embodiment 3

[0028] The difference between the preparation of MOF-Zr material C and Example 1 is that the metal zirconium salt is 11.7 g of zirconium tetrachloride, and the reaction time is 12 h.

[0029] For the preparation of cigarette paper, the amount of MOF-Zr material C added is 6% of the mass of the cigarette paper, (see figure 1 ),From figure 1 It can be seen that the structures of MOF-Zr materials A, B, and C are basically the same, and the anions of metal salts have no effect on the material structure.

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PUM

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Abstract

The invention belongs to the technical field of cigarette paper preparation, and particularly relates to a moisturizing type cigarette paper and a preparation method thereof. The cigarette paper comprises a cigarette paper base material and an MOF-Zr material which is uniformly dispersed in the base material, wherein the addition amount of the MOF-Zr material accounts for 5-10% of the mass of thecigarette paper. The MOF-Zr material with the moisture is added into the cigarette paper, so that the novel moisturizing type cigarette paper disclosed by the invention can be obtained. A cigarette smoking experiment prepared by using the cigarette paper shows that the moisture release amount in the flue gas is well adjusted, the drying feeling and the irritation of the smoke during smoking are reduced, and the good moisturizing effect is achieved. In addition, Fumaric acid in the MOF-Zr material can bond the grey pieces after cigarette burning together, so that the cigarettes are not easy toscatter, thus a good ash-wrapping effect is achieved, the carbon line is narrow, no peculiar smell is generated, and harm to a human body is avoided, so that the cigarette paper and the method has good practical value and popularization and application significance.

Description

technical field [0001] The invention belongs to the technical field of cigarette paper preparation, and in particular relates to a moisture-retaining cigarette paper technology and a preparation method thereof. Background technique [0002] Cigarette paper is one of the important auxiliary materials in cigarette production. It directly participates in the burning of cigarettes and has a very important impact on the burning speed of cigarettes, the amount of harmful components released in mainstream smoke, the taste of smoking and the appearance of cigarette products. In addition, the mainstream smoke of cigarettes The moisture content in cigarettes is also an important index affecting the sensory comfort of cigarettes, and directly affects the intrinsic quality of cigarettes. If the moisture content of the smoke is appropriate, the smoke will be soft and delicate, less irritating, and better in sensory comfort. If the moisture content of the smoke is too low, the smoke will ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G83/00D21F11/00D21H17/46D21H21/14D21H27/00
CPCC08G83/008D21F11/00D21H17/46D21H21/14D21H27/00
Inventor 楚文娟田海英鲁平胡少东冯晓民高明奇李明哲顾亮纪朋席高磊李怀奇冯颖杰
Owner CHINA TOBACCO HENAN IND
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