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Low-phosphorus scale and corrosion inhibitor, and preparation method thereof

A scale and corrosion inhibitor, technology in parts by weight, applied in the field of scale and corrosion inhibition, can solve problems such as difficulty in maintaining scale and corrosion inhibition effects, reduce the risk of environmental pollution, have good stability, and improve scale and corrosion dispersion performance effect

Inactive Publication Date: 2019-01-11
昆明明净科技有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current scale and corrosion inhibitors are usually difficult to maintain good scale and corrosion inhibition effects under the current increasingly complex water quality conditions

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0025] A preparation method of a low-phosphorus scale and corrosion inhibitor, comprising the steps:

[0026] A. Slowly add acid to water, then add water-soluble zinc salt to obtain an acid solution of zinc salt;

[0027] B. Add 2-phosphonic acid group-1,2,4 tricarboxylic butane, polyaminopolyether methylidene phosphonic acid, polyaspartic acid, phosphono group to the acid solution of zinc salt at constant temperature The copolymer of carboxylic acid and itaconic acid, after stirring evenly, is cooled to room temperature to obtain a low-phosphorus scale and corrosion inhibitor.

[0028] Further, the constant temperature of the step B is 40-60°C.

[0029] Further, the acid is sulfuric acid; the water-soluble zinc salt of the step A is zinc sulfate.

Embodiment 1

[0031] A low-phosphorus scale and corrosion inhibitor, the low-phosphorus scale and corrosion inhibitor comprises the following components in parts by weight: 20 parts of 2-phosphonic acid group-1,2,4 tricarboxylic butane, polyamino acid 12 parts of ether methylidene phosphonic acid, 15 parts of polyaspartic acid, 12 parts of phosphonocarboxylic acid, 15 parts of itaconic acid copolymer, 12 parts of water-soluble zinc salt and 7 parts of acid.

[0032] A preparation method of a low-phosphorus scale and corrosion inhibitor, comprising the steps:

[0033] A. Slowly add acid to water, then add water-soluble zinc salt to obtain an acid solution of zinc salt;

[0034] B. Add 2-phosphonic acid group-1,2,4 tricarboxylic butane, polyaminopolyether methylidene phosphonic acid, polyaspartic acid, phosphono group to the acid solution of zinc salt at constant temperature The copolymer of carboxylic acid and itaconic acid, after stirring evenly, is cooled to room temperature to obtain a l...

Embodiment 2

[0036] A low-phosphorus scale and corrosion inhibitor, the low-phosphorus scale and corrosion inhibitor comprises the following components in parts by weight: 10 parts of 2-phosphonic acid group-1,2,4 tricarboxylic acid butane, polyamino acid 5 parts of ether based methylene phosphonic acid, 8 parts of polyaspartic acid, 5 parts of phosphonocarboxylic acid, 8 parts of itaconic acid copolymer, 5 parts of water-soluble zinc salt and 3 parts of acid.

[0037] A preparation method of a low-phosphorus scale and corrosion inhibitor, comprising the steps:

[0038] A. Slowly add acid to water, then add water-soluble zinc salt to obtain an acid solution of zinc salt;

[0039] B. Add 2-phosphonic acid group-1,2,4 tricarboxylic butane, polyaminopolyether methylidene phosphonic acid, polyaspartic acid, phosphono group to the acid solution of zinc salt at constant temperature The copolymer of carboxylic acid and itaconic acid, after stirring evenly, is cooled to room temperature to obtain...

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PUM

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Abstract

The invention belongs to the technical field of scale and corrosion inhibition, and discloses a low-phosphorus scale and corrosion inhibitor, and a preparation method thereof. The low-phosphorus scaleand corrosion inhibitor comprises, by weight, 10-20 parts of 2-phosphonobutane-1,2,4-tricarboxylic acid, 5-12 parts of polyaminopolyether methylene phosphonate, 8-15 parts of polyaspartic acid, 5-12parts of phosphonocarboxylic acid, 8-15 parts of an itaconic acid copolymer, 5-12 parts of a water-soluble zinc salt and 3-7 parts of an acid. The preparation method comprises the following steps: A,slowly adding the acid to water, and then adding the water-soluble zinc salt to obtain an acid solution of the zinc salt; and B, adding the 2-phosphonobutane-1,2,4-tricarboxylic acid, polyaminopolyether methylene phosphonate, polyaspartic acid, phosphonocarboxylic acid and itaconic acid copolymer to the acid solution of the zinc salt at a constant temperature, performing uniform stirring, and cooling the obtained mixture to room temperature in order to obtain the low-phosphorus scale and corrosion inhibitor. The low-phosphorus scale and corrosion inhibitor has the characteristics of good stability, low phosphorus, environmental protection and low cost.

Description

technical field [0001] The invention belongs to the technical field of scale and corrosion inhibition, in particular to a low-phosphorus scale and corrosion inhibitor and a preparation method. Background technique [0002] Industrial circulating cooling water is the main body of industrial water, and improving its reuse rate and recycling is a necessary means of saving water and energy. [0003] The industrial circulating cooling water is continuously evaporated during the cooling process, so that the salt concentration in the water continues to increase, which exceeds the solubility of some salts and deeply adheres to the system pipe wall to form scale. Common ones are calcium carbonate, calcium phosphate and magnesium silicate. The generation of scale greatly reduces the heat transfer efficiency, and the scale thickness of 0.5mm reduces the heat transfer coefficient by 15%-20%. At the same time, because the main equipment of the cooling water system is carbon steel, diss...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14
CPCC02F5/14C02F2303/08
Inventor 罗叶
Owner 昆明明净科技有限责任公司
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