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Multi-polymer composite conductive additive and preparation method thereof

A composite conductive and additive technology, used in conductive materials, conductive materials, cable/conductor manufacturing, etc., can solve problems such as low stability of finished products, poor solubility, and difficulty in ensuring the quality of polythiophene, and achieve good conductivity. Excellent comprehensive performance

Inactive Publication Date: 2018-12-21
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] There are few reports on the combination of unsubstituted thiophene and inorganic materials, all of which are compounded in organic solvents (chloroform) or thiophene directly with montmorillonite at the boiling point of thiophene; unsubstituted polythiophene has poor solubility in water, Usually in organic solvents such as chloroform or by electrochemical polymerization, when thiophene is polymerized in chloroform solvent, it is often necessary to evaporate the chloroform or dispose of it by other means, which increases the time and cost of the reaction, which is not conducive to industrialization; and When electrochemical polymerization, it is necessary to seek a suitable solvent, and there are too many variable factors, it is difficult to guarantee the quality of polythiophene, and the industrialization is also limited; the compatibility of inorganic fillers and polythiophene is poor, and the stability of the finished product is low, so The purpose of the present invention is to endow the composite material with new functions on the basis of improving the stability and compatibility of polythiophene and inorganic fillers, so as to enhance its applicability in different fields

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A kind of multi-polymer composite conductive additive, it is made up of the raw material of following weight part:

[0025] Thiophene 50, aniline 100, ferric chloride hexahydrate 1.8, ammonium persulfate 4, stannous sulfide 0.3, beeswax 4, alkenyl succinic anhydride 3, calcium ricinoleate 1, tert-butyl hydrodiphenol 0.7, nano-dispersion 10.

[0026] Described nano dispersion liquid is made up of the raw material of following parts by weight:

[0027] Nano silicon dioxide 20, hydroxyethyl cellulose 3, trimethylolpropane 1, sorbitan monooleate 0.8.

[0028] The preparation method of described nanometer dispersion liquid, comprises the following steps:

[0029] (1) Get hydroxyethyl cellulose, add it in the isopropanol of 16 times of its weight, insulate and stir at 60 ℃ for 10 minutes, obtain inositol solution;

[0030] (2) Get nanometer silicon dioxide, sorbitan monooleate and mix, join in the deionized water of 30 times of weight of mixture, ultrasonic 20 minutes, obt...

Embodiment 2

[0041] A kind of multi-polymer composite conductive additive, it is made up of the raw material of following weight part:

[0042] Thiophene 60, aniline 120, ferric chloride hexahydrate 2, ammonium persulfate 5, stannous sulfide 1, beeswax 7, alkenyl succinic anhydride 4, calcium ricinoleate 2, tert-butyl hydrodiphenol 1, nano-dispersion 18.

[0043] Described nano dispersion liquid is made up of the raw material of following parts by weight:

[0044] Nano silicon dioxide 30, hydroxyethyl cellulose 4, trimethylol propane 2, sorbitan monooleate 1.

[0045] The preparation method of described nanometer dispersion liquid, comprises the following steps:

[0046] (1) Take hydroxyethyl cellulose, add it to 20 times of its weight in isopropanol, keep stirring at 65°C for 30 minutes to obtain inositol solution;

[0047] (2) Get nano silicon dioxide, sorbitan monooleate and mix, join in the deionized water of 40 times of weight of mixture, ultrasonic 30 minutes, obtain silicon dioxi...

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PUM

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Abstract

The invention discloses a multi-polymer composite conductive additive comprising the following raw materials, by weight: 50 to 60 parts of thiophene, 100 to 120 parts of aniline, 1.8 to 2 parts of ferric chloride hexahydrate, 4 to 5 parts of ammonium persulfate, 0.3 to 1 part of stannous sulfide, 4 to 7 parts of beeswax, 3 to 4 parts of alkenyl succinic anhydride, 1 to 2 parts of calcium ricinoleate, 0. 7 to 1 part of tert-butyl hydroquinone, and 10 to 18 parts of nanodispersion. The materials employed by the finished product have the high electrical conductivity stability and the multi-polymer composite conductive additive has excellent comprehensive performance.

Description

technical field [0001] The invention belongs to the field of conductive materials, and in particular relates to a multi-polymer composite conductive additive and a preparation method thereof. Background technique [0002] There are few reports on the combination of unsubstituted thiophene and inorganic materials, all of which are compounded in organic solvents (chloroform) or thiophene directly with montmorillonite at the boiling point of thiophene; unsubstituted polythiophene has poor solubility in water, Usually in organic solvents such as chloroform or by electrochemical polymerization, when thiophene is polymerized in chloroform solvent, it is often necessary to evaporate the chloroform or dispose of it by other means, which increases the time and cost of the reaction, which is not conducive to industrialization; and When electrochemical polymerization, it is necessary to seek a suitable solvent, and there are too many variable factors, it is difficult to guarantee the q...

Claims

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Application Information

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IPC IPC(8): H01B1/12H01B13/00
CPCH01B1/124H01B1/127H01B1/128H01B13/00
Inventor 查公祥
Owner 查公祥
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