Method for producing ethanol by reusing anaerobic digestion effluent and refining tower residue

An anaerobic digestion and residual liquid technology, applied in the direction of fermentation, can solve the problems of poisoning ethanol fermentation yeast, reducing the utilization rate of raw materials, and reducing the utilization rate of raw materials, so as to avoid acid production in ethanol fermentation, improve the performance of ethanol fermentation, and utilize raw materials. rate increase effect

Active Publication Date: 2019-01-11
JIANGNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to reduce the discharge of wastewater and reduce the cost of wastewater treatment, part of the distiller's grains will be directly reused in the ethanol batching process during production, but studies have shown that the reuse ratio of the distiller's grains generally does not exceed 30%, otherwise the solids in the distiller's grains, Substances such as acetic acid, lactic acid and sodium salts will accumulate and poison the ethanol fermentation yeast, resulting in lower raw material utilization
There are still two disadvantages in directly reusing distiller's grains as ingredients: one is that the distiller's grains contains miscellaneous bacteria, and the reuse of ingredients can easily lead to acid production by ethanol fermentation, which reduces the utilization rate of raw materials; It is necessary to add alkali or ammonia water to adjust the pH value to the optimum pH range of liquefaction enzyme, which increases the operation and cost
Taking ethanol fermentation with conventional mixing material concentration as an example, the ethanol concentration of the mature fermented mash is about 11-13% (v / v) after the end of fermentation. If the absolute concentration of ethanol is reduced by 0.1- 0.2% (v / v), it is difficult to detect in production, but for an ethanol production enterprise with an annual output of 100,000 tons, the economic loss caused by this slight impact is about 5 million yuan

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  • Method for producing ethanol by reusing anaerobic digestion effluent and refining tower residue

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Embodiment 1

[0062] The method for producing ethanol by reusing the anaerobic digestion effluent and the residual liquid of the refined tower of the present invention adopts the following process steps:

[0063] Mix the membrane filtrate and the refined tower residue in a ratio of 85:15, the volatile acid concentration is 600mg / L; take 100Kg of crushed corn flour, add 310L of mixed solution ingredients, and add high temperature resistant α-amylase (10U / g starch ), stir well and heat to 86°C and maintain for 200min; reduce the temperature to 60°C, add glucoamylase (180U / g starch), stir well and keep saccharification for 15min. After saccharification, the temperature is lowered to 30°C, and 15% (v / v) yeast seed liquid is added to start fermentation. After the fermentation is completed, ethanol, distillation waste liquid and refined tower liquid are obtained by distillation. The distillation waste was filtered with a 60-mesh filter cloth to obtain wet vinasse and vinasse clear liquid, which was...

Embodiment 2

[0066] The method for producing ethanol by reusing the anaerobic digestion effluent and the residual liquid of the refined tower of the present invention adopts the following process steps:

[0067] Mix the membrane filtrate and the refined tower residue in a ratio of 90:10, the volatile acid concentration is 400mg / L; take 100Kg of crushed brown rice powder, add 260L of mixed liquid ingredients, and add high-temperature resistant α-amylase (8U / g starch ), stir well and heat to 90°C and maintain for 100min; reduce the temperature to 58°C, add glucoamylase (150U / g starch), stir well and keep saccharification for 30min. After saccharification, the temperature is lowered to 30°C, and 10% (v / v) yeast seed liquid is inserted to start fermentation. After the fermentation is completed, ethanol, distillation waste liquid and refined tower liquid are obtained by distillation. The distillation waste was filtered with a 60-mesh filter cloth to obtain wet vinasse and vinasse clear liquid, wh...

Embodiment 3

[0070] The method for producing ethanol by reusing the anaerobic digestion effluent and the residual liquid of the refined tower of the present invention adopts the following process steps:

[0071] Mix the membrane filtrate and the refined tower residue in a ratio of 99:1, the volatile acid concentration is 100mg / L; take 1000Kg of crushed brown rice powder and add 2600L of mixed solution ingredients, add high temperature resistant α-amylase (15U / g starch) , After stirring, heat to 95°C and maintain for 100min; lower the temperature to 60°C, add glucoamylase (160U / g starch), stir well and keep for 30min saccharification. After saccharification, the temperature is lowered to 30°C, and 12% (v / v) yeast seed liquid is inserted to start fermentation. After the fermentation is completed, ethanol, distillation waste liquid and refined tower liquid are obtained by distillation. The distillation waste was filtered with a 60-mesh filter cloth to obtain wet vinasse and vinasse clear liquid...

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Abstract

The invention discloses a method for producing ethanol by reusing anaerobic digestion effluent and refining tower residue, belonging to the technical field of wastewater treatment and ethanol fermentation industry, including the steps: mixing membrane filtrate of anaerobic digestion effluent filtered through films, the residual liquid of the refining tower and the other ingredient water with the crushed grain raw materials, according to the ratio of ingredient water to the crushed grain raw materials is 1 : (2-3.5), saccharifying, fermenting and distilling to obtain ethanol, wherein that membrane filtrate accounts for 10-90% of the water mass of the total ingredient, and the residual liquid in the refining tower accounts for 1-30% of the total ingredient water, and the other ingredient water accounts for 0-60%, and that volatile acid concentration of the ingredient water is controlled at 100-1200 mg / L by adjust the proportion of the membrane filtrate, the residual liquor of the refining tower and other ingredient water or adding acetic acid (based on acetic acid), and at the same time, the alcohol yield is remarkably improve, and the utilization rate of raw materials is improve by1. 5%, reduce that energy consumption and cost of ethanol production.

Description

Technical field [0001] The invention relates to a method for producing ethanol by recycling anaerobic digestion effluent and refined tower residual liquid, and belongs to the technical field of wastewater treatment and ethanol fermentation industry. Background technique [0002] Ethanol is an important industrial raw material. It is widely used in food, medicine, chemical and other industrial fields. It is also an important renewable biomass energy (fuel ethanol) and is highly valued by governments around the world. [0003] While the ethanol industry is developing rapidly, it is also facing very prominent practical problems. That is, the production process needs to consume a lot of starch raw materials and water resources, and produce a lot of high-concentration organic wastewater (distillation waste liquid). According to statistics, at present, more than 60% of ethanol production materials in my country are corn, wheat, aged rice, and brown rice. Each ton of ethanol produced co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P7/08
CPCC12P7/08
Inventor 张建华王柯张宏建陈旭升毛忠贵
Owner JIANGNAN UNIV
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