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Multi-stage photocatalytic antimicrobial membrane reactor

A photocatalytic reaction and reactor technology, applied in chemical instruments and methods, water/sewage multi-stage treatment, light water/sewage treatment, etc., can solve the problems of poor flexibility of composite materials, complicated preparation methods, and easy peeling of catalysts, etc. To achieve efficient purification treatment, improve the effect of reaction efficiency

Inactive Publication Date: 2018-12-14
DONGHUA UNIV
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Problems solved by technology

[0006] The reaction membrane of a common integrated membrane reactor is formed by mixing catalytic materials into a fixed carrier, such as embedding catalytic materials in glass, stainless steel, fibers or carbon nanotubes, etc., but these immobilization methods have various Such problems as easy peeling off of the catalyst, poor compatibility, and poor flexibility of composite materials, etc. For example, patent CN103936097A discloses a method for degrading methyl orange with a perovskite / polysaccharide composite photocatalyst. The preparation method is complicated and requires 700°C At the same time, although the stability of the composite material is not mentioned in the article, the compatibility between the inorganic particles and the polymer material in this state is poor, the catalyst is very easy to fall off, and it is difficult to reuse

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Examples

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Embodiment 1

[0042] A multi-stage photocatalytic antibacterial membrane reactor, the schematic diagram of which is as follows figure 1 As shown, it includes an outer shell 5 and a reaction tank, the reaction tank is arranged in the outer shell 5 and is separated into a first-level purification tank 4 and a second-level purification tank 7 by a vertically arranged filter screen 6, and the second-level purification tank 7 is provided with LED simulation. Light source 9 and photocatalytic reaction gel film 10;

[0043] The bottom of the first-level purification tank 4 is filled with an activated carbon filter layer 8, and the bottom of the first-level purification tank 4 is connected with a sewage inlet pipe 2 and a pneumatic pipe. The outer end of the pneumatic pipe is connected to the air pump 12, and the pneumatic pipe penetrates into the first-level purification tank. The part of 4 is provided with aeration holes 3, the end of the sewage inlet pipe 2 is buried in the activated carbon filt...

Embodiment 2

[0047] A multi-stage photocatalytic antibacterial film reactor, the structure of the reactor is basically the same as that of Example 1, the difference is that the photocatalytic reaction gel film is mainly composed of a polymer hydrogel film with a water absorption rate of 92% and a photocatalytic reaction gel film. The composition of the reaction system, the content of the photocatalytic reaction system in the photocatalytic reaction gel film is 2.47wt%, the polymer hydrogel film contains adsorption sites, the adsorption sites adsorb the photocatalytic reaction system and fix it in the pores, Polymer hydrogel films contain non-strongly adsorbing polar groups -COO - , -COO - The non-strong adsorption polar group region is formed, wherein the material of the polymer hydrogel film is sodium alginate, and the photocatalytic reaction system is mainly composed of nano-silver and free ammonium oleate complex alkyl chains and adsorption on the nano-scale. The silver surface is comp...

Embodiment 3

[0050] A multi-stage photocatalytic antibacterial film reactor, the structure of the reactor is basically the same as that of Example 1, the difference is that the photocatalytic reaction gel film is mainly composed of a polymer hydrogel film with a water absorption rate of 90% and a photocatalytic reaction gel film. The composition of the reaction system, the content of the photocatalytic reaction system in the photocatalytic reaction gel film is 2.38wt%, the polymer hydrogel film contains adsorption sites, and the adsorption sites adsorb the photocatalytic reaction system and fix it in the pores, Polymer hydrogel films contain non-strongly adsorbing polar groups -COO - , -COO - A non-strong adsorption polar group region is formed; wherein, the material of the polymer hydrogel film is sodium carboxymethyl cellulose, and the photocatalytic reaction system is mainly composed of nano-silver and the alkyl chain of the free ammonium oleate complex. The coating layer is formed by ...

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Abstract

The invention relates to a multi-stage photocatalytic antimicrobial membrane reactor, comprising a reaction cell, wherein the reaction cell is separated by a vertically arranged filtering mesh into afirst-level purifying cell and a second-level purifying cell, a light source is arranged in the second-level purifying cell, and a photocatalytic reaction gel film is arranged in the second-order purifying cell, the photocatalytic reaction gel film comprises a photocatalytic reaction site and a polar group, the surrounding region of the photocatalytic reaction site is a high-adsorption polar groupregion, each charge in the high-adsorption polar group region and a non-high-adsorption polar group region is positive or negative, the potential of the high-adsorption polar group region is higher than that of the non-high-adsorption polar group region, and the high-adsorption polar group region is formed by high-adsorption polar groups, or weak-adsorption groups in a gathering manner. The reactor disclosed by the invention can be used for deeply treating particles, bacteria, gel and toxic substances in sewage, and degrading most of organic matters in the sewage, so as to achieve the efficient sewage purification, thus having the great promotion value.

Description

technical field [0001] The invention belongs to the field of sewage treatment, and relates to a multistage photocatalytic antibacterial membrane reactor. Background technique [0002] In recent years, with the rapid development of my country's economy and the continuous growth of the population, a large number of pollutants have been discharged into surface water ecosystems such as rivers and lakes, resulting in the destruction of the ecological environment of the river basin and seriously restricting the sustainable development of economy and society. affect people's quality of life. Sewage treatment technology and its engineering applications have become an essential part of maintaining social and economic sustainable development. [0003] For water pollution problems, traditional treatment methods include oxidation, adsorption and biological methods. The oxidation method is mainly divided into liquid chlorine disinfection, chlorine dioxide disinfection and ozone oxidatio...

Claims

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Application Information

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IPC IPC(8): C02F9/08
CPCC02F1/001C02F1/283C02F1/30C02F9/00
Inventor 孙宾纪晓寰朱美芳曾婷杨升元邓锋
Owner DONGHUA UNIV
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