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Multi-layer composite pipe material and preparation method thereof

A multi-layer composite and layer-composite technology, which is applied in the direction of pipes, rigid pipes, and pipeline protection. problems, to achieve the effects of good mechanical strength and toughness, outstanding oxygen barrier properties, and tight interlayer bonding

Active Publication Date: 2019-01-22
ZHEJIANG JUHUA NEW MATERIALS RES INST CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] 1. The inner layer must use modified or composite polyvinylidene fluoride material, which is easy to precipitate small molecules and difficult to pass the hygienic performance test;
[0008] 2. The cohesive force of the inner and outer layer materials is not strong, and the inner and outer layers are easy to detach, so it is difficult to pass the hydrostatic test of cold water internal pressure, hot water internal pressure and thermal cycle to verify the strength and life of the pipe;
[0009] 3. One-time co-extrusion molding cannot be achieved, and the production process is complicated

Method used

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  • Multi-layer composite pipe material and preparation method thereof

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preparation example Construction

[0032] Adopt the preparation method of a kind of multi-layer composite pipe material as claimed in claim 1, comprise the steps:

[0033] (1) Add different materials to the three extruders that are extruded to form the inner layer, the middle layer and the outer layer, wherein fluoroolefin polymer pellets are added to the extruder used to form the inner layer to form the outer layer Add random polyolefin pellets to the extruder for the middle layer, and add alloy pellets to the extruder for forming the middle layer. After the alloy pellets are mixed with a compatibilizer, fluoroolefin polymer and random polyolefin, the obtained by extrusion granulation;

[0034](2) Under certain extrusion process conditions, use three extruders to extrude the inner layer, middle layer and outer layer respectively. The barrels of the three extruders are divided into 6 heating sections for the inner layer The heating temperature of each section of the barrel of the extruder is: the heating tempe...

Embodiment 1

[0038] The outer layer material uses random polypropylene, and the usage amount is 100 parts by weight; the middle layer material uses an alloy of polyvinylidene fluoride and random polypropylene, and the usage amount is 20 parts by weight, including 45% by weight. Polyvinylidene fluoride, 10% compatibilizer material and 45% random polypropylene; the inner layer material is vinylidene fluoride homopolymer, and the usage amount is 20 parts by weight. Composite pipes are obtained through three-layer co-extrusion once.

Embodiment 2

[0040] The material of the outer layer is atactic polypropylene, and the amount used is 100 parts by weight; the material of the middle layer is an alloy of polyvinylidene fluoride and random polypropylene, and the amount used is 40 parts by weight, including a mass fraction of 40% polypropylene. Vinylidene fluoride, 20% compatibilizer material and 40% random polypropylene; the inner layer material is vinylidene fluoride homopolymer, and the usage amount is 40 parts by weight. Composite pipes are obtained through three-layer co-extrusion once.

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Abstract

The invention discloses a multi-layer composite pipe material and a preparation method thereof. The pipe material is divided into an inner layer, a middle layer and an outer layer, the inner layer ismade from fluoroolefin polymer, the middle layer is made from macromolecule alloy containing a comb-shaped compatilizer, and the outer layer is made from atactic polyolefin. The pipe material adopts athree-layer co-extrusion one-time forming technology and has the advantages that the precipitation is low, the combination among layers is compact, and the production technology is convenient; the pure polyvinylidene fluoride pipe material is environmentally friendly, the precipitating performance is low, and the chemical stability is good; the anti-impacting strength is high, the anti-abrasion and anti-creep effects are achieved, and the mechanical strength and toughness are good; the heat resistance performance is good, the long-term using temperature is -20-100 DEG C, the surface of the material is smooth, the fluid resistance is low, and the oxygen resistance performance is excellent.

Description

technical field [0001] The invention belongs to the technical field of pipes, and in particular relates to a multilayer composite pipe and a preparation method thereof. Background technique [0002] Polyvinylidene fluoride is a material with excellent performance, which is environmentally friendly, has little precipitation and good chemical stability; high impact strength, wear resistance, creep resistance, good mechanical strength and toughness; good heat resistance and non-combustibility , Long-term use temperature -40-150 ℃; excellent quality such as smooth surface, small fluid resistance, and outstanding oxygen barrier performance, especially suitable for pure water transportation and other fields, but the high price of polyvinylidene fluoride makes it difficult for this material to enter the civilian field. Therefore, it has not been widely used in the pipe field. In order to expand the application range of polyvinylidene fluoride in the field of high-purity water tran...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F16L9/12F16L57/02F16L57/04F16L57/06C08L27/16C08L23/12B29C48/18B29C48/49B29L23/00
CPCB29L2023/22C08L23/12C08L27/16C08L2201/08C08L2203/18C08L2205/03F16L9/121F16L57/02F16L57/04F16L57/06
Inventor 范文春郑宏杰张博文毛明忠盛仲夷
Owner ZHEJIANG JUHUA NEW MATERIALS RES INST CO LTD
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