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A method for preparing a wear-resistant layer on a magnesium-based surface of a graphene oxide alloy by laser cladding

A laser cladding and wear-resistant layer technology, applied in metal material coating process, coating and other directions, can solve the problems of lack of preparation technology of graphene oxide-plated wear-resistant layer, high powder waste, long production cycle, etc. The effect of reducing delamination, improving surface hardness, and low risk factor

Active Publication Date: 2019-11-15
NANCHANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In fact, due to the limitations of electroless plating, this method is more harmful to the human body, and it also needs to carboxylate graphene separately, which has a long production cycle. At the same time, it uses the powder spraying sintering method, which has a high degree of waste for this type of powder and has certain limitations
[0008] Therefore, there is still a lack of a cost-effective preparation technology for the preparation of a graphene oxide wear-resistant layer on the surface of magnesium-based materials.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Graphene oxide was ultrasonically pre-dispersed in analytical pure ethanol for 1 h, the temperature was at room temperature, and no water vapor was controlled throughout the process. The volume ratio was strictly controlled at 0.2:50, and then the resulting dispersion was poured into a precursor solution consisting of glycerol and tetraisopropyl titanate, sealed and sonicated for 1 hour. Among them, the volume ratio of glycerol and tetraisopropyl titanate is 10:0.4. Carry out hydrothermal treatment afterwards, wherein the volume of suspension liquid accounts for 50% of reactor volume. Then put it into the reaction furnace to heat, raise the temperature to 90°C at 5°C / min, keep it for 2h, then raise the temperature to 180°C at 3°C / min, and keep it for 10h. Cool in air after taking out the reactor. The resulting solution was taken out, centrifuged, and centrifuged several times by pouring analytical pure ethanol until the solution was colorless. The whole process is se...

Embodiment 2

[0031]Graphene oxide was ultrasonically pre-dispersed in analytical pure ethanol for 3 hours, the temperature was at room temperature, and no water vapor was controlled throughout. The volume ratio was strictly controlled at 0.2:50, and then the resulting dispersion was poured into a precursor solution consisting of glycerol and tetraisopropyl titanate, sealed and sonicated for 1 hour. Among them, the volume ratio of glycerol and tetraisopropyl titanate is 10:0.8. Carry out hydrothermal treatment afterwards, wherein the volume of suspension liquid accounts for 50% of reactor volume. Then put it into the reaction furnace to heat, raise the temperature to 90°C at 3°C / min, keep it for 1h, then raise the temperature to 180°C at 2°C / min, and keep it for 12h. Cool in air after taking out the reactor. The resulting solution was taken out, centrifuged, and centrifuged several times by pouring analytical pure ethanol until the solution was colorless. The whole process is sealed to e...

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PUM

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Abstract

The invention discloses a method for preparing a graphene oxide alloy magnesium-based surface abrasion-resistant layer by laser cladding. The method includes the steps: adsorbing Ti ions under the action of functional groups of graphene oxide by the aid of high hydrothermal pressure in an environment without water, and acquiring anatase GO@TiO2 (anatase) in final-period baking; adjusting and mixing the acquired powder, fine Fe powder, Al2O3 particles, Si powder and glycerol according to a certain proportion to obtain adhesive mixed powder; grinding a substrate magnesium alloy plate by the aidof abrasive paper, and uniformly coating the surface of a substrate with the adhesive mixed powder; rapidly and uniformly pre-sintering the powder on the surface of the substrate by the aid of a flamegun; treating a material by laser cladding. A surface cladding material of a magnesium alloy treated by the method is low in abrasion loss and has the advantages of high surface hardness and the like, the materials has various enhanced phases such as Al2O3, SiC and GO, and the method has the advantages of simplicity, safety, low cost, easiness in operation, controllability and the like.

Description

technical field [0001] The invention belongs to the technical field of material preparation. Background technique [0002] Graphene nanosheets are made of sp 2 A one-atom-thick two-dimensional material composed of hybridized carbon atoms exhibits a series of unusual physical properties. Because of its special two-dimensional structure, graphene nanosheets have attracted great interest from researchers in physics, chemistry and materials science. Basic research and engineering application research on graphene have become a research hotspot in recent years. Due to the high strength of graphene, its tensile strength can reach 130GPa, implying that graphene has a huge application space in material application research. [0003] Due to the extremely outstanding physical properties of graphene such as strength, current research focuses on the enhancement of its mechanical properties, while ignoring its excellent properties in terms of material wear and hardness. A large number ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C24/10
CPCC23C24/103
Inventor 闫洪吴庆捷
Owner NANCHANG UNIV
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